麦羟硅钠石/聚合物纳米复合材料研究进展
|
摘要
麦羟硅钠石(magadiite)是一种新型的层状纳米硅酸盐材料,由于其具有制备工艺简单、比表面积大、阳离子交换性能高、吸附性能强、层间膨胀性能好等优点,成为纳米材料提升聚合物性能最具有发展潜力的材料之一。本文主要综述了麦羟硅钠石/聚合物纳米复合材料的常用制备方法及其优缺点,包括聚合物插层法、单体原位插层聚合法、锚固插层聚合法。浅谈了国内外利用3种方法制备的基于聚苯乙烯、聚丙烯、环氧树脂、尼龙6、聚己内酯和聚甲基丙烯酸甲酯等多种聚合物的麦羟硅钠石/聚合物纳米复合材料,对在纳米复合材料结构中出现界面不相容、麦羟硅钠石分布不均匀的问题提出了解决方法,并阐述了麦羟硅钠石对纳米复合材料结构和性能的影响,最后展望了麦羟硅钠石/聚合物纳米复合材料的发展前景。
Magadiite is a new type of layered nano-silicate material, which has the advantages of large specific surface area, high cation exchange, strong adsorption and good inter-layer swelling performance.It has become one of the most promising potential for nano-material modified polymers. This article mainly summarized the common preparation methods of magadiite/polymer nanocomposites, including polymer intercalation, monomer in-situ intercalation polymerization and anchor intercalation polymerization. The magadiite/polymer nanocomposites prepared by three methods at home and abroad based on polystyrene, polypropylene, epoxy resin, nylon 6, polycaprolactone and polymethylmethacrylate were discussed. The solution to the incompatibility of the interface and the uneven distribution of magadiite in the nanocomposite structure was proposed, and the influence of magadiite on the structure and properties of the nanocomposite was explained. Finally, the outlook for the development of magadiite/polymer nanocomposites was presented.
Magadiite is a new type of layered nano-silicate material, which has the advantages of large specific surface area, high cation exchange, strong adsorption and good inter-layer swelling performance.It has become one of the most promising potential for nano-material modified polymers. This article mainly summarized the common preparation methods of magadiite/polymer nanocomposites, including polymer intercalation, monomer in-situ intercalation polymerization and anchor intercalation polymerization. The magadiite/polymer nanocomposites prepared by three methods at home and abroad based on polystyrene, polypropylene, epoxy resin, nylon 6, polycaprolactone and polymethylmethacrylate were discussed. The solution to the incompatibility of the interface and the uneven distribution of magadiite in the nanocomposite structure was proposed, and the influence of magadiite on the structure and properties of the nanocomposite was explained. Finally, the outlook for the development of magadiite/polymer nanocomposites was presented.
引文
[1]LIVI S,SAR G,BUGATTI V,et al.Synthesis and physical properties of new layered silicates based on ionic liquids:improvement of thermal stability,mechanical behaviour and water permeability of PBATnanocomposites[J].RSC Advances,2014,4(50):26452-26461.
[2]CHEN J,LI S,ZHONG J,et al.The effect of epoxidized natural rubber on mechanical properties of siliceous earth/natural rubber composites[J].Polymer Bulletin,2017,74(10):3955-3975.
[3]VULUGA Z,PANAITESCU D M,SANPOREAN C G,et al.The effect of polystyrene blocks content and of type of elastomer blocks on the properties of block copolymer/layered silicate nanocomposites[J].Journal of Alloys and Compounds,2014,616:569-576.
[4]GUO Y,HE S,YANG K,et al.Enhancing the mechanical properties of biodegradable polymer blends using tubular nanoparticle stitching of the interfaces[J].ACS Applied Materials&Interfaces,2016,8(27):17565-17573.
[5]RAMYA E,RAJASHREE C,NAYAK P L,et al.New hybrid organic polymer montmorillonite/chitosan/polyphenylenediamine composites for nonlinear optical studies[J].Applied Clay Science,2017,150:323-332.
[6]AL-QADHI M,MERAH N.Mechanical and physical properties of polymer-based nanocomposites containing different types of clay[J].Polymer Composites,2015,36(11):1998-2007.
[7]PRAMOD C V,UPENDAR K,MOHAN V,et al.Hydrotalcite-SBA-15 composite material for efficient carbondioxide capture[J].Journal of CO2Utilization,2015,12:109-115.
