A Highly Sensitive Enzyme Catalytic Method for the Detection of Ethanol Based on Resonance Scattering Effect of Gold Particles

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• 作者：Yanghe Luo (1) (2)
  Pengfei Wang (1)
  Tingsheng Li (1)
  Jianniao Tian (1)
  Aihui Liang (1)
  Zhiliang Jiang (1)
  
• 关键词：Ethanol ; Gold particle ; Enzyme catalytic resonance scattering assay
• 刊名：Plasmonics
• 出版年：2013
• 出版时间：June 2013
• 年：2013
• 卷：8
• 期：2
• 页码：307-312
• 全文大小：271KB
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• 作者单位：Yanghe Luo (1) (2)
  Pengfei Wang (1)
  Tingsheng Li (1)
  Jianniao Tian (1)
  Aihui Liang (1)
  Zhiliang Jiang (1)
  
  1. Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection, Ministry of Education; Guangxi Key Laboratory of Environmental Engineering, Protection and Assessment, Guangxi Normal University, Guilin, 541004, China
  2. Province Key Construction Laboratory of Characteristic Resources Research and Development of East Guangxi, Hezhou University, Hezhou, 542800, China
  
• ISSN：1557-1963

文摘

In pH?8.4 Tris–HCl buffer solutions, alcohol dehydrogenase catalyzed the reaction between ethanol and nicotinamide adenine dinucleotide to produce acetaldehyde. In the medium of HCl, acetaldehyde reduced HAuCl4 to form gold particles that exhibited a strong resonance scattering (RS) peak at 600?nm. The RS peak increased with ethanol concentration. The increased RS intensity at 600?nm (ΔI 600?nm) was proportional to the ethanol concentration (C) from 0.068 to 10.2?mmol/L, with a regression equation of ΔI 600?nm--5.59-em class="a-plus-plus">C--6.1, and a detection limit (3σ) of 3.2?μmol/L. This proposed method was applied to detect ethanol in saliva and plant cell culture medium samples, with satisfactory results.