The polyacrylic latex: an efficient water-soluble binder for LiNi1/3Co1/3Mn1/3O2 cathode in li-ion batteries

详细信息    查看全文

• 作者：Haoxiang Zhong ; Minghao Sun ; Yong Li ; Jiarong He…
• 关键词：Water ; soluble binder ; Cathode ; LiNi1/3Co1/3Mn1/3O2 ; Li ; ion battery
• 刊名：Journal of Solid State Electrochemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：20
• 期：1
• 页码：1-8
• 全文大小：1,415 KB
• 参考文献：1.Aaron C, Timothy B, Colin H, Kyle K, Buddie M, Brian K (2012) Influences of gold, binder and electrolyte on silicon nanowire performance in li-ion batteries. J Phys Chem C 116:18079–18086CrossRef
  2.Cai ZP, Liang Y, Li WS, Xing LD, Liao YH (2009) Preparation and performances of LiFePO4 cathode in aqueous solvent with polyacrylic acid as a binder. J Power Sources 189:547–551CrossRef
  3.Chen JC, Liu JY, Qi Y, Sun T, Li XD (2013) Unveiling the roles of binder in the mechanical integrity of electrodes for lithium-ion batteries. J Electrochem Soc 160:A1502–A1509CrossRef
  4.Doberdò I, Löffle N, Laszczynski N, Cericola D, Penazzi N, Bodoardoilvia S, Kim GT, Passerini S (2014) Performance of LiNi1/3Mn1/3Co1/3O2/graphite batteries based on aqueous binder. J Power Sources 248:915–922CrossRef
  5.Doberdò I, Löffle N, Laszczynski N, Cericola D, Penazzi N, Bodoardoilvia S, Kim GT, Passerini S (2014) Enabling aqueous binders for lithium battery cathodes—carbon coating of aluminum current collector. J Power Sources 248:1000–1006CrossRef
  6.Fergus JW (2010) Recent developments in cathode materials for lithium ion batteries. J Power Sources 195:939–954CrossRef
  7.Ishii K, Ozaki R, Kaneko K, Fukushima H, Masuda M (2007) Continuous monitoring of aluminum corrosion process in deaerated water. Corros Sci 49:2581–2601CrossRef
  8.Kovalenko I, Zdyrko B, Magasinski A, Hertzberg B, Milicev Z, Burtovyy R, Luzinov I, Yushin G (2011) A major constituent of brown algae for use in high-capacity li-ion batteries. Science 6052:75–79CrossRef
  9.Li JL, Armstrong BL, Kiggans J, Daniel C, WoodIII DL (2012) Optimization of LiFePO4 nanoparticle suspensions with polyethyleneimine for aqueous processing. Langmuir 28:3783–3790CrossRef
  10.Li JL, Armstrong BL, Kiggans J, Daniel C, WoodIII DL (2013) Lithium ion cell performance enhancement using aqueous LiFePO4 cathode dispersions and polyethyleneimine dispersant. J Electrochem Soc 160:A201–A206CrossRef
  11.Li CC, Lee JT, Lo CY, Wu MS (2005) Effects of PAA-NH4 addition on the dispersion property of aqueous LiCoO2 slurries and the cell performance of as-prepared LiCoO2 cathodes. Electrochem Solid St 8:A509–A512CrossRef
  12.Li CC, Lee JT, Peng XW (2006) Improvements of dispersion homogeneity and cell performance of aqueous-processed LiCoO2 cathodes by using dispersant of PAA-NH4. J Electrochem Soc 153:A809–A815CrossRef
  13.Li CC, Wang YW (2013) Importance of binder compositions to the dispersion and electrochemical properties of water-based LiCoO2 cathodes. J Power Sources 227:204–210CrossRef
  14.Ling M, Qiu JX, Li S, Zhao H, Liu G, Zhang SQ (2013) An environmentally benign LIB fabrication process using a low cost, water soluble and efficient binder. J Mater Chem A 1:1543–11547
  15.Liu XZ, Li HQ, Li D, Ishida M, Zhou HS (2013) PEDOT modified LiNi1/3Co1/3Mn1/3O2 with enhanced electrochemical performance for lithium ion batteries. J Power Sources 243:374–380CrossRef
  16.Liu S, Xiong L, He C (2014) Long cycle life lithium ion battery with lithium nickel cobalt manganese oxide (NCM) cathode. J Power Sources 261:285–291CrossRef
  17.Liu G, Zheng H, Kim S, Deng Y, Minor AM, Song X, Battaglia VS (2008) Effects of various conductive additive and polymeric binder contents on the performance of lithium-ion composite cathode. J Electrochem Soc 155:A887–A892CrossRef
  18.Liu G, Zheng H, Simens AS, Minor AM, Song X, Battaglia VS (2007) Optimization of acetylene black conductive additive and PVDF composition for high-power rechargeable lithium-ion cells. J Electrochem Soc 154:A1129–A1134CrossRef
  19.Liu G, Zheng H, Song X, Battaglia VS (2012) Particles and polymer binder interaction: a controlling factor in lithium-ion electrode performance. J Electrochem Soc 159:A214–A221CrossRef
  20.Lux SF, Schappacher F, Balducci A, Passerini S, Winter MJ (2010) Low cost, environmentally benign binders for lithium-ion batteries. J Electrochemical Soc 157:A320–A325CrossRef
  21.Manthiram A, Choi J (2006) Chemical and structural instabilities of lithium ion battery cathodes. J Power Sources 159:249–253CrossRef
  22.Pohjalainen E, Räsänen S, Jokinen M, Yliniemi K, Worsley DA, Kuusivaara J, Juurikivi J, Ekqvist R, Kallio T, Karppinen M (2013) Water soluble binder for fabrication of Li4Ti5O12 electrodes. J Power Sources 226:134–139CrossRef
  23.Ryu WH, Lim SJ, Kim WK, Kwon HS (2014) 3-D dumbbell-like LiNi1/3Mn1/3Co1/3O2 cathode materials assembled with nano-building blocks for lithium-ion batteries. J Power Sources 257:186–191CrossRef
  24.Wang ZL, Dupréa N, Gaillot AC, Lestriez B, Martin JF, Daniel L, Patoux S, Guyomard D (2012) CMC as a binder in LiNi0.4Mn1.6O4 5 V cathodes and their electrochemical performance for li-ion batteries. Electrochimica Acta 62:77–83CrossRef
  25.Wang JL, Yao ZD, Monroe CW, Yang J, Nuli Y (2013) Carbonyl-β-Cyclodextrin as a novel binder for sulfur composite cathodes in rechargeable lithium batteries. Adv Funct Mater 23:1194–1201CrossRef
  26.Wu QL, Ha S, Prakash J, Dees WD, Lu WQ (2013) Investigations on high energy lithium-ion batteries with aqueous binder. Electrochimica Acta 114:1–6CrossRef
  27.Xu JT, Chou SL, Gu QF, Liu HK, Dou SX (2013) The effect of different binders on electrochemical properties of LiNi1/3Mn1/3Co1/3O2 cathode material in lithium ion batteries. J Power Sources 225:172–178CrossRef
  28.Xu YH, Yin GP, Ma YL, Zuo PJ, Cheng XQ (2010) Simple annealing process for performance improvement of silicon anode based on polyvinylidene fluoride binder. J Power Sources 195:2069–2073CrossRef
  29.Zhang XY, Jiang WJ, Zhu XP, Mauger A, Lu Q, Julien CM (2011) Aging of LiNi1/3Mn1/3Co1/3O2 cathode material upon exposure to H2O. J Power Sources 196:5102–5108CrossRef
  30.Zhang ZA, Zeng T, Qu CM, Lu H, Jia M, Lai YQ, Li J (2012) Cycle performance improvement of LiFePO4 cathode with polyacrylic acid as binder. Electrochimica Acta 80:440–444CrossRef
  31.Zhang L, Zhang LY, Chai LL, Xue P, Hao WW, Zheng HH (2014) A coordinatively cross-linked polymeric network as a functional binder for high-performance silicon submicro-particle anodes in lithium-ion batteries. J Mater Chem A 2:19036–19045CrossRef
  32.Zheng HH, Tan L, Liu G, Song XY, Battaglia VS (2012) Calendering effects on the physical and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 cathode. J Power Sources 208:52–57CrossRef
  33.Zheng HH, Yang RZ, Liu G, Song XY, Battaglia VS (2012) Cooperation between active material, polymeric binder and conductive carbon additive in lithium ion battery cathode. J Phys Chem C 116:4875–4881CrossRef
  34.Zhu J, Lu L, Zeng KY (2013) Nanoscale mapping of lithium-ion diffusion in a cathode within an all-solid-state lithium-ion battery by advanced scanning probe microscopy techniques. ACS Nano 7:1666–1675CrossRef
  35.Zhu SM, Zhou HS, Miyoshi T, Hibino M, Honma I, Ichihara M (2004) Self-assembly of the mesoporous electrode material Li3Fe2(PO4)3 using a cationic surfactant as the template. Adv Mater 16:2012–2017CrossRef
  