[8]ESSAWY H,BADRAN A,EL-HAKIM E F A,et al.Catalytic effect of various kaolinite forms on the emulsion polymerization of vinylacetate using acetone sodium bisulfite as initiator[J].Journal of Macromolecular Science:Part D,Reviews in Polymer Processing,2007,47(1):66-71.
[9]ELBOKL T A,DETELLIER C.Kaolinite-poly(methacrylamide)intercalated nanocomposite via in situ polymerization[J].Revue Canadienne De Chimie.,2009,87(1):272-279.
[10]YIN H,MA L,GAN M,et al.Preparation and properties of poly(2,3-dimethylaniline)/organic-kaolinite nanocomposites via in situ intercalative polymerization[J].Composites Science and Technology,2014,94:139-146.
[11]TALEBNEZHAD S,POURMAHDIAN S.Immobilization of alphadiimine nickel(Ⅱ)catalysts on multi-walled carbon nanotube for slurry ethylene polymerization[J].Colloid and Polymer Science,2015,293(3):721-733.
[12]CHATJAROENPORN K,BAKER R W,FITZGERALD P A,et al.Structure changes in micelles and adsorbed layers during surfactant polymerization[J].Journal of Colloid and Interface Science,2009,336(2):449-454.
[13]胡春联,陈元涛,张炜,等.磁性伊利石复合材料的制备及其对Co(Ⅱ)吸附性能的影响[J].化工进展,2014,33(9):2409-2414.HU C L,CHEN Y T,ZHANG W,et al.Preparation of magnetic illite composite and its sorption behavior for Co(Ⅱ)[J].Chemical Industry and Engineering Progress,2014,33(9):2409-2414.
[14]YANG L,MA X,GUO N,et al.Konjac glucomannan/poly(vinyl alcohol)/Na(+)rectorite nanocomposite films:structure,characteristic and drug delivery behaviour[J].Journal of Inorganic and Organometallic Polymers and Materials,2013,23(6):1459-1467.
[15]EUGSTER H P.Hydrous sodium silicates from lake magadi,kenya:precursors of bedded chert[J].Science,1967,157(3793):1177-1180.
[16]MAO Q,SILVIA S,HERBERT Z,et al.Molecular motion in surfactant layers inside polymer composites with synthetical magadiite[J].Macromolecular Chemistry&Physics,2010,208(19/20):2145-2160.
[17]HUANG Y N,JIANG Z M,SCHWIEGER W.Vibrational spectroscopic studies of layered silicates[J].Chemistry of Materials,1999,11(5):1210-1217.
[18]PENG S,GAO Q M,WANG Q G,et al.Layered structural heme protein magadiite nanocomposites with high enzyme-like peroxidase activity[J].Chemistry of Materials,2004,16(13):2675-2684.
[19]MAO Y,LI S,FANG R L,et al.Magadiite/styrene-butadiene rubber composites for tire tread applications:effects of varying layer spacing and alternate inorganic fillers[J].Journal of Applied Polymer Science,2017,134(18):44764.
[20]BOUKOUSSA B,ABIDALLAH F,ABID Z,et al.Synthesis of polypyrrole/Fe-kanemite nanocomposite through in situ polymerization:effect of iron exchange,acid treatment,and CO2adsorption properties[J].Journal of Materials Science,2017,52(5):2460-2472.
[21]SONG S,GAO Q,JIANG J,et al.A novel kind of porous carbon nitride using H-magadiite as the template[J].Materials Letters,2008,62(15):2520-2523.
[22]徐志扬,凌凤香,马波,等.天然层状硅酸盐黏土合成分子筛研究进展[J].化工进展,2007,26(11):1518-1524.XU Z Y,LING F X,MA B,et al.Advances in synthesis of molecular sieves with natural layered silicate[J].Chemical Industry and Engineering Progress,2007,26(11):1518-1524.
[23]PARK K,JUNG J H,SEO H,et al.Mesoporous silica-pillared kenyaite and magadiite as catalytic support for partial oxidation of methane[J].Microporous and Mesoporous Materials,2009,121(1/2/3):219-225.
[24]PARK K,SEO H J,KWON O.Mesoporous silica-pillared titanosilicate as catalytic support for partial oxidation of methane[J].Microporous and Mesoporous Materials,2014,195:191-196.
