聚氨酯用阻燃聚醚多元醇的研究进展
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摘要
简述了阻燃剂的发展概况、阻燃机制,综述了卤系阻燃聚醚多元醇、磷系阻燃聚醚多元醇、芳杂环阻燃聚醚多元醇及复合型阻燃聚醚多元醇用于聚氨酯的研究进展,指出未来阻燃聚醚多元醇的发展方向。
The development of flame retardants and the mechanism of flame retardancy were introduced in this paper. The research and application of flame retardant polyether polyols with halogen, phosphorus,aromatic heterocyclic and mixed type used for polyurethan were reviewed as well, and the future research directions of flame retardant polyether polyols were pointed out.
The development of flame retardants and the mechanism of flame retardancy were introduced in this paper. The research and application of flame retardant polyether polyols with halogen, phosphorus,aromatic heterocyclic and mixed type used for polyurethan were reviewed as well, and the future research directions of flame retardant polyether polyols were pointed out.
引文
[1]YEGANEH H,TALEMI PH,AMSHIDI S.Novel method for preparation of polyurethane elastomers with improved thermal stability and electrical insulating properties[J].Journal of Applied Polymer Science,2010,103(3):1776-1785.
[2]CHATTOPADHYAY DK,WEBSTER DC.Thermal stability and flame retardancy of polyurethanes[J].Progress in Polymer Science,2009,34(10):1068-1133.
[3]朱吕民,刘益军,苏醒,等.聚氨酯泡沫塑料[M].北京:化学工业出版社,2004:209.
[4]郑敏睿,张猛,李书龙,等.阻燃型聚氨酯泡沫研究新进展[J].热固性树脂,2016,31(4):62-68.
[5]徐娜,尤勇军,陆敏,等.反应型阻燃聚醚多元醇的合成及应用[J].热固性树脂,2017,32(4):20-23,28.
[6]乔英华.环氧环己烷-环氧氯丙烷聚醚多元醇的合成及其聚氨酯的制备[D].郑州:郑州大学,2018.
[7]杨中文,刘西文.塑料无卤阻燃剂的研究进展[J].塑料助剂,2015(5):6-14.
[8]WU Q,ZHANG Q,ZHAO L,et al.A novel and facile strategy for highly flame retardant polymer foam composite materials:Transforming silicone resin coating into silica self-extinguishing layer[J].Journal of Hazardous Materials,2017,336:222.
[9]PARK HS,KWON SY,SEO KJ,et al.Preparation and physical properties of polyurethane flame retardant coatings using phosphorus-containing lactone modified polyesters[J].Journal of Coating Technology,1999,71(899):59-65.
[10]PARK HS,KIM K,YOU HJ,et al.Preparation of modified polyesters containing triphosphorous and their application to PU flame-retardant coatings[J].Journal of Coatings Technology and Research,2006,3(1):53-60.
[11]TOYO BOSEKI,Polyester and process for producing the same:US,2008300349[P].2008.
[12]李艳,贾积恒,田盛益,等.含磷阻燃聚醚多元醇的制备及其在聚氨酯硬泡中的应用[J].聚氨酯工业,2016,31(1):25-28.
[13]吴昊,王庭慰,孔新平.含磷多元醇的合成及其阻燃改性PUR硬泡[J].工程塑料应用,2017,45(2):116-119.
[14]王夏春.新型含磷阻燃聚醚多元醇合成及应用的研究[A]//中国聚氨酯工业协会聚醚专业委员会.第七届聚醚(环氧丙烷)科研、生产、技术交流大会论文集[C].中国聚氨酯工业协会聚醚专业委员会:中国聚氨酯工业协会,2011:6.
[15]徐娜,胡娜,沈晓冬,等.曼尼希聚醚多元醇的合成及其应用[J].热固性树脂,2015,30(6):11-16.
[16]刘博,赵哲,董良建,等.芳香族聚醚的合成及用其制备的硬质聚氨酯泡沫的性能[J].化学推进剂与高分子材料,2017,15(6):82-85.
[17]贾润萍,魏路,何新耀,等.三聚氰胺基结构阻燃聚醚多元醇的合成及其阻燃性能评价[J].功能材料,2015,46(S1):156-160.
