Diffusion, Permeation and Solubility of Hydrogen in Copper

详细信息    查看全文

• 作者：Hans Magnusson ; Karin Frisk
• 关键词：diffusion ; hydrogen ; OFP ; copper ; permeation ; solubility ; thermodynamic assessment
• 刊名：Journal of Phase Equilibria and Diffusion
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：38
• 期：1
• 页码：65-69
• 全文大小：
• 刊物类别：Physics and Astronomy
• 刊物主题：Crystallography and Scattering Methods; Thermodynamics; Engineering Thermodynamics, Heat and Mass Transfer; Ceramics, Glass, Composites, Natural Materials; Metallic Materials;
• 出版者：Springer US
• ISSN：1863-7345
• 卷排序：38

文摘

The thermodynamic description for the Cu-H system has been updated. The solubility of hydrogen in copper at low temperature has been backwards calculated from permeability data. The solubility, diffusivity, and permeability of hydrogen in copper can be described by single Arrhenius expressions. These expressions are given below. The temperature dependence of both solubility and diffusivity will together yield a strong temperature dependency on the permeability. The possibility for hydrogen transport in copper is therefore limited at low temperature.$$\begin{aligned} & {\text{Diffusivity}}:D_{{{\text{H}},{\text{Cu}}}}^{\text{FCC}} = 1.74 \times 10^{ - 6} \exp \left( { - \frac{42000}{RT}} \right){\text{m}}^{2} /{\text{s}} \\ & {\text{Solubility}}:C_{{{\text{H}},{\text{Cu}}}}^{\text{FCC}} = 5.8 \times 10^{ - 3} \exp \left( { - \frac{48550}{RT}} \right) \\ & {\text{Permeability}}:P_{{{\text{H}},{\text{Cu}}}}^{\text{FCC}} = 4.5 \times 10^{ - 4} \exp \left( { - \frac{84320}{RT}} \right){\text{mole}}\,{\text{H}}_{2} /{\text{m}}\,{\text{s}}\,{\text{atm}}^{ - 0.5} \\ \end{aligned}$$KeywordsdiffusionhydrogenOFP-copperpermeationsolubilitythermodynamic assessmentReferences1.SKB, Corrosion Calculations Report for the Safety Assessment SR-Site, SKB TR-10-66, Svensk Kärnbränslehantering AB, Stockholm, Sweden. www.skb.se 2.T. Ishikawa and R.B. McLellan, The Diffusivity of Hydrogen in Copper at Low Temperatures, J. Phys. Chem. Solids, 1985, 46, p 445-447ADSCrossRefGoogle Scholar3.Y. Sakamoto and K. Takao, The Electrochemical Determination of Diffusivity and Solubility of Hydrogen in Copper, J. Jpn. I. Met., 1982, 46, p 285-290Google Scholar4.H. Magnusson and K. Frisk, Thermodynamic Evaluation of the Copper-Rich Part of the Cu-H-O-S-P System at Low Temperatures, CALPHAD, 2014, 47, p 148-160CrossRefGoogle Scholar5.G.R. Caskey, A.H. Dexter, M.L. Holzworth, M.R. Louthan, and R.G. Derrick, The Effect of Oxygen on Hydrogen Transport in Copper, Corrosion, 1976, 32, p 370-374CrossRefGoogle Scholar6.H. Horinouchi, M. Shinohara, T. Otsuka, K. Hashizume, and T. Tanabe, Determination of Hydrogen Diffusion and Permeation Coefficients in Pure Copper at Near Room Temperature by Means of Tritium Tracer Techniques, J. Alloy. Compd., 2013, 580, p S73-S75CrossRefGoogle Scholar7.W.G. Perkins and D.R. Begeal, Permeation and Diffusion of Hydrogen in ceramvar, copper and ceramvar-copper laminates, Ber. Bunsenges. Ph. Chem., 1972, 76, p 863Google Scholar8.D.B. Butrymowicz, J.R. Manning, and M.E. Read, Diffusion in Copper and Copper Alloys. Part III. Diffusion in Systems Involving Elements of the Groups IA, IIA, IIIB, IVB, VB, VIB, and VIIB, J. Phys. Chem. Ref. Data, 1975, 4, p 177-249ADSCrossRefGoogle Scholar9.W. Eichenauer, W. Löser, and H. Witte H, Löslichkeit und diffusiongeschwindigkeit von wasserstoff und deuterium in einkristallen aus nickel und kupfer. Z. Metallk., 1965, 56, p 287-293 (in German).10.W. Eichenauer and A. Pebler, Messung des diffusionskoeffizienten und der löslichkeit von wasserstoff in