污染底泥制备陶粒及除磷潜力研究
|
摘要
底泥疏浚能够有效解决河道水体黑臭问题并提高水质,但后期底泥处置成为难题。为了合理处置污染河道疏浚过程中产生的底泥,采用高温烧结法制备底泥陶粒,并回用于河道水体治理。采用响应面优化方法得到底泥陶粒制备最优条件:烧结时间为14 min,烧结温度为1 025℃,Al_2O_3添加量w为8.10%。底泥陶粒吸附磷的试验结果表明,底泥陶粒吸附磷的热力学过程符合单层吸附的Langmuir模型,拟合计算得到底泥陶粒对磷最大吸附量为9.40 mg·g~(-1),底泥陶粒的磷吸附动力学过程符合伪一级动力学模型。结合化学成分、扫描电镜、能谱及红外光谱分析,底泥陶粒主要通过吸附作用去除水体中磷。与其他吸附剂相比,底泥陶粒具有吸附性能好和价格低廉的优点,在河道水体治理中使用底泥陶粒可以解决疏浚底泥的处置问题,实现底泥资源化利用。
Dredging can effectively solve the problem of black and offensive odor in river and improve water quality, but the disposal of sediment produced in dredging has become difficult in the later stage. In order to better dispose the river sediment, sediment ceramsite was prepared by thermal treatment and reused for river regulation. Based on single factor experiment, the optimum preparation conditions of sediment ceramsite were obtained by response surface methodology, with sintering time as 14 min, sintering temperature as 1 025 ℃, and the addition amount of w(Al_2O_3) as 8.10%. As suggested by experimental results, the phosphorus adsorption process on sediment ceramsite was better accorded with Langmuir isotherm by single layer adsorption, and the maximum phosphorus sorption capacity was 9.40 mg·g~(-1) by model calculation. Pseudo-first order kinetic model accurately fitted the adsorption data. Combined with XRD, SEM-EDS and FTIR analysis, phosphorus was mainly removed by sediment ceramsite adsorption. Compared with other adsorbents, sediment ceramsite has the advantages of better adsorption performance and lower cost. The application of sediment ceramsite in river water treatment can not only solve the problem of dredged sediment disposal, but also effectively reduce phosphorus released from river sediment and realize sediment utilization.
Dredging can effectively solve the problem of black and offensive odor in river and improve water quality, but the disposal of sediment produced in dredging has become difficult in the later stage. In order to better dispose the river sediment, sediment ceramsite was prepared by thermal treatment and reused for river regulation. Based on single factor experiment, the optimum preparation conditions of sediment ceramsite were obtained by response surface methodology, with sintering time as 14 min, sintering temperature as 1 025 ℃, and the addition amount of w(Al_2O_3) as 8.10%. As suggested by experimental results, the phosphorus adsorption process on sediment ceramsite was better accorded with Langmuir isotherm by single layer adsorption, and the maximum phosphorus sorption capacity was 9.40 mg·g~(-1) by model calculation. Pseudo-first order kinetic model accurately fitted the adsorption data. Combined with XRD, SEM-EDS and FTIR analysis, phosphorus was mainly removed by sediment ceramsite adsorption. Compared with other adsorbents, sediment ceramsite has the advantages of better adsorption performance and lower cost. The application of sediment ceramsite in river water treatment can not only solve the problem of dredged sediment disposal, but also effectively reduce phosphorus released from river sediment and realize sediment utilization.
引文
[1] 李文超,王文浩,何岩,等.黑臭河道沉积物中硫铁行为与氮磷循环的耦合机制[J].华东师范大学学报(自然科学版),2015(2):1-8,29.[LI Wen-chao,WANG Wen-hao,HE Yan,et al.Coupling of Sulfur and Iron With Nitrogen and Phosphorus in Sediments of Malodorous River:A Review[J].Journal of East China Normal University (Natural Science),2015(2):1-8,29.]
