Synthesis and structures of two cobalt compounds of 2-amino-2-methyl-1-propanol

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• 作者：YONGJIE QIN ; SHANSHAN YANG ; LONG LIU ; YUNING LIANG…
• 关键词：Crystal structure ; Cobalt ; 2 ; amino ; 2 ; methyl ; 1 ; propanol.
• 刊名：Journal of Chemical Sciences
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：129
• 期：1
• 页码：31-37
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry/Food Science, general;
• 出版者：Springer India
• ISSN：0973-7103
• 卷排序：129

文摘

The reactions of 2-amino-2-methyl-1-propanol (MepH) with Co(ClO₄)₂⋅6H₂O in the presence of acetic acid gave [Co₂(Mep)₃(OAc)(MepH)](ClO₄)₂⋅MepH (1) and [Co\(^{\text {III}}_{4}\)Co\(^{\text {II}}_{2}\)(Mep)₈(μ₃-OH)₂(OAc)₄](ClO₄)₂⋅ 2EtOH ⋅2H₂O (2). They were characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. Compound 1 presents a dinuclear structure with its two Co atoms linked by two Mep− ligands and one acetate ligand. The two Co(II) and four Co(III) centers in 2 are held together by eight Mep− ligands, two μ₃-OH− ions and four acetate ligands to form a hexanuclear skeleton which contains a defected face-shared dicubane core. Their discrete polynuclear units are further linked into double-layered and mono-layered two-dimensional H-bonded framework, respectively.