[25]KIM S J,KIM M H,SEO G,et al.Preparation of tantalum-pillared magadiite and its catalytic performance in Beckmann rearrangement[J].Research on Chemical Intermediates,2012,38(6):1181-1190.
[26]FUJITA I,KURODA K,OGAWA M.Adsorption of alcohols from aqueous solutions into a layered silicate modified with octyltrichlorosilane[J].Chemistry of Materials,2005,17(14):3717-3722.
[27]NUNES A R,MOURA A O,PRADO A G S.Calorimetric aspects of adsorption of pesticides 2,4-D,diuron and atrazine on a magadiite surface[J].Journal of Thermal Analysis and Calorimetry,2011,106(2):445-452.
[28]OKABE Y,OGAWA M.Photoinduced adsorption of spiropyran into mesoporous silicas as photomerocyanine[J].RSC Advances,2015,5(123):101789-101793.
[29]刘儒平,孔祥贵,岳钊,等.水滑石纳米材料特性及其在电化学生物传感器方面的应用[J].化工进展,2013,32(11):2661-2667.LIU R P,KONG X G,YUE Z,et al.Properties and application of layered double hydroxides for electrochemical biosensors[J].Chemical Industry and Engineering Progress,2013,32(11):2661-2667.
[30]NGO T D,TON-THAT M T,HOA S V,et al.Reinforcing effect of organoclay in rubbery and classy epoxy resins,part 1:dispersion and properties[J].Journal of Applied Polymer Science,2008,107(2):1154-1162.
[31]YUKUTAKE H,KOBAYASHI M,OTSUKA H,et al.Influence of magadiite dispersion states on the flammability of polystyrene and polyphenylene ether-polystyrene alloy nanocomposites[J].Polymer Journal,2010,42(3):223-231.
[32]SHAHABADI S I S,GARMABI H.Polyethylene/Na+-montmorillonite composites prepared by slurry-fed melt intercalation:response surface analysis of rheological behavior[J].Journal of Reinforced Plastics and Composites,2012,31(14):977-988.
[33]COSTACHE M C,HEIDECKER M J,MANIAS E,et al.Preparation and characterization of poly(ethylene terephthalate)/clay nanocomposites by melt blending using thermally stable surfactants[J].Polymers for Advanced Technologies,2006,17(9-10):764-771.
[34]BLAADEREN A V,KENTGENS A P M.Particle morphology and chemical microstructure of colloidal silica spheres made from alkoxysilanes[J].Journal of Non-Crystalline Solids,1992,149(3):161-178.
[35]ACHARYA H,SRIVASTAVA S K.EPDM/Silicone blend layered silicate nanocomposite by solution intercalation method:morphology and properties[J].Polymer Composites,2014,35(9):1834-1841.
[36]LI Y,REN P,ZHANG Q,et al.Properties of poly(lactic acid)/organomontmorillonite nanocomposites prepared by solution intercalation[J].Journal of Macromolecular Science Part B:Physics,2013,52(8):1041-1055.
[37]戈明亮,曹罗香,杜明艺,等.聚丙烯/有机磷盐改性麦羟硅钠石纳米复合材料的结构与性能[J].高分子材料科学与工程,2017(11):87-92.GE M L,CAO L X,DU M Y,et al.Structure and characterization of polypropyplene/organo-magadiite modified by alkyl phosphonium nanocomposites[J].Polymer Materials Science&Engineering,2017(11):87-92.
[38]戈明亮,朱彩萍,王雁武,等.有机季鏻盐改性纳米麦羟硅钠石/尼龙6复合材料的制备与性能[J].复合材料学报,2017(10):2134-2140.GE M L,ZHU C P,WANG Y W,et al.Preparation and properties of organic quaternary phosphonium salts modified nano-magadiite/nylon6 composites[J].Acta Materiae Compositae Sinica,2017(10):2134-2140.
[39]KARIM M R,YEUM J H.In situ intercalative polymerization of conducting polypyrrole/montmorillonite nanocomposites[J].Journal of Polymer Science Part B:Polymer Physics,2008,46(21):2279-2285.
[40]ZHEN W,PINNAVAIA T J.Hybrid organic-inorganic nanocomposites:exfoliation of magadiite nanolayers in an elastomeric epoxy polymer[J].Chemistry of Materials,1998,10(7):38-39.
