Electrostatic-Induced Assembly of Graphene-Encapsulated Carbon@Nickel–Aluminum Layered Double Hydroxide Core–Shell Spheres Hybrid Structure for High-Energy and High-Power-Density Asymmetric Supercapacitor

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• 作者：Shuxing Wu ; Kwan San Hui ; Kwun Nam Hui ; Kwang Ho Kim
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2017
• 出版时间：January 18, 2017
• 年：2017
• 卷：9
• 期：2
• 页码：1395-1406
• 全文大小：787K
• ISSN：1944-8252

文摘

Achieving high energy density while retaining high power density is difficult in electrical double-layer capacitors and in pseudocapacitors considering the origin of different charge storage mechanisms. Rational structural design became an appealing strategy in circumventing these trade-offs between energy and power densities. A hybrid structure consists of chemically converted graphene-encapsulated carbon@nickel–aluminum layered double hydroxide core–shell spheres as spacers among graphene layers (G-CLS) used as an advanced electrode to achieve high energy density while retaining high power density for high-performance supercapacitors. The merits of the proposed architecture are as follows: (1) CLS act as spacers to avoid the close restacking of graphene; (2) highly conductive carbon sphere and graphene preserve the mechanical integrity and improve the electrical conductivity of LDHs hybrid. Thus, the proposed hybrid structure can simultaneously achieve high electrical double-layer capacitance and pseudocapacitance resulting in the overall highly active electrode. The G-CLS electrode exhibited high specific capacitance (1710.5 F g<sup>–1sup> at 1 A g<sup>–1sup>) under three-electrode tests. An ASC fabricated using the G-CLS as positive electrode and reduced graphite oxide as negative electrode demonstrated remarkable electrochemical performance. The ASC device operated at 1.4 V and delivered a high energy density of 35.5 Wh kg<sup>–1sup> at a 670.7 W kg<sup>–1sup> power density at 1 A g<sup>–1sup> with an excellent rate capability as well as a robust long-term cycling stability of up to 10 000 cycles.