[2] 丁涛,田英杰,刘进宝,等.杭州市河道底泥重金属污染评价与环保疏浚深度研究[J].环境科学学报,2015,35(3):911-917.[DING Tao,TIAN Ying-jie,LIU Jin-bao,et al.Assessment of Heavy Metal Status in Sediments and Environmental Dredging Depth in Hangzhou[J].Acta Scientiae Circumstantiae,2015,35 (3):911-917.]
[3] ROY E D.Phosphorus Recovery and Recycling With Ecological Engineering:A Review[J].Ecological Engineering,2017,98:213-227.
[4] 许炼烽,邓绍龙,陈继鑫,等.河流底泥污染及其控制与修复[J].生态环境学报,2014,23(10):1708-1715.[XU Lian-feng,DENG Shao-long,CHEN Ji-xin,et al.River sediment Pollution and Its Control and Restoration[J].Ecology and Environmental Sciences,2014,23(10):1708-1715.]
[5] XU G R,ZOU J L,LI G B.Effect of Sintering Temperature on the Characteristics of Sludge Ceramsite[J].Journal of Hazardous Materials,2007,150(2):394-400.
[6] XU G R,LIU M W,LI G B.Stabilization of Heavy Metals in Lightweight Aggregate Made From Sewage Sludge and River Sediment[J].Journal of Hazardous Materials,2013,260:74-81.
[7] XU G R,ZOU J L,LI G B.Stabilization of Heavy Metals in Ceramsite Made With Sewage Sludge[J].Journal of Hazardous Materials,2007,152(1):56-61.
[8] XU G R,ZOU J L,LI G B.Stabilization/Solidification of Heavy Metals in Sludge Ceramsite and Leachability Affected by Oxide Substances[J].Environmental Science and Technology,2009,43(15):5902-5907.
[9] LIU M W,XU G R,LI G B.Effect of the Ratio of Components on the Characteristics of Lightweight Aggregate Made From Sewage Sludge and River Sediment[J].Process Safety and Environmental Protection,2017,105:109-116.
[10] 王发洲,曾兴华,黄劲.利用东湖淤泥制备超轻陶粒的研究[J].低温建筑技术,2008,30(4):4-6.[WANG Fa-zhou,ZENG Xing-hua,HUANG Jin.Research on Preparation of Ultra Lightweight Aggragate Manufactured From East Lake Sludge[J].Low Temperature Architecture Technology,2008,30(4):4-6.]
[11] 刘贵云,奚旦立.利用河道底泥制备陶粒的试验研究[J].东华大学学报(自然科学版),2003,29(4):81-83,94.[LIU Gui-yun,XI Dan-li.Experiment on Producing Ceramsite With River Sediment[J].Journal of Donghua University,2003,29(4):81-83,94.]
[12] 徐淑红,马春燕,张静文,等.正交设计与回归分析在底泥陶粒松散容重研究中的应用[J].中国陶瓷,2008,44(9):54-57.[XU Shu-hong,MA Chun-yan,ZHANG Jing-wen,et al.The Application of Thogonal Design and Regression Analysis on the Study of Losse Bulk Density of Ceramsite[J].China Ceramics,2008,44(9):54-57.]
[13] 刘贵云,李承勇,奚旦立.河道底泥陶粒对生活污水中NH3-N的深度处理试验研究[J].东华大学学报(自然科学版),2003,29(5):100-103.[LIU Gui-yun,LI Cheng-yong,XI Dan-li.NH3-N Removal Performance of the Advanced Sewage Treatment With Biological Aerated Filter[J].Journal of Donghua University,2003,29(5):100-103.]
[14] 郑育毅,余育方,李妍,等.自来水厂污泥制得陶粒对污水中磷和氨氮的吸附[J].环境工程学报,2015,9(2):756-762.[ZHENG Yu-yi,YU Yu-fang,LI Yan,et al.Adsorption of Phosphorus or Ammonia Nitrogen by Ceramsite Made From Waterworks Sludge[J].Chinese Journal of Environmental Engineering,2015,9(2):756-762.]