• 作者单位：Haoxiang Zhong (1)
  Minghao Sun (1) (2)
  Yong Li (1) (2)
  Jiarong He (1) (2)
  Jianwen Yang (3)
  Lingzhi Zhang (1)
  
  1. Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, Guangdong, 510640, China
  2. University of Chinese Academy of Sciences, Beijing, 100039, China
  3. College of Chemistry & Bioengineering, Guilin University of Technology, Jiangan Road, Guilin, Guangxi, 541004, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Analytical Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  Condensed Matter
  Electronic and Computer Engineering
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1433-0768

文摘

The polyacrylic latex (LA132) was firstly reported as a water-soluble binder for LiNi_1/3Co_1/3Mn_1/3O₂ (NCM) cathode in Li-ion battery. The electrochemical performances of NCM cathode with LA132 binder were investigated and compared with the conventional water-soluble sodium carboxymethyl cellulose (CMC) and commercial non-aqueous polyvinylidene difluoride (PVDF). NCM cathode with LA132 binder exhibited a much higher specific capacity of 146 mAh g−1 and capacity retention of 96.4 % after 100 cycles as compared with 122 mAh g−1/88 % and 121 mAh g−1/75% for the NCM electrode with CMC and PVDF, respectively. In addition, NCM cathode with LA132 binder exhibited better rate capability than that of CMC and PVDF, e.g., retaining 34.3 % capacity of C/5 at 5 C rate as compared with 28.5 and 10.9 % for CMC and PVDF, respectively.