High-Performance Aluminum-Ion Battery with CuS@C Microsphere Composite Cathode

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• 作者：Shuai Wang ; Shuqiang JiaoJunxiang Wang ; Hao-Sen Chen ; Donghua Tian ; Haiping Lei ; Dai-Ning Fang
• 刊名：ACS Nano
• 出版年：2017
• 出版时间：January 24, 2017
• 年：2017
• 卷：11
• 期：1
• 页码：469-477
• 全文大小：598K
• ISSN：1936-086X

文摘

On the basis of low-cost, rich resources, and safety performance, aluminum-ion batteries have been regarded as a promising candidate for next-generation energy storage batteries in large-scale energy applications. A rechargeable aluminum-ion battery has been fabricated based on a 3D hierarchical copper sulfide (CuS) microsphere composed of nanoflakes as cathode material and room-temperature ionic liquid containing AlCl₃ and 1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) as electrolyte. The aluminum-ion battery with a microsphere electrode exhibits a high average discharge voltage of ∼1.0 V vs Al/AlCl₄^–, reversible specific capacity of about 90 mA h g^–1 at 20 mA g^–1, and good cyclability of nearly 100% Coulombic efficiency after 100 cycles. Such remarkable electrochemical performance is attributed to the well-defined nanostructure of the cathode material facilitating the electron and ion transfer, especially for chloroaluminate ions with large size, which is desirable for aluminum-ion battery applications.