[41]WANG D,JIANG D D,PABST J,et al.Polystyrene magadiite nanocomposites[J].Polymer Engineering&Science,2004,44(6):1122-1131.
[42]WANG D,WILKIE C A.In-situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites[J].Polymer Degradation&Stability,2003,80(1):171-182.
[43]戈明亮,池水莲.锚固型聚合物/蒙脱石纳米杂化材料的制备方法:CN 102504062A[P].2012-06-20.GE M L,CHI S L.Anchoring polymer/montmorillonite nano hybrid material preparation method:CN 102504062A[P].2012-06-20.
[44]LI C P,HUANG C M,HSIEH M T,et al.Properties of covalently bonded layered-silicate/polystyrene nanocomposites synthesized via atom transfer radical polymerization[J].Journal of Polymer Science Part A,Polymer Chemistry,2005,43(43):534-542.
[45]陈萌.层状硅酸盐的制备、改性及应用[D].广州:华南理工大学,2014.CHEN M.The preparation,modification and application of layered silicates[D].Guangzhou:South China University of Technology,2014.
[46]ISODA K,KURODA K,OGAWA M.Interlamellar grafting ofγ-methacryloxypropylsilyl groups on magadiite and copolymerization with methyl methacrylate[J].Chemistry of Materials,2000,12(6):1702-1707.
[47]LEPOITTEVIN B,PANTOUSTIER N,DEVALCKENAERE M,et al.Polymer/layered silicate nanocomposites by combined intercalative polymerization and melt intercalation:a masterbatch process[J].Polymer,2003,44(7):2033-2040.
[2]CHEN J,LI S,ZHONG J,et al.The effect of epoxidized natural rubber on mechanical properties of siliceous earth/natural rubber composites[J].Polymer Bulletin,2017,74(10):3955-3975.
[3]VULUGA Z,PANAITESCU D M,SANPOREAN C G,et al.The effect of polystyrene blocks content and of type of elastomer blocks on the properties of block copolymer/layered silicate nanocomposites[J].Journal of Alloys and Compounds,2014,616:569-576.
[4]GUO Y,HE S,YANG K,et al.Enhancing the mechanical properties of biodegradable polymer blends using tubular nanoparticle stitching of the interfaces[J].ACS Applied Materials&Interfaces,2016,8(27):17565-17573.
[5]RAMYA E,RAJASHREE C,NAYAK P L,et al.New hybrid organic polymer montmorillonite/chitosan/polyphenylenediamine composites for nonlinear optical studies[J].Applied Clay Science,2017,150:323-332.
[6]AL-QADHI M,MERAH N.Mechanical and physical properties of polymer-based nanocomposites containing different types of clay[J].Polymer Composites,2015,36(11):1998-2007.
[7]PRAMOD C V,UPENDAR K,MOHAN V,et al.Hydrotalcite-SBA-15 composite material for efficient carbondioxide capture[J].Journal of CO2Utilization,2015,12:109-115.
[8]ESSAWY H,BADRAN A,EL-HAKIM E F A,et al.Catalytic effect of various kaolinite forms on the emulsion polymerization of vinylacetate using acetone sodium bisulfite as initiator[J].Journal of Macromolecular Science:Part D,Reviews in Polymer Processing,2007,47(1):66-71.
[9]ELBOKL T A,DETELLIER C.Kaolinite-poly(methacrylamide)intercalated nanocomposite via in situ polymerization[J].Revue Canadienne De Chimie.,2009,87(1):272-279.
[10]YIN H,MA L,GAN M,et al.Preparation and properties of poly(2,3-dimethylaniline)/organic-kaolinite nanocomposites via in situ intercalative polymerization[J].Composites Science and Technology,2014,94:139-146.
[11]TALEBNEZHAD S,POURMAHDIAN S.Immobilization of alphadiimine nickel(Ⅱ)catalysts on multi-walled carbon nanotube for slurry ethylene polymerization[J].Colloid and Polymer Science,2015,293(3):721-733.
[12]CHATJAROENPORN K,BAKER R W,FITZGERALD P A,et al.Structure changes in micelles and adsorbed layers during surfactant polymerization[J].Journal of Colloid and Interface Science,2009,336(2):449-454.
[13]胡春联,陈元涛,张炜,等.磁性伊利石复合材料的制备及其对Co(Ⅱ)吸附性能的影响[J].化工进展,2014,33(9):2409-2414.HU C L,CHEN Y T,ZHANG W,et al.Preparation of magnetic illite composite and its sorption behavior for Co(Ⅱ)[J].Chemical Industry and Engineering Progress,2014,33(9):2409-2414.