[15] 林建伟,詹艳慧,陆霞.锆改性沸石对水中磷酸盐和铵的吸附特性[J].中国环境科学,2012,32(11):2023-2031.[LIN Jian-wei,ZHAN Yan-hui,LU Xia.Adsorption of Phosphate and Ammonium From Aqueous Solution on Zirconium Modified Zeolite[J].China Environmental Science,2012,32(11):2023-2031]
[16] 李佳,詹艳慧,林建伟.镧改性沸石改良太湖底泥的磷吸附特征[J].生态与农村环境学报,2013,29(4):500-506.[LI Jia,ZHAN Yan-hui,LIN Jian-wei.Effect of La-Modified Zeolite on Phosphate Sorption of Taihu Lake Sediments[J].Journal of Ecology and Rural Environment,2013,29(4):500-506.]
[17] HJ 613—2011,土壤干物质和水分的测定重量法[S].[HJ 613-2011,Soil.Determination of Dry Matter and Water Content.Gravimetric Method[S].]
[18] 李海峰,王庆仁,朱永官.土壤重金属测定两种前处理方法的比较[J].环境化学,2006,25(1):108-109.
[19] 钱君龙,张连弟,乐美麟.过硫酸盐消化法测定土壤全氮全磷[J].土壤,1990,22(5):258-262.
[20] 余莹,黄江南,林波,等.新型水处理填料:纳米改性陶粒的研制[J].给水排水,2004,30(12):95-99.[YU Ying,HUANG Jiang-nan,LIN Bo,et al.Development of New Water Purification Material:Modified Nanometer Ceramsite[J].Water & Wastewater Engineering,2004,30(12):95-99.]
[21] 刘燕芳,夏雨,余莹,等.纳米改性陶粒:高比表面积水处理填料的研制[J].江西化工,2004(2):91-96.[LIU Yan-fang,XIA Yu,YU Ying,et al.Development of Water Treatment Nano-Modified Ceramsites Filler With High Specific Area[J]Jiangxi Chemical Industry,2004(2):91-96.]
[22] 刘明伟,许国仁,李圭白.Al2O3对污泥和河道底泥制取陶粒的性能影响[J].中国给水排水,2013,29(21):132-134.[LIU Ming-wei,XU Guo-ren,LI Gui-bai.Effect of Al2O3 on Characteristics of Lightweight Aggregates Made From Sewage Sludge and River Sediment[J].China Water & Wastewater,2013,29(21):132-134.]
[23] 邓蕾,杨正宏.Al粉增强淤泥陶粒及其机理的研究[J].新型建筑材料,2013,40(1):6-9,19.[DENG Lei,YANG Zheng-hong.Research on Al Powder-Reinforced Lightweight Aggregates Manufactured From River Sedimentand Its Mechanism[J].New Building Materials,2013,40(1):6-9,19.]
[24] 章丹.利用竺山湾底泥制备磁改性轻质陶粒实验研究[D].青岛:青岛理工大学,2014.[ZHANG Dan.Research on Preparation of Magnetic Modified Lightweight Haydite by Sediment From Zhushan Bay of Taihu Lake[D].Qingdao:Qingdao Technological University,2014.]
[25] GB 15618—2018,土壤环境质量农用地土壤污染风险管控标准(试行)[S].[GB 15618-2018,Soil Environmental Quality Risk Control Standard for Soil Contamination of Agricultural Land[S].]
[26] XU G R,ZOU J L,LI G B.Stabilization of Heavy Metals in Sludge Ceramsite[J].Water Research,2010,44(9):2930-2938.
