Self-healing polymers based on a photo-active reversible addition-fragmentation chain transfer (RAFT) agent

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• 作者：Chuanjie Cheng (1)
  Xiongxiong Bai (1)
  Xu Zhang (1)
  Hongxia Li (1)
  Qinghua Huang (1)
  Yuanming Tu (1)
  
  1. Jiangxi Key Laboratory of Organic Chemistry ; Jiangxi Science & Technology Normal University ; Fenglin Street ; Nanchang ; Jiangxi ; 330013 ; People鈥檚 Republic of China
  
• 关键词：Self ; healing ; Reversible addition ; fragmentation chain transfer (RAFT) ; Photo ; active ; Trithiocarbonate ; Functional polymer
• 刊名：Journal of Polymer Research
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：22
• 期：4
• 全文大小：1,860 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1572-8935

文摘

A symmetric photo-active trithiocarbonate was designed and synthesized, which can act not only as a functional reversible addition-fragmentation chain transfer (RAFT) agent, but also as a crosslinker in crosslinking poly(methyl methacrylate-co-hydroxy ethyl acrylate) (poly(MMA-co-HEA)) due to interactions of benzophenone moieties of trithiocarbonate and hydroxyl groups of poly(MMA-co-HEA) under UV irradiation. In addition, the crosslinked poly(MMA-co-HEA) demonstrates photo-promoted self-healing properties by reshuffling C-S bonds of trithiocarbonate.