Anchoring Triazole-Gold(I) Complex into Porous Organic Polymer To Boost the Stability and Reactivity of Gold(I) Catalyst

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• 作者：Rong Cai ; Xiaohan Ye ; Qi Sun ; Qiuqin He ; Ying He ; Shengqian MaXiaodong Shi
• 刊名：ACS Catalysis
• 出版年：2017
• 出版时间：February 3, 2017
• 年：2017
• 卷：7
• 期：2
• 页码：1087-1092
• 全文大小：468K
• ISSN：2155-5435

文摘

Stability and reactivity have been recognized as some critical issues for gold(I) catalysts. Such issues can be well-circumvented by anchoring the gold(I) complex onto the backbones of porous organic polymer (POP) followed by coordination with a triazole ligand as illustrated in the present work via a series of gold(I)-catalyzed reactions. In this strategy, 1,2,3-triazole was used as the special “X-factor” to avoid the formation of solid AgCl involved in typical gold-activation processes. The catalyst could be readily recycled without loss of reactivity. Moreover, compared with the PPh₃-modified polystyrene beads, the POP support was advantageous by providing high surface area, hierarchical porosity, and better stabilization of cations. In some cases, significantly improved reactivity was observed, even more so than using the homogeneous system, which further highlighted the great potential of this heterogeneous gold catalyst.