Pendant-Arm Macrocycles Derived from the Cyclocondensation Reaction of Sodium 2,6-Diformyl-4-substitutedphenolates and Tris-(2-aminoethyl)amine Derivatives. Preparation, Characterization and Propertie

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• 作者：Zeng ; Qingdao ; Gou ; Shaohua ; Zhu ; Jianglin ; Zhu ; Junjie ; You ; Xiaozeng
• 关键词：pendant ; arm macrocycles ; dinuclear macrocyclic copper(II) complexes ; sodium template ; Schiff base cyclocondensation
• 刊名：Journal of Inclusion Phenomena and Molecular Recognition inChemistry
• 出版年：1999
• 出版时间：1999
• 年：1999
• 卷：35
• 期：1/2
• 页码：299-309
• 全文大小：68 KB

文摘

A series of pendant-arm Schiff base macrocycles have been obtained via the cyclocondensation reaction between sodium 2,6-diformyl-4-substitutedphenolates and tris-(2-aminoethyl)- amine derivatives followed by transmetallation with Cu(ClO$\_4$)$\_2$·6H$\_2$O. The resulting dinuclear copper(II) complexes have been characterized by elemental analysis, infrared and mass spectra as well as magnetic moments at room temperature. All complexes have been electrochemically investigated, and two typical compounds have been studied with ESR spectra as well.