Kinetic and thermodynamic studies on adsorption of Cu²⁺, Pb²⁺, methylene blue and malachite green from aqueous solution using AMPS-modified hazelnut shell powder

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• 作者：Linlin Lü ; Xiaojun Jiang ; Lian Jia ; Tian Ai…
• 关键词：Hazelnut shell ; Kinetic ; Thermodynamic ; Adsorption ; Metal ion ; Dye
• 刊名：Chemical Research in Chinese Universities
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：33
• 期：1
• 页码：112-118
• 全文大小：
• 刊物主题：Chemistry/Food Science, general; Analytical Chemistry; Inorganic Chemistry; Organic Chemistry; Physical Chemistry;
• 出版者：Jilin University and The Editorial Department of Chemical Research in Chinese Universities
• ISSN：2210-3171
• 卷排序：33

文摘

A high-efficiency, low-cost and environment-friendly 2-acrylamide-2-methyl propane sulfonic acid (AMPS)-modified hazelnut-shell-based adsorbent(AHS) was synthesized and used to adsorb Cu2+, Pb2+, methylene blue(MB) and malachite green(MG) from aqueous solutions. The AHS was characterized by means of SEM, BET, FTIR and XPS. Different experimental parameters were evaluated in batch adsorption experiments to determine the optimal adsorption conditions. Adsorption kinetics shows that the adsorption rate is well represented by the pseudo- second-order rate model, and the Langmuir model gives the best fit adsorption isotherm. The Langmuir maximum adsorption capacities were found to be 21.14 mg/g for Cu2+, 32.74 mg/g for Pb2+, 68.03 mg/g for MB and 263.16 mg/g for MG, respectively, while the adsorption capacities could be maintained above 90% even after ten adsorp-tion-desorption cycles. The experimental results show that AHS could be applied to treat both industrial and munici-pal wastewaters.