聚丙烯/茂金属催化乙烯—丙烯共聚物相结构的演变与性能
|
摘要
采用密炼机制备了不同组成的聚丙烯/茂金属催化乙烯-丙烯共聚物(PP/mEPE)共混体系,用扫描电子显微镜(SEM)、小角激光散射(SALS)、相差显微镜(PCM)及SEM傅立叶变换研究共混体系共混过程中的相结构的形成及演变规律。运用粒径理论讨论了该共混体系扫描电子显微镜图样,采用对数正态分布的图估计理论证明分散相粒径的分布符合正态分布,进而求取了用以表征尺寸分布宽度的参数σ。根据Debye-Bueche光散射理论,利用光散射图像处理软件,得出表征合金体系相结构的结构参数:旋转半径Rg、分散相相关距离ac 2、平均弦长l、积分不变量Q、光强平面积分Js、分散相比表面积Ssp和不均匀性距离lc等。分析讨论了各个结构参数随混炼时间,共混组成,混炼温度,混炼的剪切速率的变化规律;并对体系的相关距离ac进行了模拟。采用傅立叶变换技术将空域范围内的相差显微镜及扫描电子显微镜图样转化到视频域内的傅立叶变化图样;并根据光散射理论分析了共混体系的平均弦长l1及分形维数Dc与共混物组成、共混时间、混炼温度、混炼的剪切速率的关系。结果表明,共混过程中相态变化主要发生在共混初期,后期处于颗粒破裂和聚结的动态平衡中;转速条件和温度条件会影响到平衡时分散相颗粒尺寸的大小,存在最佳转速和最佳温度;颗粒尺寸随着分散相含量的增加而增大。四种方法的研究结果是一致的,说明这四种方法均可以用来研究PP/mEPE共混体系的相结构的形成及演变规律。
在研究了PP/mEPE共混体系的结构与形态的基础上,研究了体系的基本性能。用差示扫描量热仪(DSC)研究了mEPE与PP/mEPE的结晶性能。茂金属乙烯-丙烯共聚物是聚丙烯和乙烯的半结晶聚合物,具有等规立构化特性。具有两个结晶温度,其一为PP嵌段的结晶,另一为PE段的结晶。PP/mEPE共混体系中PP的结晶度随PP含量的增大而降低。用平板式旋转流变仪研究了mEPE与PP/mEPE的流变特性。用Han曲线研究表明,温度低于160℃,mEPE出现结晶相。PP/mEPE体系中,随着mEPE含量的增高,在不同温度下测得的曲线没有完全重合,表明共混体系的微结构在一定程度上依赖于实验测量的温度,共混体系出现部分相分离。用动态热机械分析仪(DMA)研究了PP/mEPE共混体系的动态力学性能。研究结果表明:PP与mEPE的Tg内移,说明PP与mEPE具有一定的相容性。总之,PP/mEPE共混体系是具有一定相容性的微相分离体系。
Polypropylene/ metallocene-ethylene propylene elastomer blends were prepared in a XXS-30 mixer and scanning electron microscope (SEM), small angle laser scattering (SALS), phase contrast microscope (PCM) and Fourier transformation were employed to describe the phase evolution and morphology development during the mixing. For SEM, particle diameter was calculated and further, a graph-estimation method was introduced to confirm the distribution of particle diameter to obey a log-normal distribution and subsequently, an effective structure parameter,σ, was computed to discuss the distribution width of particle size. For laser scattering, different parameters, e.g., gyration radius, correlation distance,mean chord length,integral constant and so on, were calculated based on Debye-Bueche scattering theory. Besides, effect of mixing time, blends composition, mixing temperature and rotor speed on each structure parameter was also investigated and the correlation distance of the blends, ac2, was studied by means of a mathematic model. For PCM and SEM images in Doi space, which correspond with light scattering images, were obtained by applying Fourier transformation to PCM and SEM images and then, corresponding scattering theory was apply to these Doi images to computed mean chord length l1 and fractal dimension Dc and discuss their dependence on blend composition, mixing time, mixing temperature and rotor speed. These results showed that, the change mainly occurs in the initial stage of the mixing and levers off due to the dynamic equilibrium between the breakup and coalescence of particles. The particle size is influenced by rotor speed and mixing temperature and there exists an optimal rotor speed and mixing temperature at which the phase morphology was more fine. Results by different methods were similar, showing that these methods were all effective to study the morphology development of PP/mEPE blends during the mixing.
Besides the structure and morphology of PP/mEPE blends, the thermal property, rheological and dynamic mechanical property were also studied using different scanning calorimeter, rheometer and dynamic mechanical analyzer, respectively. The results showed that, the mEPE is a semi-crystalline copolymer of propylene and ethylene, which have two crystalline temperatures: one is of PP segment and the other is of PE segment. The crystallnity of PP/mEPE decreased with the content of PP. The result of rheology property by plate-plate rotating rheometer indicated that, with Han curve,the results showed that there is crystallization phase in mEPE below 160℃. The curves with different composition in PP/mEPE blends are not entirely coincidence, which notes that the blends microstructure dependents on experimental temperature, PP/mEPE is to some extend phase separation blends. The result of DMA showed that the glass temperature of PP approaches to that of mEPE, indicating that PP/mEPE is a part-compatible blend system, so, PP/mEPE is a part-compatible and some phase separation blend system.
在研究了PP/mEPE共混体系的结构与形态的基础上,研究了体系的基本性能。用差示扫描量热仪(DSC)研究了mEPE与PP/mEPE的结晶性能。茂金属乙烯-丙烯共聚物是聚丙烯和乙烯的半结晶聚合物,具有等规立构化特性。具有两个结晶温度,其一为PP嵌段的结晶,另一为PE段的结晶。PP/mEPE共混体系中PP的结晶度随PP含量的增大而降低。用平板式旋转流变仪研究了mEPE与PP/mEPE的流变特性。用Han曲线研究表明,温度低于160℃,mEPE出现结晶相。PP/mEPE体系中,随着mEPE含量的增高,在不同温度下测得的曲线没有完全重合,表明共混体系的微结构在一定程度上依赖于实验测量的温度,共混体系出现部分相分离。用动态热机械分析仪(DMA)研究了PP/mEPE共混体系的动态力学性能。研究结果表明:PP与mEPE的Tg内移,说明PP与mEPE具有一定的相容性。总之,PP/mEPE共混体系是具有一定相容性的微相分离体系。
Polypropylene/ metallocene-ethylene propylene elastomer blends were prepared in a XXS-30 mixer and scanning electron microscope (SEM), small angle laser scattering (SALS), phase contrast microscope (PCM) and Fourier transformation were employed to describe the phase evolution and morphology development during the mixing. For SEM, particle diameter was calculated and further, a graph-estimation method was introduced to confirm the distribution of particle diameter to obey a log-normal distribution and subsequently, an effective structure parameter,σ, was computed to discuss the distribution width of particle size. For laser scattering, different parameters, e.g., gyration radius, correlation distance,mean chord length,integral constant and so on, were calculated based on Debye-Bueche scattering theory. Besides, effect of mixing time, blends composition, mixing temperature and rotor speed on each structure parameter was also investigated and the correlation distance of the blends, ac2, was studied by means of a mathematic model. For PCM and SEM images in Doi space, which correspond with light scattering images, were obtained by applying Fourier transformation to PCM and SEM images and then, corresponding scattering theory was apply to these Doi images to computed mean chord length l1 and fractal dimension Dc and discuss their dependence on blend composition, mixing time, mixing temperature and rotor speed. These results showed that, the change mainly occurs in the initial stage of the mixing and levers off due to the dynamic equilibrium between the breakup and coalescence of particles. The particle size is influenced by rotor speed and mixing temperature and there exists an optimal rotor speed and mixing temperature at which the phase morphology was more fine. Results by different methods were similar, showing that these methods were all effective to study the morphology development of PP/mEPE blends during the mixing.
Besides the structure and morphology of PP/mEPE blends, the thermal property, rheological and dynamic mechanical property were also studied using different scanning calorimeter, rheometer and dynamic mechanical analyzer, respectively. The results showed that, the mEPE is a semi-crystalline copolymer of propylene and ethylene, which have two crystalline temperatures: one is of PP segment and the other is of PE segment. The crystallnity of PP/mEPE decreased with the content of PP. The result of rheology property by plate-plate rotating rheometer indicated that, with Han curve,the results showed that there is crystallization phase in mEPE below 160℃. The curves with different composition in PP/mEPE blends are not entirely coincidence, which notes that the blends microstructure dependents on experimental temperature, PP/mEPE is to some extend phase separation blends. The result of DMA showed that the glass temperature of PP approaches to that of mEPE, indicating that PP/mEPE is a part-compatible blend system, so, PP/mEPE is a part-compatible and some phase separation blend system.
