A highly Selective Fluorescent Sensor for Monitoring Cu²⁺ Ion: Synthesis, Characterization and Photophysical Properties

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• 作者：Stephen Opeyemi Aderinto ; Yuling Xu ; Hongping Peng ; Fei Wang…
• 关键词：Naphthalimide ; Schiff base ; Cu2+ ; Fluorescent sensor
• 刊名：Journal of Fluorescence
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：27
• 期：1
• 页码：79-87
• 全文大小：
• 刊物类别：Biomedical and Life Sciences
• 刊物主题：Biomedicine, general; Biological and Medical Physics, Biophysics; Biotechnology; Biochemistry, general; Analytical Chemistry;
• 出版者：Springer US
• ISSN：1573-4994
• 卷排序：27

文摘

A new fluorescent sensor, 4-allylamine-N-(N-salicylidene)-1,8-naphthalimide (1), anchoring a naphthalimide moiety as fluorophore and a Schiff base group as receptor, was synthesized and characterized. The photophysical properties of sensor 1 were conducted in organic solvents of different polarities. Our study revealed that, depending on the solvent polarity, the fluorescence quantum yields varied from 0.59 to 0.89. The fluorescent activity of the sensor was monitored and the sensor was consequently applied for the detection of Cu2+ with high selectivity over various metal ions by fluorescence quenching in Tris-HCl (pH = 7.2) buffer/DMF (1:1, v/v) solution. From the binding stoichiometry, it was indicated that a 1:1 complex was formed between Cu2+ and the sensor 1. The fluorescence intensity was linear with Cu2+ in the concentration range 0.5–5 μM. Moreso, the detection limit was calculated to be 0.32 μM, which is sufficiently low for good sensitivity of Cu2+ ion. The binding mode was due to the intramolecular charge transfer (ICT) and the coordination of Cu2+ with C = N and hydroxyl oxygen groups of the sensor 1. The sensor proved effective for Cu2+ monitoring in real water samples with recovery rates of 95–112.6 % obtained.