[18]丁海阳,王基夫,春鹏,等.阻燃型聚氨酯泡沫的制备及性能研究[J].热固性树脂,2017,32(1):39-43.
[19]王秋英.氮磷结构型阻燃聚醚多元醇的制备及其在慢回弹泡沫的应用[A]//中国聚氨酯工业协会.中国聚氨酯工业协会第十八次年会论文集[C].中国聚氨酯工业协会:中国聚氨酯工业协会,2016:5.
[20]张立柱,李心强,刘延良,等.阻燃聚醚多元醇、组合聚醚、聚氨酯泡沫及其制备方法:CN,104004175 A[P].2014.
[2]CHATTOPADHYAY DK,WEBSTER DC.Thermal stability and flame retardancy of polyurethanes[J].Progress in Polymer Science,2009,34(10):1068-1133.
[3]朱吕民,刘益军,苏醒,等.聚氨酯泡沫塑料[M].北京:化学工业出版社,2004:209.
[4]郑敏睿,张猛,李书龙,等.阻燃型聚氨酯泡沫研究新进展[J].热固性树脂,2016,31(4):62-68.
[5]徐娜,尤勇军,陆敏,等.反应型阻燃聚醚多元醇的合成及应用[J].热固性树脂,2017,32(4):20-23,28.
[6]乔英华.环氧环己烷-环氧氯丙烷聚醚多元醇的合成及其聚氨酯的制备[D].郑州:郑州大学,2018.
[7]杨中文,刘西文.塑料无卤阻燃剂的研究进展[J].塑料助剂,2015(5):6-14.
[8]WU Q,ZHANG Q,ZHAO L,et al.A novel and facile strategy for highly flame retardant polymer foam composite materials:Transforming silicone resin coating into silica self-extinguishing layer[J].Journal of Hazardous Materials,2017,336:222.
[9]PARK HS,KWON SY,SEO KJ,et al.Preparation and physical properties of polyurethane flame retardant coatings using phosphorus-containing lactone modified polyesters[J].Journal of Coating Technology,1999,71(899):59-65.
[10]PARK HS,KIM K,YOU HJ,et al.Preparation of modified polyesters containing triphosphorous and their application to PU flame-retardant coatings[J].Journal of Coatings Technology and Research,2006,3(1):53-60.
[11]TOYO BOSEKI,Polyester and process for producing the same:US,2008300349[P].2008.
[12]李艳,贾积恒,田盛益,等.含磷阻燃聚醚多元醇的制备及其在聚氨酯硬泡中的应用[J].聚氨酯工业,2016,31(1):25-28.
[13]吴昊,王庭慰,孔新平.含磷多元醇的合成及其阻燃改性PUR硬泡[J].工程塑料应用,2017,45(2):116-119.
[14]王夏春.新型含磷阻燃聚醚多元醇合成及应用的研究[A]//中国聚氨酯工业协会聚醚专业委员会.第七届聚醚(环氧丙烷)科研、生产、技术交流大会论文集[C].中国聚氨酯工业协会聚醚专业委员会:中国聚氨酯工业协会,2011:6.
[15]徐娜,胡娜,沈晓冬,等.曼尼希聚醚多元醇的合成及其应用[J].热固性树脂,2015,30(6):11-16.
[16]刘博,赵哲,董良建,等.芳香族聚醚的合成及用其制备的硬质聚氨酯泡沫的性能[J].化学推进剂与高分子材料,2017,15(6):82-85.
[17]贾润萍,魏路,何新耀,等.三聚氰胺基结构阻燃聚醚多元醇的合成及其阻燃性能评价[J].功能材料,2015,46(S1):156-160.
[18]丁海阳,王基夫,春鹏,等.阻燃型聚氨酯泡沫的制备及性能研究[J].热固性树脂,2017,32(1):39-43.
[19]王秋英.氮磷结构型阻燃聚醚多元醇的制备及其在慢回弹泡沫的应用[A]//中国聚氨酯工业协会.中国聚氨酯工业协会第十八次年会论文集[C].中国聚氨酯工业协会:中国聚氨酯工业协会,2016:5.
[20]张立柱,李心强,刘延良,等.阻燃聚醚多元醇、组合聚醚、聚氨酯泡沫及其制备方法:CN,104004175 A[P].2014.
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