Mesoporous carbon–ZrO2 composites prepared using thermolysis of zirconium based metal–organic frameworks and their adsorption properties

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• 作者：Shu-Cheng Liu ; Zi-Feng Yue ; Yi Liu
• 关键词：MOFs ; Mesoporous carbon ; zirconia ; Congo red ; Water treatment
• 刊名：Journal of Porous Materials
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：22
• 期：2
• 页码：465-471
• 全文大小：2,312 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

Mesoporous carbon–ZrO2 (MCZ) composites are prepared using a simple thermal conversion of metal–organic frameworks (MOFs). By choosing a zirconium based MOFs, called UiO-66, as both the Zr and C precursor and the porous template, porous carbon–ZrO2 hybrid materials are formed by carbonizing UiO-66 at 600?°C in an inert atmosphere. The structure, morphology, and porosity of the products were studied using powder X-ray diffraction, transmission electron microscopy, thermogravimetry, and the BET surface area method. The obtained MCZ materials exhibit a relatively high specific surface area of ~136?m2?g?, a large pore size, and pore volumes of ~9.6?nm and ~0.33?cm??g?, respectively. The results also indicate that the MCZ materials have a good capacity to adsorb Congo red from an aqueous solution.