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Effective removal of anilines using porous activated carbon based on ureaformaldehyde resin
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  • 作者:Fu-Qiang An ; Dong Zhang ; Xiao-Xia Yue ; Guo-Li Ou…
  • 关键词:Activated Carbon ; Nitrogen ; containing ; Adsorption ; Anilines ; Ureaformaldehyde Resin
  • 刊名:Korean Journal of Chemical Engineering
  • 出版年:2016
  • 出版时间:February 2016
  • 年:2016
  • 卷:33
  • 期:2
  • 页码:576-581
  • 全文大小:730 KB
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  • 作者单位:Fu-Qiang An (1)
    Dong Zhang (1)
    Xiao-Xia Yue (1)
    Guo-Li Ou (1)
    Jian-Feng Gao (1)
    Tuo-Ping Hu (1)

    1. Chemical Department, North University of China, Taiyuan, Shanxi, 030051, China
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Industrial Chemistry and Chemical Engineering
    Catalysis
    Materials Science
    Biotechnology
  • 出版者:Springer New York
  • ISSN:1975-7220
文摘
The effective removal of aniline and its derivatives from wastewater is very important due to the high toxicity. Adsorption with a high-performance adsorbent is an efficient pathway. A novel activated carbon, ACUF-700, was synthesized using homemade ureaformaldehyde resin as the major carbon source carbonized at 700 °C. ACUF-700 is characterized by surface area analyzer, FTIR, elemental analyzer, and SEM. The adsorption properties of ACUF-700 towards anilines are also investigated by using batch methods. The test results showed that the ACUF-700 possesses higher specific surface area and narrower pore size distribution. In virtue of its developed pore structure and nitrogencontaining chemical groups, the adsorption capacities towards aniline, p-toluidine and p-chloroaniline could reach 95.6, 108.1 and 128.9mg/g, respectively. The adsorption process could be well described by the intra-particle mass transfer diffusion model and Sips model. Besides, ACUF700 was regenerated easily using diluted hydrochloric acid solution as eluent and ACUF700 possesses better reusability. Keywords Activated Carbon Nitrogen-containing Adsorption Anilines Ureaformaldehyde Resin

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