Novel Templating Route Using Pt Infiltrated Block Copolymer Microparticles for Catalytic Pt Functionalized Macroporous WO3 Nanofibers and Its Application in Breath Pattern Recognition

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• 作者：Seon-Jin Choi ; Kang Hee Ku ; Bumjoon J. Kim ; Il-Doo Kim
• 刊名：ACS Sensor
• 出版年：2016
• 出版时间：September 23, 2016
• 年：2016
• 卷：1
• 期：9
• 页码：1124-1131
• 全文大小：682K
• ISSN：2379-3694

文摘

We propose a new route for transferring catalysts onto macroporous metal oxide nanofibers (NFs) using metallic nanoparticles (NPs) infiltrated block copolymer microparticles as sacrificial templates. Pt decorated polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP) copolymer microparticles (Pt-BCP MPs), produced from oil-in-water emulsions, were uniformly dispersed within electrospun PVP/W precursor composite NFs. The macropore-loaded WO₃ NFs (macroporous Pt-WO₃ NFs), which are additionally functionalized by Pt NPs (10 nm), were achieved by decomposition of polymeric components and oxidization of W precursor after high-temperature calcination. In particular, macropores with the similar size distribution (50–300 nm) with BCP MPs were also formed on interior and exterior of WO₃ NFs. Chemical sensing performance of macroporous Pt-WO₃ NFs was investigated for pattern recognition of simulated breath gas components at highly humid ambient (95% RH). The result revealed that superior hydrogen sulfide sensitivity (R_air/R_gas = 834.2 ± 20.1 at 5 ppm) and noticeable selectivity were achieved. In addition, H₂S pattern recognition against other chemical components (acetone, toluene, and methyl mercaptan) was clearly identified without any overlapping of each pattern. This work demonstrates the potential application of BCP-templated maroporous Pt-WO₃ NFs in exhaled breath analysis for noninvasive monitoring of physical conditions.