湿法烟气脱硫技术的现状与进展
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摘要
综述了国内外湿法烟气脱硫技术的现状,比较了不同工艺的优缺点;总结了各种烟气脱硫技术的主要研究方向及最新研究进展,指出了完善的湿法烟气脱硫工艺应包含高效的烟气脱硫技术、脱硫副产物的资源综合利用技术以及脱硫废水(近)零排放处理技术。
This paper summarizes the status of wet flue gas desulfurization technology at home and abroad,and compares the advantages and disadvantages of different processes. The main research directions and the latest research progress of wet flue gas desulfurization technology are also summarized,it is pointed out that a perfect wet flue gas desulfurization process should contain efficient flue gas desulfurization technology,comprehensive utilization technology of desulfurization by-products,and( near) zero-emission treatment technology for desulfurization wastewater.
This paper summarizes the status of wet flue gas desulfurization technology at home and abroad,and compares the advantages and disadvantages of different processes. The main research directions and the latest research progress of wet flue gas desulfurization technology are also summarized,it is pointed out that a perfect wet flue gas desulfurization process should contain efficient flue gas desulfurization technology,comprehensive utilization technology of desulfurization by-products,and( near) zero-emission treatment technology for desulfurization wastewater.
引文
[1]余昭,何育东,李兴华,等.石灰石-石膏法串联脱硫塔系统[J].热力发电,2016,45(2):91-95.
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[3]武宝会,李帅英,牛国平,等.燃煤机组烟气污染物协同脱除技术及应用[J].热力发电,2017,46(11):103-107.
[4]张军,张涌新,郑成航,等.复合脱硫添加剂在湿法烟气脱硫系统中的工程应用[J].中国环境科学,2014,34(9):2186-2191.
[5]贺鹏,张先明.中国燃煤发电厂烟气脱硫技术及应用[J].电力科技与环保,2014,30(1):8-11.
[6]武春锦,吕武华,梅毅,等.湿法烟气脱硫技术及运行经济性分析[J].化工进展,2015,34(12):4368-4374.
[7]景建平,吴文辉.石灰石膏湿法脱硫工艺主要运行参数控制调整探析[J].热力发电,2011,40(11):14-16.
[8]董丽彦,宋宝华,刘玉朋,等.烧结机脱硫系统应用复合增效剂的节能增效分析[J].环境工程,2016,34:602-605.
[9]董丽彦,程恺豪,柳雷,等.湿式石灰石-石膏法脱硫增效剂机理研究[J].广东化工,2014,41(18):133-134.
[10]赵丹,董延茂,王建华.氧化镁烟气脱硫废渣-硫酸镁废水-高钙粉煤灰脱氮除磷[J].环境工程学报,2016,10(8):4504-4510.
[11]刘阳,赵丹,董延茂,等.氧化镁烟气脱硫废渣在废水除磷中的应用[J].工业水处理,2013,22(18):19-21.
[12]齐笑言,宋宝华,刘安安,等.提高镁法烟气脱硫副产物氧化速率的实验研究[J].环境工程,2011,29:409-411.
[13]吕丽.氨法脱硫在锅炉烟气净化中的应用[J].能源化工,2017,38(2):75-79.
[14]丁红蕾,苏秋凤,张涌新,等.湿式氨法烟气脱硫工艺影响因素的试验研究[J].热力发电,2014,43(1):96-98.
[15]邱伟,刘盛余,陆成伟,等.氢氧化钠-钢渣双碱法烧结烟气脱硫工艺[J].环境工程学报,2013,7(3):1095-1100.
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[17] Wang Dongpeng,Lu Yonghong,Li Zhe,et al. Integrated electrochemical-aerating oxidation in recovery system of seawater flue gas desulfurization[J]. Chemical Engineering Journal,2018,338:184-190.
[18] Bian Junjie,Zhang Shu,Zhang Jingwei,et al. Supported manganese dioxide catalyst for seawater flue gas desulfurization application[J]. Chemical Engineering Journal,2012,190:57-61.
[19]王思粉,冯丽娟,李先国.浅析我国海水烟气脱硫技术及改进[J].热力发电,2011,40(1):4-7.
[20]郭娟,袁东星,陈进生,等.燃煤电厂海水脱硫工艺的排水对海域环境的影响[J].环境工程学报,2008,2(5):707-711.
[21]骆锦钊.海水法烟气脱硫排水水质的估算和分析[J].电力环境保护,2007,23(2):19-22.
