Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path risk within an abandoned pesticide manufacturing plant

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• 作者：Sheng Huang ; Xin Zhao ; Yanqiu Sun ; Jianli Ma…
• 关键词：Industrial demolition wastes ; Heavy metals ; Pesticides ; Leaching characteristics ; Risk assessment ; Waste management
• 刊名：Frontiers of Environmental Science & Engineering
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：11
• 期：1
• 全文大小：
• 刊物主题：Environment, general;
• 出版者：Higher Education Press
• ISSN：2095-221X
• 卷排序：11

文摘

Exploration of heavy metals and organic pollutants, their leaching capacity along with health and environmental risks in contaminated industrial construction and demolition waste (ICDW) within a pesticide manufacturing plant were investigated. A maximum content of 90.8 mg•kg–1 Cd was found present in the wastes, which might originate from phosphorus rocks and industrial sulfuric acid used in pesticide production processes. An average concentration of 979.8 mg•kg–1 dichlorovos and other 11 organophosphorus pesticide were also detected. Relatively high leaching rates of around 4.14‰were obtained from laboratory simulated ICDW using both glacial acetic acid-sodium hydroxide and deionized water. Pesticide pollutants had the strongest tendency to retaining on dry bricks (leaching rate 1.68‰) compared to mortar-coatings, etc. due to their different physical characteristics and octanol-water partioning coefficient. Mobility of pesticide from on-site ICDW by water was spatially correlated to waste types, process sections and human activities, with a flux of leaching rate between 5.9‰ to 27.4%. Risk-based corrective action (RBCA) model was used to simulate the risk of contaminated ICDW debris randomly scattered. Oral and dermal ingestion amount by local workers was 9.8 × 10–3 and 1.9 × 10–2 mg•(kg•d)–1, respectively. Potential leaching risk to aquatic systems exceeded the limit for nearly 75% waste. Environmental and health risk exceedance was found in most ICDW, while the risk value of the most severely contaminated brick waste was 660 times beyond critical level. Implications for waste management involving construction and deconstruction work, waste transferring and regulation supplying were also provided.KeywordsIndustrial demolition wastesHeavy metalsPesticidesLeaching characteristicsRisk assessmentWaste managementReferences1.Jang Y C, Townsend T G. 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Pest Management Science, 2005, 61(12): 1168–1178CrossRefGoogle ScholarCopyright information© Higher Education Press and Springer-Verlag Berlin Heidelberg 2017Authors and AffiliationsSheng Huang1Xin Zhao2Yanqiu Sun1Jianli Ma3Xiaofeng Gao1Tian Xie1Dongsheng Xu4Yi Yu5Youcai Zhao1Email author1.The State Key Laboratory of Pollution Control and Resource ReuseTongji UniversityShanghaiChina2.Shanghai Chengpei Enterprise Management Consulting Co., Ltd.ShanghaiChina3.Tianjin Academy of Environmental SciencesTianjinChina4.Debin Environmental Protection and Technology Holding Co., Ltd.ShanghaiChina5.Shanghai Design Institute in Environmental Sanitary EngineeringShanghaiChina About this article CrossMark Publisher Name Higher Education Press Print ISSN 2095-2201 Online ISSN 2095-221X About this journal Reprints and Permissions Article actions .buybox { margin: 16px 0 0; position: relative; } .buybox { font-family: Source Sans Pro, Helvetica, Arial, sans-serif; font-size: 14px; font-size: .875rem; } .buybox { zoom: 1; 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