aluminium und kupfer, Z. Metallk., 1957, 48, p 373-378 (in German)Google Scholar11.L. Katz, M. Guinan, and R.J. Borg, Diffusion of H₂, D₂, and T₂ in Single-Crystal Ni and Cu, Phys. Rev. B, 1971, 4, p 330-341ADSCrossRefGoogle Scholar12.W. Huang, S.M. Opalka, D. Wang, and T.B. Flanagan, Thermodynamic Modelling of the Cu-Pd-H System, CALPHAD, 2007, 31, p 315-329CrossRefGoogle Scholar13.R.B. McLellan, Solid Solutions of Hydrogen in Gold, Silver and Copper, J. Phys. Chem. Solids, 1973, 34, p 1137-1141ADSCrossRefGoogle Scholar14.A.K. Sverchkova, L.A. Andreev, and Y.A. Minaev, Effect of Crystal Structure on the Solubility of Hydrogen in Copper, Met. Sci. Heat. Treat., 1989, 31, p 833-836ADSCrossRefGoogle Scholar15.P. Röntgen and F. Möller, The Solubility of Gases in Copper and Aluminum, Metallwirtschaft, 1934, 13, p 81-83Google Scholar16.K.H. Lieser and H. Witte, Löslichkeit von Wasserstoff in Legierungen IV. Diskussion der Ergebnisse, Z. Phys. Chem., 1954, 202, p 321-351 (in German)Google Scholar17.C.L. Thomas, Solubility of Hydrogen in Solid Copper, Silver, and Gold Obtained by a Rapid Quench and Extraction Technique, Trans. Am. Inst. Min. Metall. Pet. Eng., 1967, 239, p 485-496Google Scholar18.G.R. Caskey, A.H. Dexter, M.L. Holzworth, M.R. Louthan, and R.G. Derrick, The Effect of Oxygen on Hydrogen Transport in Copper, Corrosion, 1975, 32, p 370-374CrossRefGoogle Scholar19.J.K. Gorman and W.R. Nardella, Hydrogen Permeation Through Metals, Vacuum, 1962, 12, p 19-24CrossRefGoogle Scholar20.P.A. Korzhavyi and R. Sandström, Monovacancy in Copper: Trapping Efficiency for Hydrogen and Oxygen Impurities, Comp. Mater. Sci., 2014, 84, p 122-128CrossRefGoogle Scholar21.Å. Martinsson and R. Sandström, Hydrogen Depth Profile in Phosphorus-Doped, Oxygen-Free Copper After Cathodic Charging, J. Mater. Sci., 2012, 47, p 6768-6776ADSCrossRefGoogle ScholarCopyright information© ASM International 2017Authors and AffiliationsHans Magnusson1Email authorKarin Frisk11.Swerea KIMAB ABKistaSweden About this article CrossMark Publisher Name Springer US Print ISSN 1547-7037 Online ISSN 1863-7345 About this journal Reprints and Permissions Article actions .buybox { margin: 16px 0 0; position: relative; } .buybox { font-family: Source Sans Pro, Helvetica, Arial, sans-serif; font-size: 14px; font-size: .875rem; } .buybox { zoom: 1; } .buybox:after, .buybox:before { content: ''; display: table; } .buybox:after { clear: both; } /*---------------------------------*/ .buybox .buybox__header { border: 1px solid #b3b3b3; border-bottom: 0; padding: 8px 12px; position: relative; background-color: #f2f2f2; } .buybox__header .buybox__login { font-family: Source Sans Pro, Helvetica, Arial, sans-serif; font-size: 14px; font-size: .875rem; letter-spacing: .017em; display: inline-block; line-height: 1.2; padding: 0; } .buybox__header .buybox__login:before { position: absolute; top: 50%; -webkit-transform: perspective(1px) translateY(-50%); transform: perspective(1px) translateY(-50%); content: '\A'; width: 34px; height: 34px; left: 10px; } /*---------------------------------*/ .buybox .buybox__body { padding: 0; padding-bottom: 16px; position: relative; text-align: center; background-color: #fcfcfc; border: 1px solid #b3b3b3; } .buybox__body .buybox__section { padding: 16px 12px 0 12px; text-align: left; } .buybox__section .buybox__buttons { text-align: center; width: 100%; } /********** mycopy buybox specific **********/ .buybox.mycopy__buybox .buybox__section .buybox__buttons { border-top: 0; padding-top: 0; } /******/ .buybox__section:nth-child(2) .buybox__buttons { border-top: 1px solid #b3b3b3; padding-top: 