[22] Sun Lumin,Lin Shanhan,Feng Lifeng,et al. The distribution and sea-air transfer of volatile mercury in waste postdesulfurization seawater discharged from a coal-fired power plant[J]. Environmental Science and Pollution Research,2013,20:6191-6200.
[23] Zhu Zhengxuan,Ma Yongpeng,Qu Zan,et al. Study on a new wet flue gas desulfurization method based on the Bunsen reaction of sulfur-iodine thermochemical cycle[J].Fuel,2017,195:33-37.
[24] Zhang Ke,Zhao Xu,Chen Sihan,et al. Direct electrolysis of Bunsen reaction product HI/H2SO4/H2O/toluene mixture for hydrogen production Pt electrode characterization[J]. International Joural of Hydrogen Energy,2018,43:13702-13710.
[25]刘昭,邹海魁,初广文,等.旋转填充床中柠檬酸钠法烟气脱硫的实验研究[J].北京化工大学学报:自然科学版,2014,41(1):34-38.
[26]关毅鹏,陈颖,张召才,等.膜吸收法烟气同时脱硫脱硝试验研究[J].膜科学与技术,2014,34(1):111-115.
[27]陈颖,关毅鹏,郭春刚,等.气-液膜接触器结构优化及其传质性能研究[J].膜科学与技术,2012,32(3):52-58.
[28]张效铭,程敢,张传祥.燃煤烟气氧化脱硫脱硝技术进展[J].应用化工,2018,47(2):375-385.
[29]丁卫科,段钰锋,张军,等.低温等离子改性复合钙基吸附剂烟气脱硫实验研究[J].化工进展,2017,36(3):1107-1112.
[30]张居兵,周莹,仲兆平,等.等离子体氧化NO耦合湿式氨法同时脱硫脱硝试验研究[J].东南大学学报:自然科学版,2014,44(6):1194-1199.
[31]国家环境保护总局,国家质量监督检验检疫总局. GB13223—2003火电厂大气污染物排放标准[S].北京:中国标准出版社,2004.
[32]环境保护部,国家质量监督检验检疫总局. GB13223—2011火电厂大气污染物排放标准[S].北京:中国标准出版社,2012.
[33]国家发展改革委,环境保护部,国家能源局.煤电节能减排升级与改造行动计划(2014~2020年)[EB/OL].[2014-09-12]. http://www. ndrc. gov. cn/gzdt/201409/t20140919_626240. html.
[34]叶春松,黄建伟,刘通,等.燃煤电厂烟气脱硫废水处理方法与技术进展[J].环境工程,2017,35(11):10-51.
[35]庞胜林,陈戎,毛进,等.火电厂石灰石-石膏湿法脱硫废水分离处理[J].热力发电,2016,45(9):128-133.
[2] Del Valle-Zermeo R,NiubóM,Formosa J,et al. Synergistic effect of the parameters affecting wet flue gas desulfurization using magnesium oxides by-products[J].Chemical Engineering Journal,2015,262:268-277.
[3]武宝会,李帅英,牛国平,等.燃煤机组烟气污染物协同脱除技术及应用[J].热力发电,2017,46(11):103-107.
[4]张军,张涌新,郑成航,等.复合脱硫添加剂在湿法烟气脱硫系统中的工程应用[J].中国环境科学,2014,34(9):2186-2191.
[5]贺鹏,张先明.中国燃煤发电厂烟气脱硫技术及应用[J].电力科技与环保,2014,30(1):8-11.
[6]武春锦,吕武华,梅毅,等.湿法烟气脱硫技术及运行经济性分析[J].化工进展,2015,34(12):4368-4374.
[7]景建平,吴文辉.石灰石膏湿法脱硫工艺主要运行参数控制调整探析[J].热力发电,2011,40(11):14-16.
[8]董丽彦,宋宝华,刘玉朋,等.烧结机脱硫系统应用复合增效剂的节能增效分析[J].环境工程,2016,34:602-605.
[9]董丽彦,程恺豪,柳雷,等.湿式石灰石-石膏法脱硫增效剂机理研究[J].广东化工,2014,41(18):133-134.
[10]赵丹,董延茂,王建华.氧化镁烟气脱硫废渣-硫酸镁废水-高钙粉煤灰脱氮除磷[J].环境工程学报,2016,10(8):4504-4510.
[11]刘阳,赵丹,董延茂,等.氧化镁烟气脱硫废渣在废水除磷中的应用[J].工业水处理,2013,22(18):19-21.
