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Three-dimensional macroporous cellulose-based bioadsorbents for efficient removal of nickel ions from aqueous solution
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  • 作者:Lin Liu ; Jin Peng Xie ; Yu Jiao Li ; Qin Zhang ; Ju Ming Yao
  • 关键词:Cellulose ; Macroporous ; Water purification ; Heavy metal removal ; Biodegradability ; Recyclability
  • 刊名:Cellulose
  • 出版年:2016
  • 出版时间:February 2016
  • 年:2016
  • 卷:23
  • 期:1
  • 页码:723-736
  • 全文大小:2,683 KB
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  • 作者单位:Lin Liu (1) (2)
    Jin Peng Xie (1)
    Yu Jiao Li (1)
    Qin Zhang (1)
    Ju Ming Yao (1) (2)

    1. The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou, 310018, China
    2. National Engineering Lab of Textile Fiber Materials & Processing Technology, Hangzhou, 310018, China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Bioorganic Chemistry
    Physical Chemistry
    Organic Chemistry
    Polymer Sciences
  • 出版者:Springer Netherlands
  • ISSN:1572-882X
文摘
We present a simple synthetic method for the preparation of cellulose-g-poly(acrylic acid-co-acrylamide) materials with three-dimensional macroporous structure, which can be used for the environmental application as the reusable bioadsorbents. In the grafting copolymerization process, the acrylic acid and acrylamide are cross-linked with cellulose molecules to form three-dimensional interconnected porous structure. Due to the macropores and the abundant functional groups, the cellulose-based bioadsorbents exhibit excellent adsorption performance for the removal of nickel ions from aqueous solution with a maximum adsorption capacity of 171.8 mg/g. The adsorption of bioadsorbents to Ni2+ is accurately described by a pseudo-second-order kinetic model and the initial concentration-dependent adsorption isotherm suggests a Langmuir isotherm model. Furthermore, the cellulose-based bioadsorbents can be easily separated from the aqueous solution after adsorption and regenerated using 0.2 M HCl solution, which exhibits high adsorption capacity after six adsorption–desorption cycles. Importantly, the biodegradation rate of 53.1 wt% for the bioadsorbents is found after being incubated in the soil extraction solution for 90 days. Therefore, the eco-friendly cellulose-based bioadsorbents could be used for water purification effectively. Keywords Cellulose Macroporous Water purification Heavy metal removal Biodegradability Recyclability

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