Effect of aldehydes crosslinkers on properties of bacterial cellulose-poly(vinyl alcohol) (BC/PVA) nanocomposite hydrogels

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• 作者：Liang Yang ; Chenfei Wang ; Liping Chen ; Xuemei Wang ; Ping Cui…
• 关键词：Bacterial cellulose ; Poly(vinyl alcohol) ; Dialdehyde ; Cross ; linking degree ; Nanocomposite hydrogels
• 刊名：Fibers and Polymers
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：18
• 期：1
• 页码：33-40
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Polymer Sciences;
• 出版者：The Korean Fiber Society
• ISSN：1875-0052
• 卷排序：18

文摘

The effects of the aldehydes crosslinkers on properties of the BC/PVA nanocomposite hydrogels were investigated. BC as the reinforcement and PVA as the matrix materials of the BC/PVA nanocomposite hydrogels, the hydrogels were prepared in coagulating bath of sodium sulfate and cross-linked with kinds of aldehydes. The hydrogels were characterized by Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), Equilibrium swelling ratio (ESR) tests, mechanical properties tests, thermo-gravimetric analysis (TGA) and X-ray diffraction (XRD) analysis. It was found that the dialdehyde (glyoxal, glutaraldehyde) crosslinkers were more efficient than monoaldehyde (formaldehyde, acetaldehyde) crosslinkers. The ESR, mechanical properties of the BC/PVA nanocomposite hydrogels were obviously influenced by aldehydes crosslinkers. However, their thermo stability and crystallinity were scarcely influenced. The nanocomposite hydrogels described in this study provides information for further development and optimization of a variety of nanofiber-polymer matrix composite hydrogels.