[27] JIANG C,JIA L Y,ZHANG B,et al.Comparison of Quartz Sand,Anthracite,Shale and Biological Ceramsite for Adsorptive Removal of Phosphorus From Aqueous Solution[J].Journal of Environmental Sciences,2014,26(2):466-477.
[28] 许国仁,邹金龙,孙丽欣.污泥作为添加剂制备轻质陶粒的试验研究[J].哈尔滨工业大学学报,2007,39(4):557-560.[XU Guo-ren,ZOU Jin-long,SUN Li-xin.Utilization of Dried Sludge as an Additive for Making Ceramsite[J].Journal of Harbin Institute of Technology,2007,39(4):557-560.]
[29] 邓林.镁铝水滑石基复合材料吸附去除水中铬(Ⅵ)、磷酸盐的研究[D].长沙:湖南大学,2015.[DENG Lin.Study on Removal of Chromium(Ⅵ) and Phosphate From Aqueous Solution Using Mg-Al Hydrotalcite-Based Composites[D].Changsha:Hunan University,2015.]
[30] 许光眉,施周,邓军.石英砂负载氧化铁吸附除锑、磷的XRD、FTIR以及XPS研究[J].环境科学学报,2007,27(3):402-407.[XU Guang-mei,SHI Zhou,DENG Jun.Characterization of Adsorption of Antmiony and Phosphate by Using IOCS With XRD,FTIR and XPS[J].Acta Scientiae Circumstantiae,2007,27(3):402-407.]
[31] 王慧.铁氧化物及其胡敏酸复合体对磷酸盐的吸附研究[D].武汉:华中农业大学,2015.[WANG Hui.Phosphate Adsorption on Iron Oxides And Iron Oxides-Humic Acid Complexes[D].Wuhan:Huazhong Agricultural University,2015.]
[32] HE Y H,LIN H,DONG Y B,et al.Simultaneous Removal of Ammonium and Phosphate by Alkaline-Activated and Lanthanum-Impregnated Zeolite[J].Chemosphere,2016,164:387-395.
[33] HASAN H A,ABDULLAH S R S,KAMARUDIN S K,et al.Response Surface Methodology for Optimization of Simultaneous COD,NH4+-N and Mn2+ Removal From Drinking Water by Biological Aerated Filter[J].Desalination,2011,275(1/2/3):50-61.
[34] 马宏林,贺涛,洪雷,等.响应面分析法优化给水污泥吸附除磷工艺[J].环境工程学报,2015,9(2):546-552.[MA Hong-lin,HE Tao,HONG Lei,et al.Optimization of the Adsorption of Phosphorus by Water Plant Sludge Using Response Surface Methodology[J].Chinese Journal of Environmental Engineering,2015,9(2):546-552.]
[35] JUNG K W,KIM D H,KIM H W,et al.Optimization of Combined (Acid+Thermal) Pretreatment for Fermentative Hydrogen Production From Laminaria japonica Using Response Surface Methodology (RSM)[J].International Journal of Hydrogen Energy,2011,36(16):9626-9631.
[36] 赵传文,赵利威.超轻粉煤灰陶粒的生产[J].新型建筑材料,2001,28(7):27-28.[ZHAO Chuan-wen,ZHAO Li-wei.Production of Super-Light Fly Ash Ceramsite[J].New Building Materials,2001,28(7):27-28.]
[37] 段宁,吴依远,张银凤.硅藻土/沸石复合颗粒吸附材料脱氮除磷的吸附动力学及热力学分析[J].硅酸盐通报,2014,33(12):3151-3158.[DUAN Ning,WU Yi-yuan,ZHANG Yin-feng.Adsorption Kinetics and Thermodynamics of Diatomite/Zeolite Composite Adsorbent Nitrogen and Phosphorus Removal[J].Bulletin of the Chinese Ceramic Society,2014,33(12):3151-3158.]
[38] HO Y S.Comments on Using of “Pseudo-First-Order Model” in Adsorption[Int.J.Biol.Macromol.,Vol.81].[J].International Journal of Biological Macromolecules,2016,88:505-506.