20px; } .buybox__buttons .buybox__buy-button { display: inline-block; text-align: center; margin-bottom: 5px; padding: 6px 12px; } .buybox__buttons .buybox__price { white-space: nowrap; text-align: center; font-size: larger; padding-top: 6px; } .buybox__section .buybox__meta { letter-spacing: 0; padding-top: 12px; } .buybox__section .buybox__meta:only-of-type { padding-top: 0; position: relative; bottom: 6px; } /********** mycopy buybox specific **********/ .buybox.mycopy__buybox .buybox__section .buybox__meta { margin-top: 0; margin-bottom: 0; } /******/ .buybox__meta .buybox__product-title { display: inline; font-weight: bold; } .buybox__meta .buybox__list { line-height: 1.3; } .buybox__meta .buybox__list li { position: relative; padding-left: 1em; list-style: none; margin-bottom: 5px; } .buybox__meta .buybox__list li:before { font-size: 1em; content: '\2022'; float: left; position: relative; top: .1em; font-family: serif; font-weight: 600; text-align: center; line-height: inherit; color: #666; width: auto; margin-left: -1em; } .buybox__meta .buybox__list li:last-child { margin-bottom: 0; } /*---------------------------------*/ .buybox .buybox__footer { border: 1px solid #b3b3b3; border-top: 0; padding: 8px 12px; position: relative; border-style: dashed; } /*-----------------------------------------------------------------*/ @media screen and (min-width: 460px) and (max-width: 1074px) { .buybox__body .buybox__section { display: inline-block; vertical-align: top; padding: 12px 12px; padding-bottom: 0; text-align: left; width: 48%; } .buybox__body .buybox__section { padding-top: 16px; padding-left: 0; } .buybox__section:nth-of-type(2) .buybox__meta { border-left: 1px solid #d3d3d3; padding-left: 28px; } .buybox__section:nth-of-type(2) .buybox__buttons { border-top: 0; padding-top: 0; padding-left: 16px ; } .buybox__buttons .buybox__buy-button { } /********** article buybox specific **********/ .buybox.article__buybox .buybox__section:nth-of-type(2) { margin-top: 16px; padding-top: 0; } .buybox.article__buybox .buybox__section:nth-of-type(2) .buybox__meta { margin-top: 40px; padding-top: 0; padding-bottom: 45px; } .buybox.article__buybox .buybox__section:nth-of-type(2) .buybox__meta:only-of-type { margin-top: 8px; padding-top: 12px; padding-bottom: 12px; } /********** mycopy buybox specific **********/ .buybox.mycopy__buybox .buybox__section:first-child { width: 69%; } .buybox.mycopy__buybox .buybox__section:last-child { width: 29%; } /******/ } /*-----------------------------------------------------------------*/ @media screen and (max-width: 459px) { /********** mycopy buybox specific **********/ .buybox.mycopy__buybox .buybox__body { padding-bottom: 5px; } .buybox.mycopy__buybox .buybox__section:last-child { text-align: center; width: 100%; } .buybox.mycopy__buybox .buybox__buttons { display: inline-block; width: 150px ; } /******/ } /*-----------------------------------------------------------------*/ Log in to check access Buy (PDF) EUR 34,95 Unlimited access to the full article Instant download Include local sales tax if applicable Subscribe to Journal Get Access to Journal of Phase Equilibria and Diffusion for the whole of 2017 Find out about institutional subscriptions (function () { var forEach = function (array, callback, scope) { for (var i = 0; i Export citation .RIS Papers Reference Manager RefWorks Zotero .ENW EndNote .BIB BibTeX JabRef Mendeley Share article Email Facebook Twitter LinkedIn Cookies We use cookies to improve your experience with our site. More information Accept Over 10 million scientific documents at your fingertips