Solubility and diffusivity of CO₂ in n-butanol + N235 system and absorption mechanism of CO₂ in a coupled reaction-extraction process

详细信息    查看全文

• 作者：Guilan Chen ; Xingfu Song ; Shuying Sun…
• 关键词：carbon dioxide ; N235 ; solubility ; diffusivity ; coupled process
• 刊名：Frontiers of Chemical Science and Engineering
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：10
• 期：4
• 页码：480-489
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Industrial Chemistry/Chemical Engineering; Nanotechnology;
• 出版者：Higher Education Press
• ISSN：2095-0187
• 卷排序：10

文摘

The absorption of CO₂ in insoluble organic amine is crucial for understanding the mechanism of coupled reaction-extraction-crystallization process between aqueous chloride and CO₂. In this study, the solubility and diffusivity of CO₂ in n-butanol + N235 system were measured and reported. The absorption of CO₂ in the system is a physical absorption behavior and the solubility of CO₂ decreases with the increase of the mass fraction of N235. The diffusivity of CO₂ increases firstly and then decreases with the increase in the mass fraction of N235. Moreover, the absorption mechanism of CO₂ in the coupled reaction-extraction-crystallization process was investigated and identified by experiments. The results indicated that in the coupled reaction-extraction-crystallization process, CO₂ is absorbed by the aqueous phase rather than by the organic phase and further transferred into the aqueous phase.Keywordscarbon dioxideN235solubilitydiffusivitycoupled processReferences1.Pai R A, Doherty M F, Malone M F. Design of reactive extractionsystems for bioproduct recovery. AIChE Journal, 2002, 48(3): 514–526CrossRefGoogle Scholar2.Van Halsema F E D, Wielen L A M, Luyben K C A M. The modeling of carbon dioxide-aided extraction of carboxylic acids from aqueous solutions. Industrial & Engineering Chemistry Research, 1998, 37(3): 748–758CrossRefGoogle Scholar3.Kuzmanovic B, Kuipers N J M, Haan André B, Kwant G. Reactive extraction of carboxylic acids from apolar hydrocarbons using aqueous solutions of sodium hydrogen carbonate with backrecovery using carbon dioxide under pressure. Separation and Purification Technology, 2005, 47(1): 58–72CrossRefGoogle Scholar4.Bi P Y, Dong H R, Guo Q Z. Separation and purification of penicillin G from fermentation broth by solvent sublation. Separation and Purification Technology, 2009, 65(2): 228–231CrossRefGoogle Scholar5.Jaquet A, Quan L, Marison I W, Stockar U V. Factors influencing the potential use of Aliquat 336 for the in situ extraction of carboxylic acids from cultures of pseudomonas putida. Journal of Biotechnology, 1999, 68(2-3): 185–196CrossRefGoogle Scholar6.Glöckler R, Roduit J P. Industrial bioprocesses for the production of substituted aromatic heterocycles. Chimia, 1996, 50(9): 413–415Google Scholar7.Miller R W, Cockrem MC M, Pablo J J D, Lightfoot E N. Extraction of lactic acid from a calcium lactate solution using amine-containing solvents and carbon dioxide gas. Industrial & Engineering Chemistry Research, 1996, 35(4): 1156–1162CrossRefGoogle Scholar8.Zhang J S, Zhang R, Geerlings H, Bi J C. A novel indirect wollastonite carbonation route for CO₂ sequestration. Chemical Engineering & Technology, 2010, 33(7): 1177–1183CrossRefGoogle Scholar9.Vinoba M, Bhagiyalakshmi M, Grace A N, Chu D H, Yoon Y. CO₂ absorption and sequestration as various polymorphs of CaCO3 using sterically hindered amine. Langmuir, 2013, 29(50): 15655–15663CrossRefGoogle Scholar10.Wang W L, Hu M Q, Zheng Y L, Wang P, Ma C Y. CO₂ fixation in Ca2+-/Mg2+-rich aqueous solutions through enhanced carbonate precipitation. Industrial & Engineering Chemistry Research, 2011, 50(13): 8333–8339CrossRefGoogle Scholar11.Liu X, Wang W L, Wang M, Wang P. Experimental study of CO₂ mineralization in Ca2+-rich aqueous solutions using tributylamine as an enhancing medium. Energy & Fuels, 2014, 28(3): 2047–2053CrossRefGoogle Scholar12.Wang W L, Wang M, Liu X, Wang P, Xi Z Q. Experiment and optimization for simultaneous carbonation of Ca2+ and Mg2+ in a two-phase system of insoluble diisobutylamine and aqueous solution. Scientific Reports, 2015, 5: 1–9CrossRefGoogle Scholar13.Li Y Z, Song X, Chen G, Sun Z, Xu Y, Yu J. Song X F, Chen G L, Sun Z, Xu Y X, Yu J G. Preparation of calcium carbonate and hydrogen chloride from distiller waste based on reactive extractioncrystallization process. Chemical Engineering Journal, 2015, 278: 55–61CrossRefGoogle Scholar14.Li Y Z, Song X F, Sun S Y, Xu Y X, Yu J G. Extraction equilibrium of hydrochloric acid at low concentrations between water and N235 in isoamyl alcohol solution: Experiments and simulation. Journal of Chemical & Engineering Data, 2015, 60(10): 3000–3008CrossRefGoogle Scholar15.Zhou Z Y, Liang F, Qin W, Fei W Y. Coupled reaction and solvent extraction process to form Li₂CO₃: Mechanism and product characterization. AIChE Journal, 2014, 60(1): 282–288CrossRefGoogle Scholar16.Li Y Z, Song X F, Chen G L, Yu J G. Extraction of hydrogen chloride by a coupled reaction-solvent extraction process. Front Chem Sci Eng, 2015, 9(4): 479–487CrossRefGoogle Scholar17.Li J, Ye Y M, Chen L F, Qi Z W. Solubilities of CO₂ in poly (ethylene glycols) from (303. 15 to 333. 15) K. Journal of Chemical & Engineering Data, 2012, 57(2): 610–616CrossRefGoogle Scholar18.Li J, Chen L F, Ye Y M, Qi Z W. Solubility of CO₂ in the mixed solvent system of alkanolamines and poly(ethylene glycol) 200. Journal of Chemical & Engineering Data, 2014, 59(6): 1781–1787CrossRefGoogle Scholar19.Guo C, Chen S Y, Zhang Y C, Wang G B. Solubility of CO₂ in nonaqueous absorption system of 2-(2-Aminoethylamine)ethanol + benzyl alcohol. Journal of Chemical & Engineering Data, 2014, 59(6): 1796–1801CrossRefGoogle Scholar20.Kim Y E, Choi J H, Nam S C, Yoon Y I. CO₂ absorption capacity using aqueous potassium carbonate with 2-methylpiperazine and piperazine. Journal of Industrial and Engineering Chemistry, 2012, 18(1): 105–110CrossRefGoogle Scholar21.Gui X, Tang Z G, Fei W Y. CO₂ capture with physical solvent dimethyl carbonate at high pressures. Journal of Chemical & Engineering Data, 2010, 55(9): 3736–3741CrossRefGoogle Scholar22.Ko J J, Li M H. Kinetics of absorption of carbon dioxide into solutions of N-methyldiethanolamine + water. Chemical Engineering Science, 2000, 55(19): 4139–4147CrossRefGoogle Scholar23.Wang Y, Gao H, Yan W. Excess molar enthalpies of diethyl malonate + (1-butanol, 2-methyl-1-propanol, 1-pentanol, n-heptane, and ethyl acetate) at T = (288. 2, 298. 2, 313. 2, 328. 2, 338. 2, and 348. 2 K) and p = 101. 3 kPa. Fluid Phase Equilibria, 2010, 291(1): 8–12CrossRefGoogle Scholar24.Estrada-Baltazar A, Iglesias-Silva G A, Caballero-Cerón C. Volumetric and transport properties of binary mixtures of n-octane + ethanol, + 1-Propanol, + 1-butanol, and + 1-pentanol from (293. 15 to 323. 15) K at atmospheric pressure. Journal of Chemical & Engineering Data, 2013, 58(12): 3351–3363CrossRefGoogle Scholar25.Mokhtarani B, Sharifi A, Mortaheb H R, Mirzaei M, Mafi M, Sadeghian F. Density and viscosity of 1-butyl-3-methylimidazolium nitrate with ethanol, 1-propanol, or 1-butanol at several temperatures. Journal of Chemical Thermodynamics, 2009, 41(12): 1432–1438CrossRefGoogle Scholar26.Gui X, Tang Z G, Fei W Y. Solubility of CO₂ in alcohols, glycols, ethers, and ketones at high pressures from (288. 15 to 318. 15) K. Journal of Chemical & Engineering Data, 2011, 56(5): 2420–2429CrossRefGoogle Scholar27.Anthony J L, Maginn E J, Brennecke J F. Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate. Journal of Physical Chemistry B, 2002, 106(29): 7315–7320CrossRefGoogle Scholar28.Abuarabi M K A, Tamimi A, Aljarrah A M. Solubility and diffusivity of CO₂ in triethanolamine solutions. Journal of Chemical & Engineering Data, 2001, 46(5): 1125–1129CrossRefGoogle Scholar29.Takeuchi H, Fujine M, Sato T, Onda K. Simultaneous determination of diffusion coefficient and solubility of gas in liquid by a diaphragm cell. Journal of Chemical Engineering of Japan, 1975, 8(3): 252–253CrossRefGoogle Scholar30.Sada E, Kumazawa H, Han Z Q, Matsuyama H. Chemical kinetics of the reaction of carbon dioxide with ethanolamines in nonaqueous solvents. AIChE Journal, 1985, 31(8): 1297–1303CrossRefGoogle Scholar31.Alvarez F C, Midoux N, Laurent A, Charpentier J C. Chemical kinetics of the reaction of carbon dioxide with amines in pseudo mnth order conditions in aqueous and organic solutions. Chemical Engineering Science, 1980, 35(8): 1717–1723CrossRefGoogle Scholar32.Won Y S, Chung D K, Mills A F. Density, viscosity, surface tension, and carbon dioxide solubility and diffusivity of methanol, ethanol, aqueous propanol, and aqueous ethylene glycol at 25 °C. Journal of Chemical & Engineering Data, 1981, 26(2): 140–141CrossRefGoogle Scholar33.Dalmolin I, Skovroinski E, Biasi A, Corazza M L, Dariva C, Oliveira J V. Solubility of carbon dioxide in binary and ternary mixtures with ethanol and water. Fluid Phase Equilibria, 2006, 245(2): 193–200CrossRefGoogle Scholar34.Versteeg G F, Van S W. Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkanolamine solutions. Journal of Chemical & Engineering Data, 1988, 33(1): 29–34CrossRefGoogle ScholarCopyright information© Higher Education Press and Springer-Verlag Berlin Heidelberg 2016Authors and AffiliationsGuilan Chen1Xingfu Song1Email authorShuying Sun1Yanxia Xu1Jianguo Yu1Email author1.National Engineering Research Center for Integrated Utilization of Salt Lake ResourceEast China University of Science and TechnologyShanghaiChina About this article CrossMark Publisher Name Higher Education Press Print ISSN 2095-0179 Online ISSN 2095-0187 About this journal Reprints and Permissions Article actions Export citation .RIS Papers Reference Manager RefWorks Zotero .ENW EndNote .BIB BibTeX JabRef Mendeley Share article Email Facebook Twitter LinkedIn Cookies We use cookies to improve your experience with our site. More information Accept Over 10 million scientific documents at your fingertips