[14]YANG L,MA X,GUO N,et al.Konjac glucomannan/poly(vinyl alcohol)/Na(+)rectorite nanocomposite films:structure,characteristic and drug delivery behaviour[J].Journal of Inorganic and Organometallic Polymers and Materials,2013,23(6):1459-1467.
[15]EUGSTER H P.Hydrous sodium silicates from lake magadi,kenya:precursors of bedded chert[J].Science,1967,157(3793):1177-1180.
[16]MAO Q,SILVIA S,HERBERT Z,et al.Molecular motion in surfactant layers inside polymer composites with synthetical magadiite[J].Macromolecular Chemistry&Physics,2010,208(19/20):2145-2160.
[17]HUANG Y N,JIANG Z M,SCHWIEGER W.Vibrational spectroscopic studies of layered silicates[J].Chemistry of Materials,1999,11(5):1210-1217.
[18]PENG S,GAO Q M,WANG Q G,et al.Layered structural heme protein magadiite nanocomposites with high enzyme-like peroxidase activity[J].Chemistry of Materials,2004,16(13):2675-2684.
[19]MAO Y,LI S,FANG R L,et al.Magadiite/styrene-butadiene rubber composites for tire tread applications:effects of varying layer spacing and alternate inorganic fillers[J].Journal of Applied Polymer Science,2017,134(18):44764.
[20]BOUKOUSSA B,ABIDALLAH F,ABID Z,et al.Synthesis of polypyrrole/Fe-kanemite nanocomposite through in situ polymerization:effect of iron exchange,acid treatment,and CO2adsorption properties[J].Journal of Materials Science,2017,52(5):2460-2472.
[21]SONG S,GAO Q,JIANG J,et al.A novel kind of porous carbon nitride using H-magadiite as the template[J].Materials Letters,2008,62(15):2520-2523.
[22]徐志扬,凌凤香,马波,等.天然层状硅酸盐黏土合成分子筛研究进展[J].化工进展,2007,26(11):1518-1524.XU Z Y,LING F X,MA B,et al.Advances in synthesis of molecular sieves with natural layered silicate[J].Chemical Industry and Engineering Progress,2007,26(11):1518-1524.
[23]PARK K,JUNG J H,SEO H,et al.Mesoporous silica-pillared kenyaite and magadiite as catalytic support for partial oxidation of methane[J].Microporous and Mesoporous Materials,2009,121(1/2/3):219-225.
[24]PARK K,SEO H J,KWON O.Mesoporous silica-pillared titanosilicate as catalytic support for partial oxidation of methane[J].Microporous and Mesoporous Materials,2014,195:191-196.
[25]KIM S J,KIM M H,SEO G,et al.Preparation of tantalum-pillared magadiite and its catalytic performance in Beckmann rearrangement[J].Research on Chemical Intermediates,2012,38(6):1181-1190.
[26]FUJITA I,KURODA K,OGAWA M.Adsorption of alcohols from aqueous solutions into a layered silicate modified with octyltrichlorosilane[J].Chemistry of Materials,2005,17(14):3717-3722.
[27]NUNES A R,MOURA A O,PRADO A G S.Calorimetric aspects of adsorption of pesticides 2,4-D,diuron and atrazine on a magadiite surface[J].Journal of Thermal Analysis and Calorimetry,2011,106(2):445-452.
[28]OKABE Y,OGAWA M.Photoinduced adsorption of spiropyran into mesoporous silicas as photomerocyanine[J].RSC Advances,2015,5(123):101789-101793.
[29]刘儒平,孔祥贵,岳钊,等.水滑石纳米材料特性及其在电化学生物传感器方面的应用[J].化工进展,2013,32(11):2661-2667.LIU R P,KONG X G,YUE Z,et al.Properties and application of layered double hydroxides for electrochemical biosensors[J].Chemical Industry and Engineering Progress,2013,32(11):2661-2667.
[30]NGO T D,TON-THAT M T,HOA S V,et al.Reinforcing effect of organoclay in rubbery and classy epoxy resins,part 1:dispersion and properties[J].Journal of Applied Polymer Science,2008,107(2):1154-1162.