[12]齐笑言,宋宝华,刘安安,等.提高镁法烟气脱硫副产物氧化速率的实验研究[J].环境工程,2011,29:409-411.
[13]吕丽.氨法脱硫在锅炉烟气净化中的应用[J].能源化工,2017,38(2):75-79.
[14]丁红蕾,苏秋凤,张涌新,等.湿式氨法烟气脱硫工艺影响因素的试验研究[J].热力发电,2014,43(1):96-98.
[15]邱伟,刘盛余,陆成伟,等.氢氧化钠-钢渣双碱法烧结烟气脱硫工艺[J].环境工程学报,2013,7(3):1095-1100.
[16] Mbango Mbida K G,宋存义,周向.双碱法用于烧结烟气脱硫中再生实验的研究[J].环境工程,2012,30(3):127-130.
[17] Wang Dongpeng,Lu Yonghong,Li Zhe,et al. Integrated electrochemical-aerating oxidation in recovery system of seawater flue gas desulfurization[J]. Chemical Engineering Journal,2018,338:184-190.
[18] Bian Junjie,Zhang Shu,Zhang Jingwei,et al. Supported manganese dioxide catalyst for seawater flue gas desulfurization application[J]. Chemical Engineering Journal,2012,190:57-61.
[19]王思粉,冯丽娟,李先国.浅析我国海水烟气脱硫技术及改进[J].热力发电,2011,40(1):4-7.
[20]郭娟,袁东星,陈进生,等.燃煤电厂海水脱硫工艺的排水对海域环境的影响[J].环境工程学报,2008,2(5):707-711.
[21]骆锦钊.海水法烟气脱硫排水水质的估算和分析[J].电力环境保护,2007,23(2):19-22.
[22] Sun Lumin,Lin Shanhan,Feng Lifeng,et al. The distribution and sea-air transfer of volatile mercury in waste postdesulfurization seawater discharged from a coal-fired power plant[J]. Environmental Science and Pollution Research,2013,20:6191-6200.
[23] Zhu Zhengxuan,Ma Yongpeng,Qu Zan,et al. Study on a new wet flue gas desulfurization method based on the Bunsen reaction of sulfur-iodine thermochemical cycle[J].Fuel,2017,195:33-37.
[24] Zhang Ke,Zhao Xu,Chen Sihan,et al. Direct electrolysis of Bunsen reaction product HI/H2SO4/H2O/toluene mixture for hydrogen production Pt electrode characterization[J]. International Joural of Hydrogen Energy,2018,43:13702-13710.
[25]刘昭,邹海魁,初广文,等.旋转填充床中柠檬酸钠法烟气脱硫的实验研究[J].北京化工大学学报:自然科学版,2014,41(1):34-38.
[26]关毅鹏,陈颖,张召才,等.膜吸收法烟气同时脱硫脱硝试验研究[J].膜科学与技术,2014,34(1):111-115.
[27]陈颖,关毅鹏,郭春刚,等.气-液膜接触器结构优化及其传质性能研究[J].膜科学与技术,2012,32(3):52-58.
[28]张效铭,程敢,张传祥.燃煤烟气氧化脱硫脱硝技术进展[J].应用化工,2018,47(2):375-385.
[29]丁卫科,段钰锋,张军,等.低温等离子改性复合钙基吸附剂烟气脱硫实验研究[J].化工进展,2017,36(3):1107-1112.
[30]张居兵,周莹,仲兆平,等.等离子体氧化NO耦合湿式氨法同时脱硫脱硝试验研究[J].东南大学学报:自然科学版,2014,44(6):1194-1199.
[31]国家环境保护总局,国家质量监督检验检疫总局. GB13223—2003火电厂大气污染物排放标准[S].北京:中国标准出版社,2004.
[32]环境保护部,国家质量监督检验检疫总局. GB13223—2011火电厂大气污染物排放标准[S].北京:中国标准出版社,2012.
[33]国家发展改革委,环境保护部,国家能源局.煤电节能减排升级与改造行动计划(2014~2020年)[EB/OL].[2014-09-12]. http://www. ndrc. gov. cn/gzdt/201409/t20140919_626240. html.
[34]叶春松,黄建伟,刘通,等.燃煤电厂烟气脱硫废水处理方法与技术进展[J].环境工程,2017,35(11):10-51.
[35]庞胜林,陈戎,毛进,等.火电厂石灰石-石膏湿法脱硫废水分离处理[J].热力发电,2016,45(9):128-133.
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