[39] HO Y S,MCKAY G.Pseudo-Second Order Model for Sorption Processes[J].Process Biochemistry,1999,34(5):451-465.
[40] KUMAR P S,RAMALINGAM S,KIRUPHAS D,et al.Adsorption Behavior of Nickel(Ⅱ) Onto Cashew Nut Shell:Equilibrium,Thermodynamics,Kinetics,Mechanism and Process Design[J].Chemical Engineering Journal,2010,167(1):122-131.
[41] CHUBAR N I,KANIBOLOTSKYY V A,STRELKO V V,et al.Adsorption of Phosphate Ions on Novel Inorganic Ion Exchangers[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,255(1/2/3):55-63.
[42] 付建秋,黄小凤,潘学军,等.底泥制备陶粒研究进展[J].硅酸盐通报,2013,32(12):2514-2519,2527.[FU Jian-qiu,HUANG Xiao-feng,PAN Xue-jun,et al.Research Progress on Preparation of Ceramisite From Sediment[J].Bulletin of the Chinese Ceramic Society,2013,32(12):2514-2519,2527.]
[43] 高红杰,彭剑峰,宋永会,等.清淤底泥制作陶粒的方法及其性能分析[J].环境工程技术学报,2011,1(4):328-333.[GAO Hong-jie,PENG Jian-feng,SONG Yong-hui,et al.The Method of Producing Haydite by Sediment and the Performance Analysis[J].Journal of Environmental Engineering Technology,2011,1(4):328-333.]
[44] 刘晓,李学莲,曹国凭.钢渣陶粒对废水中磷的吸附特性[J].工业水处理,2014,34(1):18-21.[LIU Xiao,LI Xue-lian,CAO Guo-ping.Adsorption Effect of Steel Slag Haydite on Phosphorus in Wastewater[J].Industrial Water Treatment,2014,34(1):18-21.]
[2] 丁涛,田英杰,刘进宝,等.杭州市河道底泥重金属污染评价与环保疏浚深度研究[J].环境科学学报,2015,35(3):911-917.[DING Tao,TIAN Ying-jie,LIU Jin-bao,et al.Assessment of Heavy Metal Status in Sediments and Environmental Dredging Depth in Hangzhou[J].Acta Scientiae Circumstantiae,2015,35 (3):911-917.]
[3] ROY E D.Phosphorus Recovery and Recycling With Ecological Engineering:A Review[J].Ecological Engineering,2017,98:213-227.
[4] 许炼烽,邓绍龙,陈继鑫,等.河流底泥污染及其控制与修复[J].生态环境学报,2014,23(10):1708-1715.[XU Lian-feng,DENG Shao-long,CHEN Ji-xin,et al.River sediment Pollution and Its Control and Restoration[J].Ecology and Environmental Sciences,2014,23(10):1708-1715.]
[5] XU G R,ZOU J L,LI G B.Effect of Sintering Temperature on the Characteristics of Sludge Ceramsite[J].Journal of Hazardous Materials,2007,150(2):394-400.
[6] XU G R,LIU M W,LI G B.Stabilization of Heavy Metals in Lightweight Aggregate Made From Sewage Sludge and River Sediment[J].Journal of Hazardous Materials,2013,260:74-81.
[7] XU G R,ZOU J L,LI G B.Stabilization of Heavy Metals in Ceramsite Made With Sewage Sludge[J].Journal of Hazardous Materials,2007,152(1):56-61.
[8] XU G R,ZOU J L,LI G B.Stabilization/Solidification of Heavy Metals in Sludge Ceramsite and Leachability Affected by Oxide Substances[J].Environmental Science and Technology,2009,43(15):5902-5907.
[9] LIU M W,XU G R,LI G B.Effect of the Ratio of Components on the Characteristics of Lightweight Aggregate Made From Sewage Sludge and River Sediment[J].Process Safety and Environmental Protection,2017,105:109-116.