引文
[1]Dayananda K, Pi BS, Kim BS, et al, Synthesis and characterization of pH/temperature-sensitive block copolymers via atom transfer radical polymerization, Polymer, 2007, 48 (3): 758-762
[2]Castelvetro V, Geppi M, Giaiacopi S, et al, Cotton fibers encapsulated with homo- and block copolymers: Synthesis by the atom transfer radical polymerization grafting-from technique and solid-state NMR dynamic investigations, Biomacromolecules, 2007, 8(2): 498-508
[3]Brar AS, Saini T, Atom transfer radical polymerization of 2-methoxy ethyl acrylate and its block copolymerization with acrylonitrile, European Polymer Journal, 2007, 43(3): 1046-1054
[4]Tasdelen MA, Yagci Y, Demirel AL, et al, Synthesis and characterization of block-graft copolymers [poly(epichlorohydrin-b-styrene)-g-poly(methyl methacrylate)] by combination of activated monomer polymerization, NMP and ATRP, Polymer Bulletin, 2007, 58(4): 653-663
[5] Yun SI, Briber RM, Kee RA, et al, Dilute-solution structure of charged arborescent graft polymer, Polymer, 2006, 47 (8): 2750-2759
[6]Unger F, Wittmar M, Kissel T, Branched polyesters based on poly[vinyl-3-(dialkylamino)alkylcarbamate-co-vinyl acetate-co-vinyl alcohol]-graft-poly(D,L-lactide-co-glycolide): Effects of polymer structure on cytotoxicity, Biomaterials 2007, 28 (9): 1610-1619
[7]Woo KM, Seo J, Zhang RY, et al, Suppression of apoptosis by enhanced protein adsorption on polymer/hydroxyapatite composite scaffolds, Biomacromolecules, 2007, 28 (16): 2622-2630
[8]Mertiny P, Gold A, Quantification of leakage damage in high-pressure fibre-reinforced polymer composite tubular vessels, Polymer Testing, 2007, 26 (2): 172-179
[9]Mohanty S, Verma SK, Nayak SK, Rheological characternization of PP/jute composite melts, Journal of Applied Polymer Science, 2006, 99 (4): 1476-1484
[10]Hoshi T, Sawaguchi T, Konno T, et al, Preparation of molecular dispersed polymer blend composed of polyethylene and poly(vinyl acetate) by in situ polymerization of vinyl acetate using supercritical carbon dioxide, Polymer, 2007, 48 (6): 1573-1580
[11]Kaito A, Iwakura Y, Hatakeyama K, et al, Organization of oriented lamellar structures in a miscible crystalline/crystalline polymer blend under uniaxial compression flow near the melting temperature , Macromolecules 2007, 40 (8): 2751-2759
[12]Kumar ES, Das CK, Banik K, et al, Viscoelastic properties of in situ composite based on ethylene acrylic elastomer (AEM) and liquid crystalline polymer (LCP) blend, Polymer, 2007, 48 (6): 1573-1580
[13]Darras V, Fichet O, Perrot F, et al, Polysiloxane-poly(fluorinated acrylate) interpenetrating polymer networks: Synthesis and characterization, Polymer, 2007, 48 (3): 687-695
[14]Huang YJ, Hsieh TH, Wang YZ, et al, Effect of nonconjugated polymers on the conjugation length and structure of poly(3-octylthiophene) in ternary polymer blend, Journal of Applied Polymer Science, 2007, 104 (2): 773-781
[15]Kim SY, Kim SH, Kim JY, et al, Novel CO2 laser drawing of thermotropic liquid crystal polymer and poly(ethylene 2,6-naphthalate) blend fibers, Journal of Applied Polymer Science, 2007, 104 (1): 205-211
[16]Ruegg ML, Reynolds BJ, Lin MY, et al, Effect of pressure on a multicomponent A/B/A-C polymer blend with attractive and repulsive interactions, Macromolecules, 2007, 40 (2): 355-365
[17]Morales G, de Leon RD, Acuna P, et al, Improved toughness in HIPS obtained from different styrene/butadiene-graded block copolymers through modification of the polydispersity index of the PS block, Polymer Engineering and Science, 2006, 46 (10): 1333-1341
[18]Souza FG, Soares BG, Siddaramaiah, et al, Influence of plasticizers (DOP and CNSL) on mechanical and electrical properties of SBS/polyaniline blends, Polymer, 47 (21): 7548-7553
[19]Dikobe DG, Luyt AS, Effect of poly(ethylene-co-glycidyl methacrylate) compatibilizer content on the morphology and physical properties of ethylene vinyl acetate-wood fiber composites, Journal of Applied Polymer Science, 2007, 104 (5): 3206-3213
[20]Guduri BR, Luyt AS, Effect of ethylene glycidyl methacrylate compatibilizer on the structure and mechanical properties of clay nanocomposites modified with ethylene vinyl acetate copolymer, Journal of Applied Polymer Science, 2007, 103 (6): 4095-4101
[21]Filippone G, Netti PA, Acierno D, Microstructural evolutions of LDPE/PA6 blends by rheological and rheo-optical analyses: Influence of flow and compatibilizer on break-up and coalescence processes, Polymer, 2007,48 (2): 564-573
[22]Soares BG, Almeida MSM, Urs MVD, et al, Influence of curing agent and compatibilizer on the physicomechanical properties of polypropylene/nitrile butadiene rubber blends investigated by positron annihilation lifetime technique, Journal of Applied Polymer Science, 2006, 102 (5): 4672-4681
[23]Kim DW, Park KW, Chowdhury SR, et al, Effect of compatibilizer and silane coupling agent on physical properties of ethylene vinyl acetate copolymer/ethylene-1-butene copolymer/clay nanocomposite foams, Journal of Applied Polymer Science, 2006, 102 (4): 3259-3265
[24]Taepaiboon P, Junkasem J, Dangtungee R, et al, In situ microfibrillar-reinforced composites of isotactic polypropylene/recycled poly(ethylene terephthalate) system and effect of compatibilizer, Journal of Applied Polymer Science, 2006, 102 (2): 1173-1181
[25]Schreiber HP, Olguin A, Aspects of dispersion and flow in thermoplastic-elastomer blends, Polymer Engineering and Science, 1983, 23:129-134
[26]Plochcki AP, Dagli SS, Andrews RD. The interface in binary mixtures of polymers containing corresponding block copolymer: effects of industrial mixing processes and of coalescence, Polymer Engineering and Science, 1990, 30: 741-752
[27]Scott CE, Macosko, CW, Morphology development during reactive and nonreactive blending of an ethylene-propylene rubber with two thermoplastic matrices, Polymer, 1994, 35: 5422
[28]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blending, Polymer, 1995, 36, 461 ]29]Isayev AI, Wang CM, Zeng X, Effect of oscillations during extrusion on rheology and mechanical properties of polymers, Advance in Polymer Technology, 1990, 10(1): 31
[30]Karger-Koscis J, Kallo A, Kuleznev VN, Phase structure of impact-modified polypropylene blends, Polymer, 1984, 25, 279
[31]Favis BD, The effect of processing parameters on the morphology of an immiscible binary blend, Journal of Applied Polymer Science, 1990, 39, 285-300
[32]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blending, Polymer Bulletin 1991, 26: 341-348
[33]Sundaraj U, Macosko CW, Nakayama A, Inoue T, Milligrams to kilograms: an evaluation of mixers for reactive polymer blending, Polymer Engineering and Science, 1995, 35(1), 100-114
[34]Lindt JT, Ghosh AK, Fluid mechanics of the formation of polymer blends. I: formation of lamellar structures, Polymer Engineering and Science, 1992, 32, 1802-1810
[35]Elemans PHM, Bos HL, Janssen JMH, Transient phenomena in dispersive mixing. Chemical Engineering Science, 1993, 48(2):267-276 36. Sundararaj U, Macosko CW, Drop breakup and coalescence in polymer blends- the effects of concentration and compatibilization, Macromolecules, 1995, 28, 2647-2652
[37]Kim JK, Lee SH, Paglicawan MA, et al, Effects of extruder parameters and compositions on mechanical properties and morphology of maleic anhydride grafted polypropylene/waste tire blends , Polymer-Plastics Technology and Engineering 2007, 46 (1): 19-29
[38]Endoh MK, Takenaka M, Hashimoto T, Effects of shear flow on a semidilute polymer solution under phase-separating condition, Polymer, 2006, 47 (20): 7271-7281
[39]Du ML, Guo BC, Jia DM, Effects of thermal and UV-induced grafting of bismaleimide on mechanical performance of reclaimed rubber/natural rubber blends, Journal of Polymer Research, 2005, 12 (6): 473-482
[40]Kim JW, Yoo JE, Kim CK, Phase behavior of ternary blends containing dimethylpolycarbonate, tetramethylpolycarbonate and poly[styrene-co-(methyl methacrylate)] copolymers (or polystyrene), Polymer International, 2005, 54 (1): 130-136
[41]Yang XD, Zhu YT, Jiang W, Online study of the formation of PA6 droplets in PP matrix under shear flow, Journal of Applied Polymer Science, 2007, 104 (4): 2690-2695
[42]Melo TJA, Canevarolo SV, In-line optical detection in the transient state of extrusion polymer blending and reactive processing, Polymer Engineering and Science, 2005 44 (1): 11-19
[43]He XJ, Cox CL, Ellison MS, Simulation of TLCP deformation during isothermal melt spinning of in situ composite fibers, Journal of Macromolecular Science-Physiscs, 2004, 43 (2): 309-328
[44]Coates PD, Barnes SE, Sibley MG, et al, In-process vibrational spectroscopy and ultrasound measurements in polymer melt extrusion, Polymer, 2003, 44 (19): 5937-5949
[45]Schlatter G, Serra C, Bouquey M, et al, Online light scattering measurements: A method to assess morphology development of polymer blends in a twin-screw extruder, Polymer Engineering and Science, 2002, 42 (10): 1965-1975
[46]Pal K, Rastogi JN, Development of halogen-free flame-retardant thermoplastic elastomer polymer blend, Journal of Applied Polymer Science, 2004, 94 (2): 407-415
[47]Favis BD, Effect of processing parameters on the morphology of an immiscible binary blend, Journal of Applied Polymer Science, 1990, 39 (2):285–300.
[48]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blends, Polymer, 1995, 36 (3):461–470.
[49]Scott CE, Macosko CW, Model experiments concerning morphology development during the initial stages of polymer blending, Polymer Bulletin, 1991, 26 (3): 341–348.
[50]Sundararaj U, Macosko CW, Rolando RJ, Chan HT, Morphology development in polymer blends, Polymer Engineering and Science, 1992, 32 (24): 1814–1823.
[51]Lindt JT, Ghosh AK, Fluid mechanics of the formation of polymer blends. Part: Q1 Formation of lamellar structures, Polymer Engineering and Science, 1992, 32 (24): 1802–1813.
[52]Yu L, Dean K, Li L, Polymer blends and composites from renewable resources, Progress in Polymer Science, 2006, 31 (6): 576-602
[53]Goossens S, Groeninckx G, Mutual influence between reaction-induced phase separation and isothermal crystallization in POM/epoxy resin blends, Macromolecular, 2006, 39 (23): 8049-8059
[54]Ruegg ML, Newstein MC, Balsara NP, et al, Small-angle neutron scattering from nonuniformly labeled block copolymers, Macromolecular, 2004, 37 (5): 1960-1968
[55]Peng M, Li DS, Chen Y, et al, Effect of an organoclay on the reaction-induced phase-separation kinetics and morphology of a poly(ether imide)/epoxy mixture, Journal of Applied Polymer Science, 2007,104 (2): 1205-1214
[56]Merfeld GD, Paul DR, Light scattering characterization of tetramethyl polycarbonate blends with polystyrene and with styrene-pentabromobenzyl acrylate copolymers Polymer, 2000,41 (2): 649-661
[57]Barnes MD, Ng KC, Fukui K, et al, Probing phase-separation behavior in polymer-blend microparticles: Effects of particle size and polymer mobility, Macromolecular, 1999, 32 (21): 7183-7189
[58]Yurekli K, Karim A, Amis EJ, et al, Phase behavior of PS-PVME nanocomposites, Macromolecular, 2004,37 (2): 507-515
[59]Takeji Hashimoto et al., J.Chem.Phys., 1986, 8(2), 123
[60]Chi-Kai Shih, Mixing and morphological transformations in the compoundign process for polymer blends: the phase for polymer inversion mechanism, Polymer Engineering and Science, 1995, 35:1688-1692
[61]Plivelic TS, Cassu SN, Goncalves MD, et al, Structure and morphology of poly(epsilon-caprolactone)/chlorinated polyethylene (PCL/PECl) blends investigated by DSC, simultaneous SAXS/WAXD, and elemental mapping by ESI-TEM, Macromolecular, 2007, 40 (2): 253-264
[62]Gemeinhardt GC, Moore RB, Characterization of ionomer-compatibilized blend morphology using synchrotron small-angle X-ray scattering, Macromolecular, 2005, 38 (7): 2813-2819
[63]Madbouly SA, Wolf BA, Shear-induced crystallization and shear-induced dissolution of poly(ethylene oxide) in mixtures with tetrahydronaphthalene and oligo(dimethyl siloxane-b-ethylene oxide), Macromolecular Chemistry and Physics 2003, 204 (3): 417-424
[64]马桂秋,原续波, 盛京,小角 X 光散射法研究聚丙烯/乙丙橡胶合金的相结构,高分子学报,2002,(1):63-67
[65]张丁浩,盛京,沈宁祥, 光散射在聚合物共混过程中形态发展研究的应用,光散射学报,2003,(2):79-100
[66]陈云,盛京,沈宁祥,等, 小角光散射在线系统研究多相聚合物双螺杆挤出过程中的相尺寸-非相容 PE/PA1010 体系, 高分子学报, 2004, (2): 282-287
[67]Macosko CW, Philippe AKK, Akinari N,| Philippe M, Takashi I, Compatibilizers for Melt Blending: remade Block Copolymers, Macromolecules, 1996, 29: 5590-5601
[68]Li YY, Chen ZQ, Huang Y, et al, Morphology development in polypropylene/polystyrene blends during coalescence under shear, Journal of Applied Polymer Science, 2007, 104 (1): 666-671
[69]Li YY, Wang Y, Li WQ, et al, Compatibilization of styrene-butadiene-styrene block copolymer in polypropylene/polystyrene blends by analysis of phase morphology, Journal of Applied Polymer Science, 2007, 103 (1): 365-370
[70]Yang YP, Li WQ, Xiao ZG, et al, Study on the mechanism of the formation and evolution of phase structure in PP/PcBR blends, Journal of Macromolecular Science-Physics, 2006, 45 (6): 1039-1052
[71]Yang YP, Xiao ZG, Jiang X, et al, Light scattering studies on phase behavior of PP/PcBR blends during melt-mixing, Journal of Macromolecular Science-Physics, 200645 (6): 1083-1098
[72]Ma GQ, Zhao YH, Yan LT, et al, Blends of polypropylene with poly(cis-butadiene) rubber: III. Study on the phase structure and morphology of incompatible blends of polypropylene with poly(cis-butadiene) rubber, Journal of Applied Polymer Science, 2006,100 (6): 4900-4909
[73]Li YY, Han YP, Zhao YH, Study on phase formation and evolution of high impact polystyrene with poly(cis-butadiene) rubber blends, Journal of Macromolecular Science-Physics, 2005, 44 (5): 651-664
[74]Chand N, Naik AM, Khaira HK, Development of UHMWPE modified PP/PET blends and their mechanical and abrasive wear behavior, Polymer Composites, 2007, 28 (2): 267-272
[75]Diaz IF, Barbosa SE, Capiati NJ, Addition compatibilization of PP/PS blends by Tailor-made copolymers, Polymer Engineering and Science 2006, 46 (3): 329-336
[76]Cidade MT, Filipe S, Duarte AP, et al, Synthesis of compatibilizers and characterization of the compatibilized and noncompatibilized blends of PP/Rodrun LC3000, Journal of Applied Polymer Science, 2007, 104 (5): 3001-3009
[77]Albano C, Gonzalez J, Ichazo M, et al, Thermal stability of PP with acetylated sisal fiber: Romero Garcia kinetic method, Polymer Bulletin, 2003, 51 (3): 245-254
[78]Jose S, Nair SV, Thomas S, et al, Effect of reactive compatibilisation on the phase morphology and tensile properties of PA12/PP blends, Journal of Applied Polymer Science, 2006, 99 (5): 2640-2660
[79]肖士镜, CS-1 型和 CS-2 型高效催化剂的研制、生产和应用, 高分子通报,2005, (4): 95-99
[80]郭红革, 盛京, 赵树高, PP/PC 共混材料的研究概况, 高分子通报, 2006, (2):46-51
[81]Resconi L, Camurati I, Malizia F, Metallocene catalysts for 1-butene polymerization, Macromolecular Chemistry and Physics, 2007, 208 (4): 423-423
[82]Kawahara N, Saito J, Matsuo S, et al, Study on unsaturated structures of polyhexene, poly(4-methylpentene) and poly (3-methylpentene) prepared with metallocene catalysts, Polymer, 2007, 48 (2): 425-428
[83]Melillo G, Izzo L, Zinna M, et al, Branching formation in the ethylene polymerization with meso ansa metallocene-based catalysts, Macromoleculars, 2002, 35 (25): 9256-9261
[84]Busico V, Cipullo R, Friederichs N, et al, H-1 NMR analysis of chain unsaturations in ethene/1-octene copolymers prepared with metallocene catalysts at high temperature, Macromolecular, 2005, 38 (16): 6988-6996
[85]Magagnini PL, Pracella M, Minkova LI, et al, Synthesis of PP-LCP graft copolymers and their compatibilizing activity for PP/LCP blends, Journal of Applied Polymer Science, 1998, 69 (2): 391-403
[86]Lu HL, Chung TC, Synthesis of PP graft copolymers via anionic living graft-from reactions of polypropylene containing reactive p-methylstyrene units, Journal of Macromolecular Science-Chemistry, 1999, 37 (22): 4176-4183
[87]Yamaguchi M, Wagner MH, Impact of processing history on rheological properties for branched polypropylene, Polymer, 2006, 47 (10): 3629-3635
[88]Kotzev G, Touleshkov N, Christova D, Foamed crosslinked LDPE/PP blends made by hot mold injection molding, Macromolecular Symposia, 2002, 181: 507-511
[89]Zhang J, Ding QJ, Zhou NL, et al, Studies on crystal morphology and crystallization kinetics of polypropylene filled with CaCO3 of different size and size distribution, Journal of Applied Polymer Science, 2006, 101 (4): 2437-2444
[90]Kultural SE, Eryurek IB, Fatigue behavior of calcium carbonate filled polypropylene under high frequency loading, Materials Design, 2007, 28 (3): 816-823
[91]Lee J, Macosko CW, Bates FS, Development of discrete nanopores: II. Comparison between layered films and blends of polyolefins, Journal of Applied Polymer Science, 2005, 95 (3): 708-718
[92]Yeh SK, Al-Mulla A, Gupta RK, Effect of the coupling agent on the properties of PNC-based wood/plastic composites, Journal of Polymer Engineering, 2006, 26 (8): 783-804
[93]Wu JS, Yu DM, Chan CM, et al, Effect of fiber pretreatment condition on the interfacial strength and mechanical properties of wood fiber/PP composites, Journal of Applied Polymer Science, 2000, 76 (7): 1000-1010
[94]Borysiak S, Paukszta D, Helwig M, Flammability of wood-polypropylene composites, Polymer Degradtion and Stability, 2006, 91 (12): 3339-3343
[95]Fan ZX, Zhang Y, Chen YM, et al, Tensile properties of glass fiber knitted fabric reinforced polypropylene composite made from GF/PP commingled yarn affected by prestretching, Journal of Reinforced Plastics and Composites, 2006, 25 (5): 553-560
[96]Abbacha N, Fellahi S, Synthesis of PP-g-MAH and evaluation of its effect on the properties of glass fibre reinforced nylon 6/polypropylene blends, Macromolecular, Symposia, 2002, 178: 131-138
[97]Friedrich K, Evstatiev M, Fakirov S, et al, Microfibrillar reinforced composites from PET/PP blends: processing, morphology and mechanical properties, Composites Science and Technology, 2005, 65 (1): 107-116
[98]Bledzki AK, Faruk O, Microcellular wood fibre reinforced PP composites - A comparative study between extrusion, injection moulding and compression moulding, International Polymer Processing, 2006, 21 (3): 256-262
[99]Tseng FP, Lin JJ, Tseng CR, et al, Poly(oxypropylene)-amide grafted polypropylene as novel compatibilizer for PP and PA6 blends, Polymer, 2001, 42 (2): 713-725
[100]Jannerfekdt G,Boogh L, Manson JAE, The morphology of hyperbranced polymer compatibilized polypropylene/polyamide6 blends, Polymer Engineering and Science 2001, 41 (2): 293-300
[101]Janerfekdt G, Boogh L, Manson JAE, Tailored interfacial properties for immiscible polymers by hyperbranced polymers, Polymer, 2000, 41 (21): 7627-7634
[102]Gonzalez-Montiel A, Keskkula H, Paul DR, Impact-modified nylon6/ polypropylene blends: Morphology-property relationships, Polymer, 1995, 36 (23): 4587-6305
[103]Wei GX, Sue HJ, Chu J, et al, Toughening and strengthening of polypropylene using the rigid-rigid polymer toughening concept PartⅠ .Morphology and mechanical property investigations , Polymer, 2000, 41 (8): 2947-2960
[104]Wei GX, Sue HJ. Toughening and strengthening of polypropylene using the rigid-rigid polymer toughening concept Part Ⅱ, Toughening mechanisms investigations, Journal of Materials Science, 2000, 35 (3): 555-566
[105]Gupta AK ,Tain AK, Study on binary and ternary blends of polypropylene with ABS and LDPE, Ⅱ Impact and tensile properties, Journal of Applied Polymer Science, 1990, 39 (3): 515-530
[106]Pate AC, Brahmb H, Sarawade RB, et al, Mophological and mechanical properties of PP/ABS blends compalibilized with PP-g-acrylic,Journal of Applied Polymer Science, 2001, 81 (7): 1731-1741
[107]周明义,ABS/改性 PP 共混物形态与冲击性能,工程塑料应用, 2000, 28 (10): 29-32
[108]Kwan HY, Lee HW , Park OK, et al, Properties of poly(ethylene terephthalate) and maleic anthydride-grafted polypropylene blends by reactive processing, Journal of Applied Polymer Science, 1998, 70 (2): 389-395
[109]Pang YX, Jia DM, Hu HJ, et al, Effects of a compatibilizing agent on the morphology, interface and mechanical behavior of polyproylene/ poly(ethylene terephthalate) blends, Polymer, 2000, 41 (1): 357-365
[110]Song M, Pang Y. Correlation among morphology, interface and mech- anical properties experimental study, Journal of macromolecules science-physics, 2001, 40 (6): 1153-1167
[111]Champange MF,Huneault MA, Roux C, et al, Reactive compatibili-zation of polypropylene/polyethylene terephthalate blends, Polymer Engineering and Science, 1999, 39 (6): 976-984
[112]Ramirez VE, Navarro RD, Medellin RFJ, et al, Morphological and mechanical properties of polypropylene [PP]/poly(ethylene vinyl acetate) [EVA] blends. I. Homopolymer PP/EVA systems, Polymer Engineering and Science, 2000, 40 (10): 2241-2250
[113]Maciel A, Salas V, Manero O, PP/EVA blends: Mechanical. properties and morphology. Effect of compatibilizers on the impact behavior, Advances in Polymer Technology, 2005, 24 (4): 241-252
[114]Ramirez VE, Medellin RFJ, Navarro RD, et al, Morphological and mechanical properties of polypropylene [PP]/poly(ethylene vinyl acetate) [EVA] blends. II: Polypropylene-(ethylene-propylene) heterophasic copolymer [PP-EP]/EVA systems, Polymer Engineering and Science, 2002, 42 (6): 1350-1358
[115]Dalai S, Chen WX, Radiation effects on poly(propylene) (PP)/ethylene-vinyl acetate copolymer (EVA) blends, Journal of Applied Polymer Science, 2002, 86 (13): 3420-3424
[116]Souza AMC,Demarquette NR, Influence of coalescence and interfacial on the mophology of PP/HDPE compatibilized blends, Polymer, 2002, 43 (7): 3959-3967
[117]Schürman BL, Nieberqall U, Swverin N, et al, Polyethylene(PEHD) /poly propylene(iPP) blends: mechanical properties, structure and morphology, Polymer, 1998, 39 (22): 5283-5291
[118]汪晓东, 励杭泉,分子量对 PP/UHMWPE 合金力学性能、形态和流变性能的影响,高分子材料科学与工程,1996,12 (3):54-60
[119]杨军,李炳海, UHMWPE 改性 PP 的结晶行为和亚微观形态研究,塑料,1998,27 (4):32-36
[120]Wang KJ, Zhou CX. The effects of melt vibration blending on the subsequent crystallization and melting behavior of polypropylene/ultra high molecular weight polyethylene , Polymer Engineering and Science, 2001, 41(12): 2249-2258
[121]杨军,李炳海, PP/UHMWPE 原为成纤复合材料的混炼及成形工艺研究,中国塑料, 1999, 13(11): 34-38
[122]Manchado MAL, Torre L, Kenny JM, Kinetic crystallization of polypropylene in ternary composites based on fiber-reinforced PP-EPDM blends, Journal of Applied Polymer Science, 2001, 81 (5): 1063-1074
[123]Datta S, Naskar K, Jelenic J, et al, Dynamically vulcanized PP/EPDM blends by multifunctional peroxides: Characterization with various analytical techniques, Journal of Applied Polymer Science, 2005, 98 (3): 1393-1403
[124]Arroyo M, Bell M, Morphology/behavior relationship and recyclability of composites based on PP/EPDM blends and short aramid fibers, Journal of Applied Polymer Science, 2002, 83 (11): 2474-2484
[125]Prut E, Medintseva T, Dreval V, Mechanical and rheological behavior of unvulcanized and dynamically vulcanized i-PP/EPDM blends, Macromolecular Symposia, 2006, 233: 78-85
[126]Wilhelm HM, Felisberti MI, Blends of i-PP and SBS. I. Influence of the in situ compatibilization on the morphology, Journal of Applied Polymer Science, 2002, 85 (4): 847-855
[127]Ichazo M, Hernandez M, Gonzalez J, et al, Comparison of rheological and mechanical behavior of dynamically and statically vulcanized PP/SBS blends, Polymer Bulletin, 2004, 51 (5): 419-427
[128]Ao NJ, Wang Q, Novel milling route for controlling structure and properties in SBS elastomer blends containing dispersed PA6 and PP particles, Plastics Rubber and Composites, 2002, 31 (1): 6-11
[129]Sengupta P, Noordermeer JWM, Effects of composition and processing conditions on morphology and properties of thermoplastic elastomer blends of SEBS-PP-oil and dynamically vulcanized EPDM-PP-oil, Journal of Elastomers and Plastics, 2004, 36 (4): 307-331
[130]Guo MY, Zhou XD, Dai G, et al, Polypropylene/ethylene-octene copolymer/organic-montmorillonite nanocomposites, Polymer & Polymer Composites, 2005, 13 (2): 173-180
[131]Wahit MU, Hassan A, Rahmat AR, et al, Effect of organoclay and ethylene-octene copolymer inclusion on the morphology and mechanical properties of polyamide/polypropylene blends, Journal of Reinforced Plastics and Composites, 2006, 25 (9): 933-955
[132]Chiu HT, Hsiao YK, Compatibilization of poly(ethylene terephthalate)/polypropylene blends with maleic anhydride grafted polyethylene-octene elastomer, Journal of Polymer Research, 2006, 13 (2): 153-160
[133]Wu H, Sun XL, Li Z, et al, Effect of interfacial structure on crystallization behavior of polypropylene/polyolefin elastomer/barium sulfate ternary composites, Journal of Macromolecular Science-Physiscs, 2007, 46 (2): 329-339
[134]张金柱, 新型热塑性弹性体 POE 的性能及其在 PP 增韧改性中的应用, 塑料科技,1999 (2):5-7
[135]夏琳, 孙阿彬, 邱桂学, 等, POE 的性能及其在聚丙烯共混改性中的应用,弹性体,2006(3):65-68
[136]孙阿彬, 任欣, 夏琳, 等, 工艺参数对动态硫化 POE/PP 体系的影响,塑料科技,2006(6):56-58
[137]吕彦梅,唐华杰,侯馨,刚性增韧材料, 塑料科技,1999,1: 33-37
[138]杨军忠,周春怀,王延伟,PP/PS/SEBS 三元共混物的研究,中国塑料, 2000, 14(11): 32-37
[139]周春怀,杨军忠,王延伟,高刚性、高韧性、高流动性聚丙烯的研制, 工程塑料应用,2001,29(3): 8-11
[140]闫瑞萍,梁善杰,PP/HDPE/EPDM 三元共混材料微观结构及增韧机理分析, 工程塑料应用, 1994, 22 (3): 31-34.
[141]Srinivasa KR, Gupta AK, Mechanical properties and morphology of PP/SEBS/PC blends, Journal of Applied Polymer Science, 1996, 53(1): 1-9
[142] 张丁浩,聚丙烯/尼龙 1010 体系共混过程中的在线分析及其结构与性能研究,[硕士学位论文],天津大学,2001
[143] 方开泰,许建伦,统计分布,北京:科学出版社,1987
[144]Mandelbrot BB, Fractal geometry of nature, New York: Freeman, 1983
[145]汪富强,李后强,分形-大自然的艺术构造,山东:山东教育出版社,1996
[146]燕立唐,多相聚合物相结构形成过程的图像分析,[硕士学位论文],天津大学,2004
[147]李云岩,多相聚合物相结构形成与演变-PS/PP 合金相结构与演变特征,[硕士学位论文],天津大学,2004
[148]左榘,陈天红,分形理论与高分子科学,高分子材料科学与工程,1992,8(4):1-6
[149]S.斯坦讲授,徐懋等译,散射和双折射方法在高聚物研究中的应用,北京:科学出版社,1983
[150]Plochocki AP; Dagli SS, Andrews RD, The interface in binary mixtures of polymers containing a corresponding block copolymer- effects of industrial mixing processes and of coalescence, Polymer Engineering and Science , 1990, 30, 741-750
[151]韩蕴萍,多相聚合物体系熔体动态过程中的相结构与行为-高抗冲聚苯乙烯/顺丁橡胶共混过程中的结构与性能,[硕士学位论文],天津大学,1998
[152]匙文雄,多相聚合物相结构的形成与演变—聚丙烯合金相结构形成及其动力学研究,[硕士学位论文],天津大学,2007
[153]李渭清,聚丙烯合金材料结构与性能,[硕士学位论文],天津大学,2007
[154]张志涌,精通 MATLAB 6.5 版,北京:北京航空航天大学出版,2003
[155]孙仲康,快速傅立叶变换变换及其应用,北京:人民邮电出版社,1982
[156]威佛 HJ 著,王仲德,孙辉译,离散和连续傅立叶分析理论,北京:北京邮电学院出版社,1991
[157]郭少云,李惠林,徐僖.聚丙烯/丁基橡胶共混体系的研究[J]. 应用化学. 1991,8(3):153-157
[158]Zheng Q, Du M, Yang BB, Relationship between Dynamic Rheological Behavior and Phase Seperation of Poly(methyl methacrylate)/ Poly(styrene-co-acrylonitrile) Blends, Polymer,2001,42:5743-5747
[159] 郑强,高桥雅兴,升田利史郎,PMMA/α-MSAN 共混体系长时驰豫区域的时温叠加失效与相分离的关系,高等学校化学学报,1998,19:1339-1342
[160] Han CD, Jhon MS, Correlation of the Fist Normal Stress Difference with Shear Stress and of the Storage Modulus with Loss Modulus for Homopolymers, Journal of Applied Polymer Science, 1986, 32, 3809
[161]Han CD, Kim JK, Molecular theory for the viscoelasticity of compatible polymer mixtures. 2. Tube model with reptation and constraint release contributions, Macromolecules, 1989, 22(11), 4292 - 4302
[162]Han CD, Kim JK, On the Use of Time-Temperature Superposition in Multicomponent/multiphase Polymer Systems, Polymer,1993,34:2533-2539
[163]Han CD, Chuang HK, Criteria for Rheological Compatibility of Polymer Blends, Journal of Applied Polymer Science,1985,30:4431-4445
[164]Han CD, Yang HH, Rheological Behavior of Compatible Polymer Blends. Ⅰ. Blends of Poly(styrene-co-acrylonitrile) and Poly(ε-caprolactone), Journal of Applied Polymer Science, 1987,33:1199-1220
[165]周持兴,聚合物流变实验与应用,上海:上海交通大学出版社,2003,72-75
[166]Madbouly SA, Otaigbe JU, Ougizawa T, Morphology and properties of novel blends prepared from simultaneous in situ polymerization and compatibilization of macrocychc carbonates and maleated poly(propylene). Macromolecular Chemistry and Physics, 2006, 207 (14): 1233-1243
[167]Mokrini A, Acosta JL. Studies of sulfonated block copolymer and its blends, Polymer, 2001, 42 (1): 9-15
[168]Hristov V, Vasileva S, Dynamic mechanical and thermal properties of modified poly(propylene) wood fiber composites. Macromolecular Materials and Engineering, 2003, 288 (10): 798-806
[169]Modesti M, Lorenzetti A, Bon D, et al, Thermal behaviour of compatibilised polypropylene nanocomposite: Effect of processing conditions. Polymer Degradation and Stability, 2006 91 (4): 672-680
[170]Grein C, Bernreitner K, Gahleitner M, Potential and limits of dynamic mechanical analysis as a tool for fracture resistance evaluation of isotactic polypropylenes and their polyolefin blends, Journal of Applied Polymer Science, 2004, 93 (4): 1854-1867
[171]Li Z, Ke YC, Hu L, Study on a new kind of polypropylene-graft-polystyrene: Preparation and application. Journal of Applied Polymer Science, 2004, 93 (1): 314-322
[172]Genovese A, Shanks RA, Dynamic mechanical properties of poly(propylene) blends with poly[ethylene-co-(methyl acrylate)], Macromolecular Materials and Engineering, 2004, 289 (1): 20-32
[173]Liu HZ, Xie TX, Zhang Y, et al, Phase morphology development in PP/PA6 blends induced by a maleated thermoplastic elastomer, Journal of Macromolecular Science-Physics, 2006, 44 (7): 1050-1061
[174]Lopez-Manchado MA, Biagiotti J, Arroyo M, et al, Ternary composites based on PP-EPDM blends reinforced with flax fibers. Part I: Processing and thermal behavior, Polymer Engineering and Science, 2003, 43 (5): 1018-1030
[175]Li J, Zhang Q, Wang C, et al, Effect of compatibility on phase morphology and orientation of isotactic polypropylene (iPP) blends obtained by dynamic packing injection molding. Chinese Journal of Polymer Science, 2006, 24 (4): 379-387
[176]Shieh YT, Chuang HC, DSC and DMA studies on silane-grafted and water-crosslinked LDPE/LLDPE blends, Journal of Applied Polymer Science ,81 (7): 1808-1816
[2]Castelvetro V, Geppi M, Giaiacopi S, et al, Cotton fibers encapsulated with homo- and block copolymers: Synthesis by the atom transfer radical polymerization grafting-from technique and solid-state NMR dynamic investigations, Biomacromolecules, 2007, 8(2): 498-508
[3]Brar AS, Saini T, Atom transfer radical polymerization of 2-methoxy ethyl acrylate and its block copolymerization with acrylonitrile, European Polymer Journal, 2007, 43(3): 1046-1054
[4]Tasdelen MA, Yagci Y, Demirel AL, et al, Synthesis and characterization of block-graft copolymers [poly(epichlorohydrin-b-styrene)-g-poly(methyl methacrylate)] by combination of activated monomer polymerization, NMP and ATRP, Polymer Bulletin, 2007, 58(4): 653-663
[5] Yun SI, Briber RM, Kee RA, et al, Dilute-solution structure of charged arborescent graft polymer, Polymer, 2006, 47 (8): 2750-2759
[6]Unger F, Wittmar M, Kissel T, Branched polyesters based on poly[vinyl-3-(dialkylamino)alkylcarbamate-co-vinyl acetate-co-vinyl alcohol]-graft-poly(D,L-lactide-co-glycolide): Effects of polymer structure on cytotoxicity, Biomaterials 2007, 28 (9): 1610-1619
[7]Woo KM, Seo J, Zhang RY, et al, Suppression of apoptosis by enhanced protein adsorption on polymer/hydroxyapatite composite scaffolds, Biomacromolecules, 2007, 28 (16): 2622-2630
[8]Mertiny P, Gold A, Quantification of leakage damage in high-pressure fibre-reinforced polymer composite tubular vessels, Polymer Testing, 2007, 26 (2): 172-179
[9]Mohanty S, Verma SK, Nayak SK, Rheological characternization of PP/jute composite melts, Journal of Applied Polymer Science, 2006, 99 (4): 1476-1484
[10]Hoshi T, Sawaguchi T, Konno T, et al, Preparation of molecular dispersed polymer blend composed of polyethylene and poly(vinyl acetate) by in situ polymerization of vinyl acetate using supercritical carbon dioxide, Polymer, 2007, 48 (6): 1573-1580
[11]Kaito A, Iwakura Y, Hatakeyama K, et al, Organization of oriented lamellar structures in a miscible crystalline/crystalline polymer blend under uniaxial compression flow near the melting temperature , Macromolecules 2007, 40 (8): 2751-2759
[12]Kumar ES, Das CK, Banik K, et al, Viscoelastic properties of in situ composite based on ethylene acrylic elastomer (AEM) and liquid crystalline polymer (LCP) blend, Polymer, 2007, 48 (6): 1573-1580
[13]Darras V, Fichet O, Perrot F, et al, Polysiloxane-poly(fluorinated acrylate) interpenetrating polymer networks: Synthesis and characterization, Polymer, 2007, 48 (3): 687-695
[14]Huang YJ, Hsieh TH, Wang YZ, et al, Effect of nonconjugated polymers on the conjugation length and structure of poly(3-octylthiophene) in ternary polymer blend, Journal of Applied Polymer Science, 2007, 104 (2): 773-781
[15]Kim SY, Kim SH, Kim JY, et al, Novel CO2 laser drawing of thermotropic liquid crystal polymer and poly(ethylene 2,6-naphthalate) blend fibers, Journal of Applied Polymer Science, 2007, 104 (1): 205-211
[16]Ruegg ML, Reynolds BJ, Lin MY, et al, Effect of pressure on a multicomponent A/B/A-C polymer blend with attractive and repulsive interactions, Macromolecules, 2007, 40 (2): 355-365
[17]Morales G, de Leon RD, Acuna P, et al, Improved toughness in HIPS obtained from different styrene/butadiene-graded block copolymers through modification of the polydispersity index of the PS block, Polymer Engineering and Science, 2006, 46 (10): 1333-1341
[18]Souza FG, Soares BG, Siddaramaiah, et al, Influence of plasticizers (DOP and CNSL) on mechanical and electrical properties of SBS/polyaniline blends, Polymer, 47 (21): 7548-7553
[19]Dikobe DG, Luyt AS, Effect of poly(ethylene-co-glycidyl methacrylate) compatibilizer content on the morphology and physical properties of ethylene vinyl acetate-wood fiber composites, Journal of Applied Polymer Science, 2007, 104 (5): 3206-3213
[20]Guduri BR, Luyt AS, Effect of ethylene glycidyl methacrylate compatibilizer on the structure and mechanical properties of clay nanocomposites modified with ethylene vinyl acetate copolymer, Journal of Applied Polymer Science, 2007, 103 (6): 4095-4101
[21]Filippone G, Netti PA, Acierno D, Microstructural evolutions of LDPE/PA6 blends by rheological and rheo-optical analyses: Influence of flow and compatibilizer on break-up and coalescence processes, Polymer, 2007,48 (2): 564-573
[22]Soares BG, Almeida MSM, Urs MVD, et al, Influence of curing agent and compatibilizer on the physicomechanical properties of polypropylene/nitrile butadiene rubber blends investigated by positron annihilation lifetime technique, Journal of Applied Polymer Science, 2006, 102 (5): 4672-4681
[23]Kim DW, Park KW, Chowdhury SR, et al, Effect of compatibilizer and silane coupling agent on physical properties of ethylene vinyl acetate copolymer/ethylene-1-butene copolymer/clay nanocomposite foams, Journal of Applied Polymer Science, 2006, 102 (4): 3259-3265
[24]Taepaiboon P, Junkasem J, Dangtungee R, et al, In situ microfibrillar-reinforced composites of isotactic polypropylene/recycled poly(ethylene terephthalate) system and effect of compatibilizer, Journal of Applied Polymer Science, 2006, 102 (2): 1173-1181
[25]Schreiber HP, Olguin A, Aspects of dispersion and flow in thermoplastic-elastomer blends, Polymer Engineering and Science, 1983, 23:129-134
[26]Plochcki AP, Dagli SS, Andrews RD. The interface in binary mixtures of polymers containing corresponding block copolymer: effects of industrial mixing processes and of coalescence, Polymer Engineering and Science, 1990, 30: 741-752
[27]Scott CE, Macosko, CW, Morphology development during reactive and nonreactive blending of an ethylene-propylene rubber with two thermoplastic matrices, Polymer, 1994, 35: 5422
[28]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blending, Polymer, 1995, 36, 461 ]29]Isayev AI, Wang CM, Zeng X, Effect of oscillations during extrusion on rheology and mechanical properties of polymers, Advance in Polymer Technology, 1990, 10(1): 31
[30]Karger-Koscis J, Kallo A, Kuleznev VN, Phase structure of impact-modified polypropylene blends, Polymer, 1984, 25, 279
[31]Favis BD, The effect of processing parameters on the morphology of an immiscible binary blend, Journal of Applied Polymer Science, 1990, 39, 285-300
[32]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blending, Polymer Bulletin 1991, 26: 341-348
[33]Sundaraj U, Macosko CW, Nakayama A, Inoue T, Milligrams to kilograms: an evaluation of mixers for reactive polymer blending, Polymer Engineering and Science, 1995, 35(1), 100-114
[34]Lindt JT, Ghosh AK, Fluid mechanics of the formation of polymer blends. I: formation of lamellar structures, Polymer Engineering and Science, 1992, 32, 1802-1810
[35]Elemans PHM, Bos HL, Janssen JMH, Transient phenomena in dispersive mixing. Chemical Engineering Science, 1993, 48(2):267-276 36. Sundararaj U, Macosko CW, Drop breakup and coalescence in polymer blends- the effects of concentration and compatibilization, Macromolecules, 1995, 28, 2647-2652
[37]Kim JK, Lee SH, Paglicawan MA, et al, Effects of extruder parameters and compositions on mechanical properties and morphology of maleic anhydride grafted polypropylene/waste tire blends , Polymer-Plastics Technology and Engineering 2007, 46 (1): 19-29
[38]Endoh MK, Takenaka M, Hashimoto T, Effects of shear flow on a semidilute polymer solution under phase-separating condition, Polymer, 2006, 47 (20): 7271-7281
[39]Du ML, Guo BC, Jia DM, Effects of thermal and UV-induced grafting of bismaleimide on mechanical performance of reclaimed rubber/natural rubber blends, Journal of Polymer Research, 2005, 12 (6): 473-482
[40]Kim JW, Yoo JE, Kim CK, Phase behavior of ternary blends containing dimethylpolycarbonate, tetramethylpolycarbonate and poly[styrene-co-(methyl methacrylate)] copolymers (or polystyrene), Polymer International, 2005, 54 (1): 130-136
[41]Yang XD, Zhu YT, Jiang W, Online study of the formation of PA6 droplets in PP matrix under shear flow, Journal of Applied Polymer Science, 2007, 104 (4): 2690-2695
[42]Melo TJA, Canevarolo SV, In-line optical detection in the transient state of extrusion polymer blending and reactive processing, Polymer Engineering and Science, 2005 44 (1): 11-19
[43]He XJ, Cox CL, Ellison MS, Simulation of TLCP deformation during isothermal melt spinning of in situ composite fibers, Journal of Macromolecular Science-Physiscs, 2004, 43 (2): 309-328
[44]Coates PD, Barnes SE, Sibley MG, et al, In-process vibrational spectroscopy and ultrasound measurements in polymer melt extrusion, Polymer, 2003, 44 (19): 5937-5949
[45]Schlatter G, Serra C, Bouquey M, et al, Online light scattering measurements: A method to assess morphology development of polymer blends in a twin-screw extruder, Polymer Engineering and Science, 2002, 42 (10): 1965-1975
[46]Pal K, Rastogi JN, Development of halogen-free flame-retardant thermoplastic elastomer polymer blend, Journal of Applied Polymer Science, 2004, 94 (2): 407-415
[47]Favis BD, Effect of processing parameters on the morphology of an immiscible binary blend, Journal of Applied Polymer Science, 1990, 39 (2):285–300.
[48]Scott CE, Macosko CW, Morphology development during the initial stages of polymer-polymer blends, Polymer, 1995, 36 (3):461–470.
[49]Scott CE, Macosko CW, Model experiments concerning morphology development during the initial stages of polymer blending, Polymer Bulletin, 1991, 26 (3): 341–348.
[50]Sundararaj U, Macosko CW, Rolando RJ, Chan HT, Morphology development in polymer blends, Polymer Engineering and Science, 1992, 32 (24): 1814–1823.
[51]Lindt JT, Ghosh AK, Fluid mechanics of the formation of polymer blends. Part: Q1 Formation of lamellar structures, Polymer Engineering and Science, 1992, 32 (24): 1802–1813.
[52]Yu L, Dean K, Li L, Polymer blends and composites from renewable resources, Progress in Polymer Science, 2006, 31 (6): 576-602
[53]Goossens S, Groeninckx G, Mutual influence between reaction-induced phase separation and isothermal crystallization in POM/epoxy resin blends, Macromolecular, 2006, 39 (23): 8049-8059
[54]Ruegg ML, Newstein MC, Balsara NP, et al, Small-angle neutron scattering from nonuniformly labeled block copolymers, Macromolecular, 2004, 37 (5): 1960-1968
[55]Peng M, Li DS, Chen Y, et al, Effect of an organoclay on the reaction-induced phase-separation kinetics and morphology of a poly(ether imide)/epoxy mixture, Journal of Applied Polymer Science, 2007,104 (2): 1205-1214
[56]Merfeld GD, Paul DR, Light scattering characterization of tetramethyl polycarbonate blends with polystyrene and with styrene-pentabromobenzyl acrylate copolymers Polymer, 2000,41 (2): 649-661
[57]Barnes MD, Ng KC, Fukui K, et al, Probing phase-separation behavior in polymer-blend microparticles: Effects of particle size and polymer mobility, Macromolecular, 1999, 32 (21): 7183-7189
[58]Yurekli K, Karim A, Amis EJ, et al, Phase behavior of PS-PVME nanocomposites, Macromolecular, 2004,37 (2): 507-515
[59]Takeji Hashimoto et al., J.Chem.Phys., 1986, 8(2), 123
[60]Chi-Kai Shih, Mixing and morphological transformations in the compoundign process for polymer blends: the phase for polymer inversion mechanism, Polymer Engineering and Science, 1995, 35:1688-1692
[61]Plivelic TS, Cassu SN, Goncalves MD, et al, Structure and morphology of poly(epsilon-caprolactone)/chlorinated polyethylene (PCL/PECl) blends investigated by DSC, simultaneous SAXS/WAXD, and elemental mapping by ESI-TEM, Macromolecular, 2007, 40 (2): 253-264
[62]Gemeinhardt GC, Moore RB, Characterization of ionomer-compatibilized blend morphology using synchrotron small-angle X-ray scattering, Macromolecular, 2005, 38 (7): 2813-2819
[63]Madbouly SA, Wolf BA, Shear-induced crystallization and shear-induced dissolution of poly(ethylene oxide) in mixtures with tetrahydronaphthalene and oligo(dimethyl siloxane-b-ethylene oxide), Macromolecular Chemistry and Physics 2003, 204 (3): 417-424
[64]马桂秋,原续波, 盛京,小角 X 光散射法研究聚丙烯/乙丙橡胶合金的相结构,高分子学报,2002,(1):63-67
[65]张丁浩,盛京,沈宁祥, 光散射在聚合物共混过程中形态发展研究的应用,光散射学报,2003,(2):79-100
[66]陈云,盛京,沈宁祥,等, 小角光散射在线系统研究多相聚合物双螺杆挤出过程中的相尺寸-非相容 PE/PA1010 体系, 高分子学报, 2004, (2): 282-287
[67]Macosko CW, Philippe AKK, Akinari N,| Philippe M, Takashi I, Compatibilizers for Melt Blending: remade Block Copolymers, Macromolecules, 1996, 29: 5590-5601
[68]Li YY, Chen ZQ, Huang Y, et al, Morphology development in polypropylene/polystyrene blends during coalescence under shear, Journal of Applied Polymer Science, 2007, 104 (1): 666-671
[69]Li YY, Wang Y, Li WQ, et al, Compatibilization of styrene-butadiene-styrene block copolymer in polypropylene/polystyrene blends by analysis of phase morphology, Journal of Applied Polymer Science, 2007, 103 (1): 365-370
[70]Yang YP, Li WQ, Xiao ZG, et al, Study on the mechanism of the formation and evolution of phase structure in PP/PcBR blends, Journal of Macromolecular Science-Physics, 2006, 45 (6): 1039-1052
[71]Yang YP, Xiao ZG, Jiang X, et al, Light scattering studies on phase behavior of PP/PcBR blends during melt-mixing, Journal of Macromolecular Science-Physics, 200645 (6): 1083-1098
[72]Ma GQ, Zhao YH, Yan LT, et al, Blends of polypropylene with poly(cis-butadiene) rubber: III. Study on the phase structure and morphology of incompatible blends of polypropylene with poly(cis-butadiene) rubber, Journal of Applied Polymer Science, 2006,100 (6): 4900-4909
[73]Li YY, Han YP, Zhao YH, Study on phase formation and evolution of high impact polystyrene with poly(cis-butadiene) rubber blends, Journal of Macromolecular Science-Physics, 2005, 44 (5): 651-664
[74]Chand N, Naik AM, Khaira HK, Development of UHMWPE modified PP/PET blends and their mechanical and abrasive wear behavior, Polymer Composites, 2007, 28 (2): 267-272
[75]Diaz IF, Barbosa SE, Capiati NJ, Addition compatibilization of PP/PS blends by Tailor-made copolymers, Polymer Engineering and Science 2006, 46 (3): 329-336
[76]Cidade MT, Filipe S, Duarte AP, et al, Synthesis of compatibilizers and characterization of the compatibilized and noncompatibilized blends of PP/Rodrun LC3000, Journal of Applied Polymer Science, 2007, 104 (5): 3001-3009
[77]Albano C, Gonzalez J, Ichazo M, et al, Thermal stability of PP with acetylated sisal fiber: Romero Garcia kinetic method, Polymer Bulletin, 2003, 51 (3): 245-254
[78]Jose S, Nair SV, Thomas S, et al, Effect of reactive compatibilisation on the phase morphology and tensile properties of PA12/PP blends, Journal of Applied Polymer Science, 2006, 99 (5): 2640-2660
[79]肖士镜, CS-1 型和 CS-2 型高效催化剂的研制、生产和应用, 高分子通报,2005, (4): 95-99
[80]郭红革, 盛京, 赵树高, PP/PC 共混材料的研究概况, 高分子通报, 2006, (2):46-51
[81]Resconi L, Camurati I, Malizia F, Metallocene catalysts for 1-butene polymerization, Macromolecular Chemistry and Physics, 2007, 208 (4): 423-423
[82]Kawahara N, Saito J, Matsuo S, et al, Study on unsaturated structures of polyhexene, poly(4-methylpentene) and poly (3-methylpentene) prepared with metallocene catalysts, Polymer, 2007, 48 (2): 425-428
[83]Melillo G, Izzo L, Zinna M, et al, Branching formation in the ethylene polymerization with meso ansa metallocene-based catalysts, Macromoleculars, 2002, 35 (25): 9256-9261
[84]Busico V, Cipullo R, Friederichs N, et al, H-1 NMR analysis of chain unsaturations in ethene/1-octene copolymers prepared with metallocene catalysts at high temperature, Macromolecular, 2005, 38 (16): 6988-6996
[85]Magagnini PL, Pracella M, Minkova LI, et al, Synthesis of PP-LCP graft copolymers and their compatibilizing activity for PP/LCP blends, Journal of Applied Polymer Science, 1998, 69 (2): 391-403
[86]Lu HL, Chung TC, Synthesis of PP graft copolymers via anionic living graft-from reactions of polypropylene containing reactive p-methylstyrene units, Journal of Macromolecular Science-Chemistry, 1999, 37 (22): 4176-4183
[87]Yamaguchi M, Wagner MH, Impact of processing history on rheological properties for branched polypropylene, Polymer, 2006, 47 (10): 3629-3635
[88]Kotzev G, Touleshkov N, Christova D, Foamed crosslinked LDPE/PP blends made by hot mold injection molding, Macromolecular Symposia, 2002, 181: 507-511
[89]Zhang J, Ding QJ, Zhou NL, et al, Studies on crystal morphology and crystallization kinetics of polypropylene filled with CaCO3 of different size and size distribution, Journal of Applied Polymer Science, 2006, 101 (4): 2437-2444
[90]Kultural SE, Eryurek IB, Fatigue behavior of calcium carbonate filled polypropylene under high frequency loading, Materials Design, 2007, 28 (3): 816-823
[91]Lee J, Macosko CW, Bates FS, Development of discrete nanopores: II. Comparison between layered films and blends of polyolefins, Journal of Applied Polymer Science, 2005, 95 (3): 708-718
[92]Yeh SK, Al-Mulla A, Gupta RK, Effect of the coupling agent on the properties of PNC-based wood/plastic composites, Journal of Polymer Engineering, 2006, 26 (8): 783-804
[93]Wu JS, Yu DM, Chan CM, et al, Effect of fiber pretreatment condition on the interfacial strength and mechanical properties of wood fiber/PP composites, Journal of Applied Polymer Science, 2000, 76 (7): 1000-1010
[94]Borysiak S, Paukszta D, Helwig M, Flammability of wood-polypropylene composites, Polymer Degradtion and Stability, 2006, 91 (12): 3339-3343
[95]Fan ZX, Zhang Y, Chen YM, et al, Tensile properties of glass fiber knitted fabric reinforced polypropylene composite made from GF/PP commingled yarn affected by prestretching, Journal of Reinforced Plastics and Composites, 2006, 25 (5): 553-560
[96]Abbacha N, Fellahi S, Synthesis of PP-g-MAH and evaluation of its effect on the properties of glass fibre reinforced nylon 6/polypropylene blends, Macromolecular, Symposia, 2002, 178: 131-138
[97]Friedrich K, Evstatiev M, Fakirov S, et al, Microfibrillar reinforced composites from PET/PP blends: processing, morphology and mechanical properties, Composites Science and Technology, 2005, 65 (1): 107-116
[98]Bledzki AK, Faruk O, Microcellular wood fibre reinforced PP composites - A comparative study between extrusion, injection moulding and compression moulding, International Polymer Processing, 2006, 21 (3): 256-262
[99]Tseng FP, Lin JJ, Tseng CR, et al, Poly(oxypropylene)-amide grafted polypropylene as novel compatibilizer for PP and PA6 blends, Polymer, 2001, 42 (2): 713-725
[100]Jannerfekdt G,Boogh L, Manson JAE, The morphology of hyperbranced polymer compatibilized polypropylene/polyamide6 blends, Polymer Engineering and Science 2001, 41 (2): 293-300
[101]Janerfekdt G, Boogh L, Manson JAE, Tailored interfacial properties for immiscible polymers by hyperbranced polymers, Polymer, 2000, 41 (21): 7627-7634
[102]Gonzalez-Montiel A, Keskkula H, Paul DR, Impact-modified nylon6/ polypropylene blends: Morphology-property relationships, Polymer, 1995, 36 (23): 4587-6305
[103]Wei GX, Sue HJ, Chu J, et al, Toughening and strengthening of polypropylene using the rigid-rigid polymer toughening concept PartⅠ .Morphology and mechanical property investigations , Polymer, 2000, 41 (8): 2947-2960
[104]Wei GX, Sue HJ. Toughening and strengthening of polypropylene using the rigid-rigid polymer toughening concept Part Ⅱ, Toughening mechanisms investigations, Journal of Materials Science, 2000, 35 (3): 555-566
[105]Gupta AK ,Tain AK, Study on binary and ternary blends of polypropylene with ABS and LDPE, Ⅱ Impact and tensile properties, Journal of Applied Polymer Science, 1990, 39 (3): 515-530
[106]Pate AC, Brahmb H, Sarawade RB, et al, Mophological and mechanical properties of PP/ABS blends compalibilized with PP-g-acrylic,Journal of Applied Polymer Science, 2001, 81 (7): 1731-1741
[107]周明义,ABS/改性 PP 共混物形态与冲击性能,工程塑料应用, 2000, 28 (10): 29-32
[108]Kwan HY, Lee HW , Park OK, et al, Properties of poly(ethylene terephthalate) and maleic anthydride-grafted polypropylene blends by reactive processing, Journal of Applied Polymer Science, 1998, 70 (2): 389-395
[109]Pang YX, Jia DM, Hu HJ, et al, Effects of a compatibilizing agent on the morphology, interface and mechanical behavior of polyproylene/ poly(ethylene terephthalate) blends, Polymer, 2000, 41 (1): 357-365
[110]Song M, Pang Y. Correlation among morphology, interface and mech- anical properties experimental study, Journal of macromolecules science-physics, 2001, 40 (6): 1153-1167
[111]Champange MF,Huneault MA, Roux C, et al, Reactive compatibili-zation of polypropylene/polyethylene terephthalate blends, Polymer Engineering and Science, 1999, 39 (6): 976-984
[112]Ramirez VE, Navarro RD, Medellin RFJ, et al, Morphological and mechanical properties of polypropylene [PP]/poly(ethylene vinyl acetate) [EVA] blends. I. Homopolymer PP/EVA systems, Polymer Engineering and Science, 2000, 40 (10): 2241-2250
[113]Maciel A, Salas V, Manero O, PP/EVA blends: Mechanical. properties and morphology. Effect of compatibilizers on the impact behavior, Advances in Polymer Technology, 2005, 24 (4): 241-252
[114]Ramirez VE, Medellin RFJ, Navarro RD, et al, Morphological and mechanical properties of polypropylene [PP]/poly(ethylene vinyl acetate) [EVA] blends. II: Polypropylene-(ethylene-propylene) heterophasic copolymer [PP-EP]/EVA systems, Polymer Engineering and Science, 2002, 42 (6): 1350-1358