[31]YUKUTAKE H,KOBAYASHI M,OTSUKA H,et al.Influence of magadiite dispersion states on the flammability of polystyrene and polyphenylene ether-polystyrene alloy nanocomposites[J].Polymer Journal,2010,42(3):223-231.
[32]SHAHABADI S I S,GARMABI H.Polyethylene/Na+-montmorillonite composites prepared by slurry-fed melt intercalation:response surface analysis of rheological behavior[J].Journal of Reinforced Plastics and Composites,2012,31(14):977-988.
[33]COSTACHE M C,HEIDECKER M J,MANIAS E,et al.Preparation and characterization of poly(ethylene terephthalate)/clay nanocomposites by melt blending using thermally stable surfactants[J].Polymers for Advanced Technologies,2006,17(9-10):764-771.
[34]BLAADEREN A V,KENTGENS A P M.Particle morphology and chemical microstructure of colloidal silica spheres made from alkoxysilanes[J].Journal of Non-Crystalline Solids,1992,149(3):161-178.
[35]ACHARYA H,SRIVASTAVA S K.EPDM/Silicone blend layered silicate nanocomposite by solution intercalation method:morphology and properties[J].Polymer Composites,2014,35(9):1834-1841.
[36]LI Y,REN P,ZHANG Q,et al.Properties of poly(lactic acid)/organomontmorillonite nanocomposites prepared by solution intercalation[J].Journal of Macromolecular Science Part B:Physics,2013,52(8):1041-1055.
[37]戈明亮,曹罗香,杜明艺,等.聚丙烯/有机磷盐改性麦羟硅钠石纳米复合材料的结构与性能[J].高分子材料科学与工程,2017(11):87-92.GE M L,CAO L X,DU M Y,et al.Structure and characterization of polypropyplene/organo-magadiite modified by alkyl phosphonium nanocomposites[J].Polymer Materials Science&Engineering,2017(11):87-92.
[38]戈明亮,朱彩萍,王雁武,等.有机季鏻盐改性纳米麦羟硅钠石/尼龙6复合材料的制备与性能[J].复合材料学报,2017(10):2134-2140.GE M L,ZHU C P,WANG Y W,et al.Preparation and properties of organic quaternary phosphonium salts modified nano-magadiite/nylon6 composites[J].Acta Materiae Compositae Sinica,2017(10):2134-2140.
[39]KARIM M R,YEUM J H.In situ intercalative polymerization of conducting polypyrrole/montmorillonite nanocomposites[J].Journal of Polymer Science Part B:Polymer Physics,2008,46(21):2279-2285.
[40]ZHEN W,PINNAVAIA T J.Hybrid organic-inorganic nanocomposites:exfoliation of magadiite nanolayers in an elastomeric epoxy polymer[J].Chemistry of Materials,1998,10(7):38-39.
[41]WANG D,JIANG D D,PABST J,et al.Polystyrene magadiite nanocomposites[J].Polymer Engineering&Science,2004,44(6):1122-1131.
[42]WANG D,WILKIE C A.In-situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites[J].Polymer Degradation&Stability,2003,80(1):171-182.
[43]戈明亮,池水莲.锚固型聚合物/蒙脱石纳米杂化材料的制备方法:CN 102504062A[P].2012-06-20.GE M L,CHI S L.Anchoring polymer/montmorillonite nano hybrid material preparation method:CN 102504062A[P].2012-06-20.
[44]LI C P,HUANG C M,HSIEH M T,et al.Properties of covalently bonded layered-silicate/polystyrene nanocomposites synthesized via atom transfer radical polymerization[J].Journal of Polymer Science Part A,Polymer Chemistry,2005,43(43):534-542.
[45]陈萌.层状硅酸盐的制备、改性及应用[D].广州:华南理工大学,2014.CHEN M.The preparation,modification and application of layered silicates[D].Guangzhou:South China University of Technology,2014.
[46]ISODA K,KURODA K,OGAWA M.Interlamellar grafting ofγ-methacryloxypropylsilyl groups on magadiite and copolymerization with methyl methacrylate[J].Chemistry of Materials,2000,12(6):1702-1707.
[47]LEPOITTEVIN B,PANTOUSTIER N,DEVALCKENAERE M,et al.Polymer/layered silicate nanocomposites by combined intercalative polymerization and melt intercalation:a masterbatch process[J].Polymer,2003,44(7):2033-2040.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |