Photoelectrochemical studies on BiVO4 membranes deposition on transparent conductive substrates by a facile electrophoresis route

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• 作者：Meirong Sui ; Cuiping Han ; Yong Wang…
• 刊名：Journal of Materials Science: Materials in Electronics
• 出版年：2016
• 出版时间：May 2016
• 年：2016
• 卷：27
• 期：5
• 页码：4290-4296
• 全文大小：1,892 KB
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• 作者单位：Meirong Sui (1)
  Cuiping Han (1)
  Yong Wang (1)
  Jingjing Li (1)
  Xiuquan Gu (2)
  
  1. School of Medical Imaging, Xuzhou Medical College, Xuzhou, 221004, China
  2. School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou, 221116, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Optical and Electronic Materials
  Characterization and Evaluation Materials
  
• 出版者：Springer New York
• ISSN：1573-482X

文摘

BiVO₄ membranes were deposited on transparent conducting oxide substrates by a facile electrophoretic deposition route, followed by a thermal sintering process. As the sintering temperature (T _a) raise, the BiVO₄ grains got larger due to the interaction and agglomeration. As a result, the 600 °C sintered BiVO₄ membranes exhibited a photocurrent density of ~23 μA/cm2 at a potential 0.5 V versus the saturated calomel electrode. Besides, a rapid decay behavior was also observed in the curves of photocurrent versus time, which might be attributed to a high carrier recombination. Through applying a positive potential, that instability behavior got suppressed effectively, while the actual photocurrent was enhanced significantly.