A method for the direct growth of carbon nanotubes on macroscopic carbon substrates

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• 作者：Rongjun Song ; Lina Liu ; Dongwan Yan ; Yun Xiong ; Chaoen Li
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：51
• 期：5
• 页码：2330-2337
• 全文大小：1,685 KB
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• 作者单位：Rongjun Song (1)
  Lina Liu (1)
  Dongwan Yan (1)
  Yun Xiong (2)
  Chaoen Li (3)
  
  1. Heilongjiang Key Laboratory of Molecular Design and Preparation of Flame Retarded Materials, College of Science, Northeast Forestry University, Harbin, 150040, People’s Republic of China
  2. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, People’s Republic of China
  3. CSIRO Energy, 71 Normanby Road, Clayton North, VIC, 3168, Australia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

A simple and general approach is reported for the direct growth of carbon nanotubes (CNTs) on macroscopic carbon substrates. Two typical geometries of biomass materials, cellulose fibers or rice husks, are chosen to act as the precursor of carbon substrates, and commercial polypropylene (PP) pellets are used as the carbon source of CNTs with the presence of Ni–Mo–Mg catalysts. This simple and general strategy was realized by a direct pyrolyzation of the PP blends containing biomass materials and Ni–Mo–Mg catalysts in a chemical vapor deposition device at 800 °C under nitrogen’s protection. The carbon products were characterized by various techniques such as X-ray diffractometer, transmission electron microscopy, scanning electron microscopy, Raman spectroscopy, and thermogravimetric analysis. Results show that the CNTs are successfully grown on the macroscopic carbon substrate derived from cellulose fibers or rice husks, whereas the addition of biomass materials as carbon precursors has to some extent an influence on the morphology of CNTs in the carbon products.