平板光极技术的基本原理及其在环境中的应用
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摘要
平板光极具有原位、实时、高分辨及多时空尺度定量观测等优点,在生物医学、海洋科学、环境科学及植物营养学等领域具有广泛的应用前景.本文详细综述平板光极技术的基本原理、近二十年荧光染料的开发、成像手段的发展历程,并简要回顾了平板光极技术在环境科学研究中的应用.系统概述了当前平板光极技术遇到的一些挑战,对其未来的发展趋势提出了展望.
Planar optodes have advantages of in-situ, real-time, high-resolution and multi-temporal-scale quantitative measurement. It has a wide range of application prospects in the research areas of biomedicine, marine science, environmental science, and plant nutrition. This article reviews the principles of planar optodes, the development of fluorescent dyes in the past two decades, the development of imaging methods, and their applications in the environmental science research. Challenges of the current planar optode technique were summarized and a perspective for future development of the technique was provided as well.
Planar optodes have advantages of in-situ, real-time, high-resolution and multi-temporal-scale quantitative measurement. It has a wide range of application prospects in the research areas of biomedicine, marine science, environmental science, and plant nutrition. This article reviews the principles of planar optodes, the development of fluorescent dyes in the past two decades, the development of imaging methods, and their applications in the environmental science research. Challenges of the current planar optode technique were summarized and a perspective for future development of the technique was provided as well.
引文
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[13] SCH?FERLING M,WU M,WOLFBEIS O S.Time-resolved fluorescent imaging of glucose[J].Journal of Fluorescence,2004,14(5):561-568.
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[20] LARSEN M,BORISOV S M,GRUNWALD B,et al.A simple and inexpensive high resolution color ratiometric planar optode imaging approach:Application to oxygen and pH sensing[J].Limnology & Oceanography Methods,2011,9(9):348-360.
[21] HULTH S.A pH plate fluorosensor (optode) for early diagenetic studies of marine sediments[J].Limnology & Oceanography,2002,47(1):212-220.
[22] ZHU Q Z,AND R C A,FAN Y.High-performance planar ph fluorosensor for two-dimensional ph measurements in marine sediment and water[J].Environmental Science & Technology,2005,39(22):8906-8911.
[23] HAKONEN A,HULTH S,DUFOUR S.Analytical performance during ratiometric long-term imaging of pH in bioturbated sediments[J].Talanta,2010,81(4-5):1393-1401.
[24] SCHR?DER C R,POLERECKY L,KLIMANT I.Time-resolved pH/pO2 mapping with luminescent hybrid sensors[J].Analytical Chemistry,2007,79(1):60-70.
[25] SCHR?DER C R,WEIDGANS B M,KLIMANT I.pH fluorosensors for use in marine systems[J].Analyst,2005,130(6):907-916.
[26] HAKONEN A,HULTH S.A high-performance fluorosensor for pH measurements between 6 and 9[J].Talanta,2010,80(5):1964-1969.
[27] ZHU Q,ALLER R C,FAN Y.A new ratiometric,planar fluorosensor for measuring high resolution,two-dimensional pCO2,distributions in marine sediments[J].Marine Chemistry,2006,101(1-2):40-53.
[28] STR?MBERG N,HULTH S.A fluorescence ratiometric detection scheme for ammonium ions based on the solvent sensitive dye MC 540[J].Sensors & Actuators B Chemical,2003,90(1):308-318.
[29] ZHU Q,ALLER R C.Planar fluorescence sensors for two-dimensional measurements of H2S distributions and dynamics in sedimentary deposits[J].Marine Chemistry,2013,157(12):49-58.
[30] KAUTSKY H.Quenching of Luminescence by Oxygen[J].Transactions Faraday Society,1939,35(1):216-219.
[31] JONES P F.On the use of phosphorescence quenching for determining permeabilities of polymeric films to gases[J].Journal of Polymer Science Part B Polymer Letters,1968,6(7):487-491.
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[33] SHAW G.Quenching by oxygen diffusion of phosphorescence emission of aromatic molecules in polymethyl methacrylate[J].Transactions of the Faraday Society,1967,63:2181-2189.
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[35] BASU B J,ANANDAN C,RAJAM K S.Study of the mechanism of degradation of pyrene-based pressure sensitive paints[J].Sensors & Actuators B Chemical,2003,94(3):257-266.
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