Highly Efficient Pt Decorated CoCu Bimetallic Nanoparticles Protected in Silica for Hydrogen Production from Ammonia–Borane

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• 作者：Yuzhen GeZameer Hussain Shah ; Xi-Jie LinRongwen Lu ; Zhangming Liao ; Shufen Zhang
• 刊名：ACS Sustainable Chemistry & Engineering
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：5
• 期：2
• 页码：1675-1684
• 全文大小：716K
• ISSN：2168-0485

文摘

Pt decorated CoCu bimetallic nanoparticles (NPs) coated by silica (Pt-CoCu@SiO₂) were synthesized for efficient catalytic hydrogen production from hydrolysis of ammonia–borane (NH₃·BH₃; AB). Initially, silica-coated CoCu bimetallic NPs (CoCu@SiO₂) were prepared by a modified co-reduction method from reverse microemulsion. Further, Pt-CoCu@SiO₂ was obtained by a facile spontaneous displacement reaction by using CoCu@SiO₂ and H₂PtCl₆ as the starting materials. The catalytic activity of Pt on bimetallic support was compared to that of monometallic supports, i.e., Co and Cu. The results of catalytic experiments showed that the support of CoCu bimetal can significantly enhance the activity of Pt as compared to that of pure Cu or Co. An impressive turnover frequency (TOF) value of 272.8 mol_H2 mol_Pt^–1 min^–1 was achieved at the hydrolysis temperature of 30 °C for Pt-CoCu@SiO₂. The detailed formation process of catalysts was described, and the samples were characterized by TEM, STEM, XPS, EDS element mapping, etc.