Fabrication and electrochemical performance of nanoflake MnO2@carbon fiber coaxial nanocables for supercapacitors

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• 作者：Ya Chen ; Wen-Qing Qin ; Jia-Wei Wang ; Bai-Zhen Chen
• 关键词：Electrochemical capacitor ; Supercapacitor ; Carbon fiber ; MnO2 ; Composite
• 刊名：Journal of Applied Electrochemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：46
• 期：2
• 页码：241-249
• 全文大小：1,505 KB
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• 作者单位：Ya Chen (1) (2)
  Wen-Qing Qin (1)
  Jia-Wei Wang (2)
  Bai-Zhen Chen (2)
  
  1. School of Resource Processing and Biological Engineering, Central South University, Changsha, 410083, China
  2. School of Metallurgy and Environment, Central South University, Changsha, 410083, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  
• 出版者：Springer Netherlands
• ISSN：1572-8838

文摘

Nanoflake MnO₂@carbon fiber coaxial nanocables were fabricated by a facile electrochemical deposition-oxidation route. The morphology, structure, composition, and pseudocapacitive performance of the obtained composite material were evaluated by scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscopy, cyclic voltammetry, and galvanostatic charge–discharge measurements. The results show that the nanoflake MnO₂ on the carbon fibers is highly amorphous and hydrous. The nanostructured material shows nearly symmetrical and rectangular CV curves in the scan-rate range from 2 to 50 mV s−1. When used as electrodes for supercapacitors, the material shows a capacitance of 511.8 F g−1 at 1 A g−1 (based on the mass of MnO₂), excellent high-rate capability, and cycling stability. Keywords Electrochemical capacitor Supercapacitor Carbon fiber MnO₂ Composite