[10] 王发洲,曾兴华,黄劲.利用东湖淤泥制备超轻陶粒的研究[J].低温建筑技术,2008,30(4):4-6.[WANG Fa-zhou,ZENG Xing-hua,HUANG Jin.Research on Preparation of Ultra Lightweight Aggragate Manufactured From East Lake Sludge[J].Low Temperature Architecture Technology,2008,30(4):4-6.]
[11] 刘贵云,奚旦立.利用河道底泥制备陶粒的试验研究[J].东华大学学报(自然科学版),2003,29(4):81-83,94.[LIU Gui-yun,XI Dan-li.Experiment on Producing Ceramsite With River Sediment[J].Journal of Donghua University,2003,29(4):81-83,94.]
[12] 徐淑红,马春燕,张静文,等.正交设计与回归分析在底泥陶粒松散容重研究中的应用[J].中国陶瓷,2008,44(9):54-57.[XU Shu-hong,MA Chun-yan,ZHANG Jing-wen,et al.The Application of Thogonal Design and Regression Analysis on the Study of Losse Bulk Density of Ceramsite[J].China Ceramics,2008,44(9):54-57.]
[13] 刘贵云,李承勇,奚旦立.河道底泥陶粒对生活污水中NH3-N的深度处理试验研究[J].东华大学学报(自然科学版),2003,29(5):100-103.[LIU Gui-yun,LI Cheng-yong,XI Dan-li.NH3-N Removal Performance of the Advanced Sewage Treatment With Biological Aerated Filter[J].Journal of Donghua University,2003,29(5):100-103.]
[14] 郑育毅,余育方,李妍,等.自来水厂污泥制得陶粒对污水中磷和氨氮的吸附[J].环境工程学报,2015,9(2):756-762.[ZHENG Yu-yi,YU Yu-fang,LI Yan,et al.Adsorption of Phosphorus or Ammonia Nitrogen by Ceramsite Made From Waterworks Sludge[J].Chinese Journal of Environmental Engineering,2015,9(2):756-762.]
[15] 林建伟,詹艳慧,陆霞.锆改性沸石对水中磷酸盐和铵的吸附特性[J].中国环境科学,2012,32(11):2023-2031.[LIN Jian-wei,ZHAN Yan-hui,LU Xia.Adsorption of Phosphate and Ammonium From Aqueous Solution on Zirconium Modified Zeolite[J].China Environmental Science,2012,32(11):2023-2031]
[16] 李佳,詹艳慧,林建伟.镧改性沸石改良太湖底泥的磷吸附特征[J].生态与农村环境学报,2013,29(4):500-506.[LI Jia,ZHAN Yan-hui,LIN Jian-wei.Effect of La-Modified Zeolite on Phosphate Sorption of Taihu Lake Sediments[J].Journal of Ecology and Rural Environment,2013,29(4):500-506.]
[17] HJ 613—2011,土壤干物质和水分的测定重量法[S].[HJ 613-2011,Soil.Determination of Dry Matter and Water Content.Gravimetric Method[S].]
[18] 李海峰,王庆仁,朱永官.土壤重金属测定两种前处理方法的比较[J].环境化学,2006,25(1):108-109.
[19] 钱君龙,张连弟,乐美麟.过硫酸盐消化法测定土壤全氮全磷[J].土壤,1990,22(5):258-262.
[20] 余莹,黄江南,林波,等.新型水处理填料:纳米改性陶粒的研制[J].给水排水,2004,30(12):95-99.[YU Ying,HUANG Jiang-nan,LIN Bo,et al.Development of New Water Purification Material:Modified Nanometer Ceramsite[J].Water & Wastewater Engineering,2004,30(12):95-99.]
[21] 刘燕芳,夏雨,余莹,等.纳米改性陶粒:高比表面积水处理填料的研制[J].江西化工,2004(2):91-96.[LIU Yan-fang,XIA Yu,YU Ying,et al.Development of Water Treatment Nano-Modified Ceramsites Filler With High Specific Area[J]Jiangxi Chemical Industry,2004(2):91-96.]
[22] 刘明伟,许国仁,李圭白.Al2O3对污泥和河道底泥制取陶粒的性能影响[J].中国给水排水,2013,29(21):132-134.[LIU Ming-wei,XU Guo-ren,LI Gui-bai.Effect of Al2O3 on Characteristics of Lightweight Aggregates Made From Sewage Sludge and River Sediment[J].China Water & Wastewater,2013,29(21):132-134.]
[23] 邓蕾,杨正宏.Al粉增强淤泥陶粒及其机理的研究[J].新型建筑材料,2013,40(1):6-9,19.[DENG Lei,YANG Zheng-hong.Research on Al Powder-Reinforced Lightweight Aggregates Manufactured From River Sedimentand Its Mechanism[J].New Building Materials,2013,40(1):6-9,19.]
[24] 章丹.利用竺山湾底泥制备磁改性轻质陶粒实验研究[D].青岛:青岛理工大学,2014.[ZHANG Dan.Research on Preparation of Magnetic Modified Lightweight Haydite by Sediment From Zhushan Bay of Taihu Lake[D].Qingdao:Qingdao Technological University,2014.]
[25] GB 15618—2018,土壤环境质量农用地土壤污染风险管控标准(试行)[S].[GB 15618-2018,Soil Environmental Quality Risk Control Standard for Soil Contamination of Agricultural Land[S].]
[26] XU G R,ZOU J L,LI G B.Stabilization of Heavy Metals in Sludge Ceramsite[J].Water Research,2010,44(9):2930-2938.
[27] JIANG C,JIA L Y,ZHANG B,et al.Comparison of Quartz Sand,Anthracite,Shale and Biological Ceramsite for Adsorptive Removal of Phosphorus From Aqueous Solution[J].Journal of Environmental Sciences,2014,26(2):466-477.
[28] 许国仁,邹金龙,孙丽欣.污泥作为添加剂制备轻质陶粒的试验研究[J].哈尔滨工业大学学报,2007,39(4):557-560.[XU Guo-ren,ZOU Jin-long,SUN Li-xin.Utilization of Dried Sludge as an Additive for Making Ceramsite[J].Journal of Harbin Institute of Technology,2007,39(4):557-560.]
[29] 邓林.镁铝水滑石基复合材料吸附去除水中铬(Ⅵ)、磷酸盐的研究[D].长沙:湖南大学,2015.[DENG Lin.Study on Removal of Chromium(Ⅵ) and Phosphate From Aqueous Solution Using Mg-Al Hydrotalcite-Based Composites[D].Changsha:Hunan University,2015.]
[30] 许光眉,施周,邓军.石英砂负载氧化铁吸附除锑、磷的XRD、FTIR以及XPS研究[J].环境科学学报,2007,27(3):402-407.[XU Guang-mei,SHI Zhou,DENG Jun.Characterization of Adsorption of Antmiony and Phosphate by Using IOCS With XRD,FTIR and XPS[J].Acta Scientiae Circumstantiae,2007,27(3):402-407.]
[31] 王慧.铁氧化物及其胡敏酸复合体对磷酸盐的吸附研究[D].武汉:华中农业大学,2015.[WANG Hui.Phosphate Adsorption on Iron Oxides And Iron Oxides-Humic Acid Complexes[D].Wuhan:Huazhong Agricultural University,2015.]
[32] HE Y H,LIN H,DONG Y B,et al.Simultaneous Removal of Ammonium and Phosphate by Alkaline-Activated and Lanthanum-Impregnated Zeolite[J].Chemosphere,2016,164:387-395.