[115]Dalai S, Chen WX, Radiation effects on poly(propylene) (PP)/ethylene-vinyl acetate copolymer (EVA) blends, Journal of Applied Polymer Science, 2002, 86 (13): 3420-3424
[116]Souza AMC,Demarquette NR, Influence of coalescence and interfacial on the mophology of PP/HDPE compatibilized blends, Polymer, 2002, 43 (7): 3959-3967
[117]Schürman BL, Nieberqall U, Swverin N, et al, Polyethylene(PEHD) /poly propylene(iPP) blends: mechanical properties, structure and morphology, Polymer, 1998, 39 (22): 5283-5291
[118]汪晓东, 励杭泉,分子量对 PP/UHMWPE 合金力学性能、形态和流变性能的影响,高分子材料科学与工程,1996,12 (3):54-60
[119]杨军,李炳海, UHMWPE 改性 PP 的结晶行为和亚微观形态研究,塑料,1998,27 (4):32-36
[120]Wang KJ, Zhou CX. The effects of melt vibration blending on the subsequent crystallization and melting behavior of polypropylene/ultra high molecular weight polyethylene , Polymer Engineering and Science, 2001, 41(12): 2249-2258
[121]杨军,李炳海, PP/UHMWPE 原为成纤复合材料的混炼及成形工艺研究,中国塑料, 1999, 13(11): 34-38
[122]Manchado MAL, Torre L, Kenny JM, Kinetic crystallization of polypropylene in ternary composites based on fiber-reinforced PP-EPDM blends, Journal of Applied Polymer Science, 2001, 81 (5): 1063-1074
[123]Datta S, Naskar K, Jelenic J, et al, Dynamically vulcanized PP/EPDM blends by multifunctional peroxides: Characterization with various analytical techniques, Journal of Applied Polymer Science, 2005, 98 (3): 1393-1403
[124]Arroyo M, Bell M, Morphology/behavior relationship and recyclability of composites based on PP/EPDM blends and short aramid fibers, Journal of Applied Polymer Science, 2002, 83 (11): 2474-2484
[125]Prut E, Medintseva T, Dreval V, Mechanical and rheological behavior of unvulcanized and dynamically vulcanized i-PP/EPDM blends, Macromolecular Symposia, 2006, 233: 78-85
[126]Wilhelm HM, Felisberti MI, Blends of i-PP and SBS. I. Influence of the in situ compatibilization on the morphology, Journal of Applied Polymer Science, 2002, 85 (4): 847-855
[127]Ichazo M, Hernandez M, Gonzalez J, et al, Comparison of rheological and mechanical behavior of dynamically and statically vulcanized PP/SBS blends, Polymer Bulletin, 2004, 51 (5): 419-427
[128]Ao NJ, Wang Q, Novel milling route for controlling structure and properties in SBS elastomer blends containing dispersed PA6 and PP particles, Plastics Rubber and Composites, 2002, 31 (1): 6-11
[129]Sengupta P, Noordermeer JWM, Effects of composition and processing conditions on morphology and properties of thermoplastic elastomer blends of SEBS-PP-oil and dynamically vulcanized EPDM-PP-oil, Journal of Elastomers and Plastics, 2004, 36 (4): 307-331
[130]Guo MY, Zhou XD, Dai G, et al, Polypropylene/ethylene-octene copolymer/organic-montmorillonite nanocomposites, Polymer & Polymer Composites, 2005, 13 (2): 173-180
[131]Wahit MU, Hassan A, Rahmat AR, et al, Effect of organoclay and ethylene-octene copolymer inclusion on the morphology and mechanical properties of polyamide/polypropylene blends, Journal of Reinforced Plastics and Composites, 2006, 25 (9): 933-955
[132]Chiu HT, Hsiao YK, Compatibilization of poly(ethylene terephthalate)/polypropylene blends with maleic anhydride grafted polyethylene-octene elastomer, Journal of Polymer Research, 2006, 13 (2): 153-160
[133]Wu H, Sun XL, Li Z, et al, Effect of interfacial structure on crystallization behavior of polypropylene/polyolefin elastomer/barium sulfate ternary composites, Journal of Macromolecular Science-Physiscs, 2007, 46 (2): 329-339
[134]张金柱, 新型热塑性弹性体 POE 的性能及其在 PP 增韧改性中的应用, 塑料科技,1999 (2):5-7
[135]夏琳, 孙阿彬, 邱桂学, 等, POE 的性能及其在聚丙烯共混改性中的应用,弹性体,2006(3):65-68
[136]孙阿彬, 任欣, 夏琳, 等, 工艺参数对动态硫化 POE/PP 体系的影响,塑料科技,2006(6):56-58
[137]吕彦梅,唐华杰,侯馨,刚性增韧材料, 塑料科技,1999,1: 33-37
[138]杨军忠,周春怀,王延伟,PP/PS/SEBS 三元共混物的研究,中国塑料, 2000, 14(11): 32-37
[139]周春怀,杨军忠,王延伟,高刚性、高韧性、高流动性聚丙烯的研制, 工程塑料应用,2001,29(3): 8-11
[140]闫瑞萍,梁善杰,PP/HDPE/EPDM 三元共混材料微观结构及增韧机理分析, 工程塑料应用, 1994, 22 (3): 31-34.
[141]Srinivasa KR, Gupta AK, Mechanical properties and morphology of PP/SEBS/PC blends, Journal of Applied Polymer Science, 1996, 53(1): 1-9
[142] 张丁浩,聚丙烯/尼龙 1010 体系共混过程中的在线分析及其结构与性能研究,[硕士学位论文],天津大学,2001
[143] 方开泰,许建伦,统计分布,北京:科学出版社,1987
[144]Mandelbrot BB, Fractal geometry of nature, New York: Freeman, 1983
[145]汪富强,李后强,分形-大自然的艺术构造,山东:山东教育出版社,1996
[146]燕立唐,多相聚合物相结构形成过程的图像分析,[硕士学位论文],天津大学,2004
[147]李云岩,多相聚合物相结构形成与演变-PS/PP 合金相结构与演变特征,[硕士学位论文],天津大学,2004
[148]左榘,陈天红,分形理论与高分子科学,高分子材料科学与工程,1992,8(4):1-6
[149]S.斯坦讲授,徐懋等译,散射和双折射方法在高聚物研究中的应用,北京:科学出版社,1983
[150]Plochocki AP; Dagli SS, Andrews RD, The interface in binary mixtures of polymers containing a corresponding block copolymer- effects of industrial mixing processes and of coalescence, Polymer Engineering and Science , 1990, 30, 741-750
[151]韩蕴萍,多相聚合物体系熔体动态过程中的相结构与行为-高抗冲聚苯乙烯/顺丁橡胶共混过程中的结构与性能,[硕士学位论文],天津大学,1998
[152]匙文雄,多相聚合物相结构的形成与演变—聚丙烯合金相结构形成及其动力学研究,[硕士学位论文],天津大学,2007
[153]李渭清,聚丙烯合金材料结构与性能,[硕士学位论文],天津大学,2007
[154]张志涌,精通 MATLAB 6.5 版,北京:北京航空航天大学出版,2003
[155]孙仲康,快速傅立叶变换变换及其应用,北京:人民邮电出版社,1982
[156]威佛 HJ 著,王仲德,孙辉译,离散和连续傅立叶分析理论,北京:北京邮电学院出版社,1991
[157]郭少云,李惠林,徐僖.聚丙烯/丁基橡胶共混体系的研究[J]. 应用化学. 1991,8(3):153-157
[158]Zheng Q, Du M, Yang BB, Relationship between Dynamic Rheological Behavior and Phase Seperation of Poly(methyl methacrylate)/ Poly(styrene-co-acrylonitrile) Blends, Polymer,2001,42:5743-5747
[159] 郑强,高桥雅兴,升田利史郎,PMMA/α-MSAN 共混体系长时驰豫区域的时温叠加失效与相分离的关系,高等学校化学学报,1998,19:1339-1342
[160] Han CD, Jhon MS, Correlation of the Fist Normal Stress Difference with Shear Stress and of the Storage Modulus with Loss Modulus for Homopolymers, Journal of Applied Polymer Science, 1986, 32, 3809
[161]Han CD, Kim JK, Molecular theory for the viscoelasticity of compatible polymer mixtures. 2. Tube model with reptation and constraint release contributions, Macromolecules, 1989, 22(11), 4292 - 4302
[162]Han CD, Kim JK, On the Use of Time-Temperature Superposition in Multicomponent/multiphase Polymer Systems, Polymer,1993,34:2533-2539
[163]Han CD, Chuang HK, Criteria for Rheological Compatibility of Polymer Blends, Journal of Applied Polymer Science,1985,30:4431-4445
[164]Han CD, Yang HH, Rheological Behavior of Compatible Polymer Blends. Ⅰ. Blends of Poly(styrene-co-acrylonitrile) and Poly(ε-caprolactone), Journal of Applied Polymer Science, 1987,33:1199-1220
[165]周持兴,聚合物流变实验与应用,上海:上海交通大学出版社,2003,72-75
[166]Madbouly SA, Otaigbe JU, Ougizawa T, Morphology and properties of novel blends prepared from simultaneous in situ polymerization and compatibilization of macrocychc carbonates and maleated poly(propylene). Macromolecular Chemistry and Physics, 2006, 207 (14): 1233-1243
[167]Mokrini A, Acosta JL. Studies of sulfonated block copolymer and its blends, Polymer, 2001, 42 (1): 9-15
[168]Hristov V, Vasileva S, Dynamic mechanical and thermal properties of modified poly(propylene) wood fiber composites. Macromolecular Materials and Engineering, 2003, 288 (10): 798-806
[169]Modesti M, Lorenzetti A, Bon D, et al, Thermal behaviour of compatibilised polypropylene nanocomposite: Effect of processing conditions. Polymer Degradation and Stability, 2006 91 (4): 672-680
[170]Grein C, Bernreitner K, Gahleitner M, Potential and limits of dynamic mechanical analysis as a tool for fracture resistance evaluation of isotactic polypropylenes and their polyolefin blends, Journal of Applied Polymer Science, 2004, 93 (4): 1854-1867
[171]Li Z, Ke YC, Hu L, Study on a new kind of polypropylene-graft-polystyrene: Preparation and application. Journal of Applied Polymer Science, 2004, 93 (1): 314-322
[172]Genovese A, Shanks RA, Dynamic mechanical properties of poly(propylene) blends with poly[ethylene-co-(methyl acrylate)], Macromolecular Materials and Engineering, 2004, 289 (1): 20-32
[173]Liu HZ, Xie TX, Zhang Y, et al, Phase morphology development in PP/PA6 blends induced by a maleated thermoplastic elastomer, Journal of Macromolecular Science-Physics, 2006, 44 (7): 1050-1061
[174]Lopez-Manchado MA, Biagiotti J, Arroyo M, et al, Ternary composites based on PP-EPDM blends reinforced with flax fibers. Part I: Processing and thermal behavior, Polymer Engineering and Science, 2003, 43 (5): 1018-1030
[175]Li J, Zhang Q, Wang C, et al, Effect of compatibility on phase morphology and orientation of isotactic polypropylene (iPP) blends obtained by dynamic packing injection molding. Chinese Journal of Polymer Science, 2006, 24 (4): 379-387
[176]Shieh YT, Chuang HC, DSC and DMA studies on silane-grafted and water-crosslinked LDPE/LLDPE blends, Journal of Applied Polymer Science ,81 (7): 1808-1816
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |