Three-dimensional graphene membrane cathode for high energy density rechargeable lithium-air batteries in ambient conditions

详细信息    查看全文

• 作者：Xing Zhong ; Benjamin Papandrea ; Yuxi Xu ; Zhaoyang Lin ; Hua Zhang ; Yuan Liu…
• 关键词：energy storage ; graphene framework ; three ; dimensional (3D) ; network ; lithium air ; battery ; water resistive
• 刊名：Nano Research
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：10
• 期：2
• 页码：472-482
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Nanotechnology; Materials Science, general; Atomic/Molecular Structure and Spectra; Condensed Matter Physics; Biotechnology; Biomedicine, general;
• 出版者：Tsinghua University Press
• ISSN：1998-0000
• 卷排序：10

文摘

Lithium-air batteries have attracted significant interest for applications in high energy density mobile power supplies, yet there are considerable challenges to the development of rechargeable Li-air batteries with stable cycling performance under ambient conditions. Here we report a three-dimensional (3D) hydrophobic graphene membrane as a moisture-resistive cathode for high performance Li-air batteries. The 3D graphene membrane features a highly interconnected graphene network for efficient charge transport, a highly porous structure for efficient diffusion of oxygen and electrolyte ions, a large specific surface area for high capacity storage of the insulating discharge product, and a network of highly tortuous hydrophobic channels for O₂/H₂O selectivity. These channels facilitate O₂ ingression while retarding moisture diffusion and ensure excellent charge/discharge cycling stability under ambient conditions. The membrane can thus enable robust Li-air batteries with exceptional performance, including a maximum cathode capacity that exceeds 5,700 mAh/g and excellent recharge cycling behavior (>2,000 cycles at 140 mAh/g, and >100 cycles at 1,400 mAh/g). The graphene membrane air cathode can deliver a lifetime capacity of 100,000–300,000 mAh/g, comparable to that of a typical lithium ion battery cathode. The stable operation of Li-air batteries with significantly improved single charge capacities and lifetime capacities comparable to those of Li-ion batteries may offer an attractive high energy density storage alternative for future mobile power supplies. These batteries may provide much longer battery lives and greatly reduced recharge frequency.