Montmorillonite-supported KF/CaO: a new solid base catalyst for biodiesel production

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• 作者：Lihua Jia ; Yanhui Li ; Juan Chen ; Xiangfeng Guo…
• 关键词：KF ; CaO ; Montmorillonite ; Solid base ; Biodiesel ; Transesterification
• 刊名：Research on Chemical Intermediates
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：42
• 期：3
• 页码：1791-1807
• 全文大小：881 KB
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• 作者单位：Lihua Jia (1)
  Yanhui Li (1)
  Juan Chen (1)
  Xiangfeng Guo (1)
  Shengfeng Lou (1)
  Hailong Duan (1)
  
  1. College of Chemistry and Chemical Engineering, Key Laboratory of Fine Chemicals, College of Heilongjiang Province, Qiqihar University, Qiqihar, 161006, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

Biodiesel is an alternative to petroleum-derived diesel fuel; development of a high-efficiency base catalyst to be used in heterogeneous biodiesel production is still a challenge. In this paper, a novel solid base catalyst, KF- and CaO-supported montmorillonite (KCa/MMT) was successfully synthesized by a facile impregnation method, and used for producing biodiesel in transesterification of commercial soybean oil with methanol. The catalysts were characterized by X-ray diffraction, carbon dioxide temperature-programmed desorption and scanning electron microscopy. Effects of the parameters, such as the loading amount of KF, the amount of KCa/MMT, and the methanol to oil molar ratios, on the yield of biodiesel were investigated. A maximum biodiesel yield of 98 % was obtained under the optimal reaction conditions. The separated catalyst can be directly used in the next round of reactions and gave a satisfactory yield. Furthermore, analysis of the catalyst's tolerance to oil-containing water or free fatty acids, and a kinetic study were also carried out. Koros–Nowak tests were designed and conducted, and it was proven that the heat and mass transfer were not limited by the reaction rate.