(Vapor + Liquid) Equilibrium (VLE) for Binary Lead-Antimony System in Vacuum Distillation: New Data and Modeling Using Nonrandom Two-Liquid (NRTL) Model

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• 作者：Junjie Xu ; Lingxin Kong ; Baoqiang Xu…
• 刊名：Metallurgical and Materials Transactions A
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：47
• 期：9
• 页码：4494-4501
• 全文大小：962 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Metallic Materials
  Structural Materials
  Physical Chemistry
  Ceramics,Glass,Composites,Natural Materials
  
• 出版者：Springer Boston
• ISSN：1543-1940
• 卷排序：47

文摘

In this work, new experimental vapor–liquid equilibrium (VLE) data of lead-antimony alloy (Pb-Sb alloy) in vacuum distillation are reported. The activity coefficients of components of Pb-Sb alloy were calculated by using the NRTL model. The calculated average relative deviations were ±0.1425 and ±0.2433 pct, and the average standard deviations were ±0.0009 and ±0.0007, respectively, for Pb and Sb. The VLE phase diagrams, such as the temperature composition (T-x) and pressure composition (P-x) diagrams of Pb-Sb alloy in vacuum distillation were predicted based on the NRTL model and VLE theory. The predicted results are consistent with the new experimental data indicating that VLE phase diagrams obtained by this method are reliable. The VLE phase diagrams of alloys will provide an effective and intuitive way for the technical design and realization of recycling and separation processes. The VLE data may be used in separation processes design, and the thermodynamic properties as the key parameters in specific applications.Manuscript submitted January 25, 2016.