Mixed matrix membranes comprising PMP polymer with dispersed alumina nanoparticle fillers to separate CO₂/N₂

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• 作者：Mohammad Hadi Nematollahi ; Amir Hossein Saeedi Dehaghani…
• 关键词：mixed matrix membranes ; CO2/N2 separation performance ; poly(4 ; methyl ; 1 ; pentyne) (PMP) ; Al2O3 nano particles ; selectivity and permeability ; operating pressure
• 刊名：Macromolecular Research
• 出版年：2016
• 出版时间：September 2016
• 年：2016
• 卷：24
• 期：9
• 页码：782-792
• 全文大小：2,041 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673
• 卷排序：24

文摘

In regards to the evolution of desirable properties and chemical structure for high performance of gas separation by membranes, mixed matrix membranes (MMMs), need to be carefully designed and controlled to realize high efficiency. This research investigates the role of the main parameters in the fabrication and performance analysis of MMMs prepared through blending of alumina nano particles (Al₂O₃) and poly(4-methyl-1-pentyne) known as PMP with various weight percentages of alumina nano-particles in the PMP precursor. Precursor and resultant MMMs were characterized using thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) techniques. SEM images demonstrated the proper dispersion of Al₂O₃ particles in the precursor matrix. Results indicated that the microstructure of the precursor, blend composition, and the content of nano particles play an important role in gas transport properties of the resulting MMMs. The influence of the percentage of alumina nano particles used in the precursor matrix on the CO₂ and N₂ permeability and CO₂/N₂ illustrated a selective trend for the MMMs. Using higher alumina content resulted in membranes with higher permeability and ideal selectivity. The highest rate of CO₂ and N₂ permeability could be obtained from PMP-alumina with a loading of 30 wt% alumina (PMP30) at 10 bar. Furthermore, these results suggest that PMP30 MMMs (at operating pressures of 8 bar) are exceptional candidates for the CO₂/N₂ separation, offering enhanced gas pair selectivity in the range of 4.5-5 depending on the operating pressure. The results of this research revealed that high-performance gas separation by MMMs can be realized through adopting a judicious combination of blending and dispersing techniques.Keywordsmixed matrix membranesCO₂/N₂ separation performancepoly(4-methyl-1-pentyne) (PMP)Al₂O₃ nano particlesselectivity and permeabilityoperating pressureReferences(1).J. H. Kim, B. R. Min, Y. W. Kim, S. W. Kang, J. Won, and Y. S. Kang, Macromol. Res., 15, 343 (2007).CrossRefGoogle Scholar(2).S. W. Kang, J. Hong, and J. H. Kim, Macromol. Res., 19, 79 (2011).CrossRefGoogle Scholar(3).S. M. Park, J. Won, M.-J. Lee, Y. S. Kang, S.-H. Kim, Y. Kim, and S.-J. Kim, Macromol. Res., 12, 598 (2004).CrossRefGoogle Scholar(4).S. W. Kang, Macromol. Res., 18, 705 (2010).CrossRefGoogle Scholar(5).U.S. Energy Information Administration, Electricity Explained - Basics (2014).(6).K. Ribeiro, S. Kobayashi, M. Beuthe, J. Gasca, D. Greene, D. S. Lee, Y. Muromachi, P. J. Newton, S. Plotkin, D. Sperling, R. Wit, and P. J. 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C, 115, 6661 (2011).CrossRefGoogle ScholarCopyright information© The Polymer Society of Korea and Springer Sciene+Business Media Dordrecht 2016Authors and AffiliationsMohammad Hadi Nematollahi1Amir Hossein Saeedi Dehaghani2Email authorVahid Pirouzfar3Ebrahim Akhondi41.Department of Chemical Engineering, Shahreza BranchIslamic Azad UniversityShahrezaIran2.Petroleum Engineering Group, Faculty of Chemical EngineeringTarbiat Modares UniversityTehranIran3.Young Researchers and Elite Club, Central Tehran BranchIslamic Azad UniversityTehranIran4.Department of Chemical Engineering, Central Tehran BranchIslamic Azad UniversityTehranIran About this article CrossMark Print ISSN 1598-5032 Online ISSN 2092-7673 Publisher Name The Polymer Society of Korea About this journal Reprints and Permissions Article actions function trackAddToCart() { var buyBoxPixel = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox", product: "10.1007/s13233-016-4113-6_Mixed matrix membranes comprising ", productStatus: "add", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); buyBoxPixel.sendinfo(); } function trackSubscription() { var subscription = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "springer_com.buybox" }); subscription.sendinfo({linkId: "inst. subscription info"}); } window.addEventListener("load", function(event) { var viewPage = new webtrekkV3({ trackDomain: "springergmbh01.webtrekk.net", trackId: "196033507532344", domain: "link.springer.com", contentId: "SL-article", product: "10.1007/s13233-016-4113-6_Mixed matrix membranes comprising ", productStatus: "view", productCategory : { 1 : "ppv" }, customEcommerceParameter : { 9 : "link.springer.com" } }); viewPage.sendinfo(); }); Log in to check your access to this article Buy (PDF)EUR 34,95 Unlimited access to full article Instant download (PDF) Price includes local sales tax if applicable Find out about institutional subscriptions Export citation .RIS Papers Reference Manager RefWorks Zotero .ENW EndNote .BIB BibTeX JabRef Mendeley Share article Email Facebook Twitter LinkedIn Cookies We use cookies to improve your experience with our site. 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