[33] HASAN H A,ABDULLAH S R S,KAMARUDIN S K,et al.Response Surface Methodology for Optimization of Simultaneous COD,NH4+-N and Mn2+ Removal From Drinking Water by Biological Aerated Filter[J].Desalination,2011,275(1/2/3):50-61.
[34] 马宏林,贺涛,洪雷,等.响应面分析法优化给水污泥吸附除磷工艺[J].环境工程学报,2015,9(2):546-552.[MA Hong-lin,HE Tao,HONG Lei,et al.Optimization of the Adsorption of Phosphorus by Water Plant Sludge Using Response Surface Methodology[J].Chinese Journal of Environmental Engineering,2015,9(2):546-552.]
[35] JUNG K W,KIM D H,KIM H W,et al.Optimization of Combined (Acid+Thermal) Pretreatment for Fermentative Hydrogen Production From Laminaria japonica Using Response Surface Methodology (RSM)[J].International Journal of Hydrogen Energy,2011,36(16):9626-9631.
[36] 赵传文,赵利威.超轻粉煤灰陶粒的生产[J].新型建筑材料,2001,28(7):27-28.[ZHAO Chuan-wen,ZHAO Li-wei.Production of Super-Light Fly Ash Ceramsite[J].New Building Materials,2001,28(7):27-28.]
[37] 段宁,吴依远,张银凤.硅藻土/沸石复合颗粒吸附材料脱氮除磷的吸附动力学及热力学分析[J].硅酸盐通报,2014,33(12):3151-3158.[DUAN Ning,WU Yi-yuan,ZHANG Yin-feng.Adsorption Kinetics and Thermodynamics of Diatomite/Zeolite Composite Adsorbent Nitrogen and Phosphorus Removal[J].Bulletin of the Chinese Ceramic Society,2014,33(12):3151-3158.]
[38] HO Y S.Comments on Using of “Pseudo-First-Order Model” in Adsorption[Int.J.Biol.Macromol.,Vol.81].[J].International Journal of Biological Macromolecules,2016,88:505-506.
[39] HO Y S,MCKAY G.Pseudo-Second Order Model for Sorption Processes[J].Process Biochemistry,1999,34(5):451-465.
[40] KUMAR P S,RAMALINGAM S,KIRUPHAS D,et al.Adsorption Behavior of Nickel(Ⅱ) Onto Cashew Nut Shell:Equilibrium,Thermodynamics,Kinetics,Mechanism and Process Design[J].Chemical Engineering Journal,2010,167(1):122-131.
[41] CHUBAR N I,KANIBOLOTSKYY V A,STRELKO V V,et al.Adsorption of Phosphate Ions on Novel Inorganic Ion Exchangers[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,255(1/2/3):55-63.
[42] 付建秋,黄小凤,潘学军,等.底泥制备陶粒研究进展[J].硅酸盐通报,2013,32(12):2514-2519,2527.[FU Jian-qiu,HUANG Xiao-feng,PAN Xue-jun,et al.Research Progress on Preparation of Ceramisite From Sediment[J].Bulletin of the Chinese Ceramic Society,2013,32(12):2514-2519,2527.]
[43] 高红杰,彭剑峰,宋永会,等.清淤底泥制作陶粒的方法及其性能分析[J].环境工程技术学报,2011,1(4):328-333.[GAO Hong-jie,PENG Jian-feng,SONG Yong-hui,et al.The Method of Producing Haydite by Sediment and the Performance Analysis[J].Journal of Environmental Engineering Technology,2011,1(4):328-333.]
[44] 刘晓,李学莲,曹国凭.钢渣陶粒对废水中磷的吸附特性[J].工业水处理,2014,34(1):18-21.[LIU Xiao,LI Xue-lian,CAO Guo-ping.Adsorption Effect of Steel Slag Haydite on Phosphorus in Wastewater[J].Industrial Water Treatment,2014,34(1):18-21.]
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |